Skip to main content
Log in

Effect of Three-Spin Groups on the Decay of Free Induction and the Primary Spin Echo in Linear Polymers with Free Ends

  • Published:
Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

A theory is proposed for signals of the decay of free induction and the primary echo in linear flexible-chain polymers containing isolated groups of dipole-coupled three spins with arbitrary constants of dipole–dipole interaction. A new way of calculating primary echo signals after the effect of two radio frequency pulses in a wide range of temperatures is described.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. Andrew, E.R. and Bersohn, R., J. Chem. Phys., 1950, vol. 18, no. 2, p. 159.

    Article  ADS  Google Scholar 

  2. Gutowsky, H.S. and Pake, G.E., J. Chem. Phys., 1950, vol. 18, p. 162.

    Article  ADS  Google Scholar 

  3. Powles, J.G. and Mansfield, P., Phys. Lett. A, 1962, no. 2, p. 58.

  4. Moskvich, Yu.N., Sergeev, N.A., and Dotsenko, G.I., Phys. Status Solidi A, 1975, p. 409.

  5. Chizhik, V.I., Kvantovaya radiofizika (Quantum Radiophysics), St. Petersburg: St. Petersburg. Gos. Univ., 2004.

  6. Kulagina, T.P., Karnaukh, G.E., and Golubeva, I.Yu., Appl. Magn. Reson., 2020, vol. 51, no. 2, p. 155.

    Article  Google Scholar 

  7. Kulagina, T.P., Karnaukh, G.E., and Golubeva, I.Yu., Russ. J. Phys. Chem. B, 2020, vol. 14, no. 2, p. 290.

    Google Scholar 

  8. Kulagina, T.P., Karnaukh, G.E., and Andrianov, S.A., Butlerovsk. Soobshch., 2013, no. 7, p. 35.

  9. Kulagina, T.P., Karnaukh, G.E., Kuzina, A.N., and Smirnov, L.P., Russ. J. Phys. Chem. B, 2013, vol. 7, no. 2, p. 170.

    Article  Google Scholar 

Download references

Funding

This work was performed as part of State Task no. АААА-А19-119071190017-7.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to T. P. Kulagina.

Additional information

Translated by A. Muravev

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kulagina, T.P., Karnaukh, G.E. & Golubeva, I.Y. Effect of Three-Spin Groups on the Decay of Free Induction and the Primary Spin Echo in Linear Polymers with Free Ends. Bull. Russ. Acad. Sci. Phys. 85, 894–897 (2021). https://doi.org/10.3103/S1062873821080153

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1062873821080153

Navigation