Skip to main content
SpringerLink
Log in

Features of the Order–Disorder Phase Transition during the Ordering of Ni4Mo and Ni4W Alloys with D1a Superstructure

  • Published:
Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Results are presented from studying atomic long-range order in Ni4Mo and Ni4W alloys via X-ray diffraction analysis. The phase transitions in these alloys are confirmed to be of the D1a → A1 type. The temperature dependences of the long-range order parameters are found to be similar in Ni4Mo and Ni4W alloys. The difference between their properties is due to different characters of the order–disorder phase transition. A transition from the single-phase state with D1a superstructure to single-phase А1 through the diphase (D1a → A1) region occurs in the Ni4Mo alloy. A more complex D1a → (A1 + δ) peritectoid transformation takes place in the Ni4W alloy. It is shown that an order parameter equal to unity can be obtained in Ni4Mo alloy through long-term ordering annealing, while such long-range order in Ni4W alloy (ηmax = 0.9) is impossible to obtain by annealing.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Potekaev, A.I., Klopotov, A.A., Morozov, M.M., et al., Strukturnye osobennosti binarnykh sistem so slaboustoichivymi sostoyaniyami (Structural Features of Binary Systems with Semi-Stable States), Tomsk: Izd. Nauchno-Tekh. Lit., 2014.

    Google Scholar 

  2. Matveeva, N.M. and Kozlov, E.V., Uporyadochennye fazy v metallicheskikh sistemakh (Ordered Phases in Metallic Systems), Moscow: Nauka, 1989.

    Google Scholar 

  3. Pollock, T.M. and Tin, S., J. Propul. Power, 2006, vol. 22, no. 2, p. 361.

    Article  Google Scholar 

  4. Genc, A., Ovecoglu, M.L., Baydogan, M., and Turan, S., Mater. Des., 2012, vol. 42, p. 495.

    Article  Google Scholar 

  5. Cheng, X.Y., Liu, W.Q., and Li, Q., Mater. Sci. Eng. A, 2008, vol. 486, p. 177.

    Article  Google Scholar 

  6. Klopotov, A.A., Kozlov, E.V., Potekaev, A.I., et al., Sb. trudov VI Mezhdunarodnoi konferentsii “Nanomaterialy i nanotekhnologii” (Proc. VI Int. Conf. “Nanomaterials and Nanotechnologies”), Ulan-Ude, 2016, p. 185.

    Google Scholar 

  7. Harker, D.J., Chem. Phys., 1944, vol. 12, no. 7, p. 315.

    ADS  Google Scholar 

  8. Lyakishev, N.P., Bannykh, O.A., Rokhlin, L.L., et al., Diagrammy sostoyaniya dvoinykh metallicheskikh sistem: Spravochnik (State Diagrams of Binary Metallic Systems: Handbook), Moscow: Mashinostroenie, 1996–2001.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Strength Physics and Materials Science, Siberian Branch, Russian Academy of Sciences, Tomsk, 634055, Russia

    M. V. Fedorischeva

  2. Tomsk State University of Architecture and Building, Tomsk, 634003, Russia

    A. A. Klopotov & R. A. Kozireva

  3. National Research Tomsk State University, Tomsk, 634050, Russia

    A. A. Klopotov, A. I. Potekaev & E. S. Marchenko

  4. Khakas State University, Abakan, 655000, Russia

    A. A. Popov

Authors
  1. M. V. Fedorischeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Klopotov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Potekaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. S. Marchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Popov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. R. A. Kozireva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. V. Fedorischeva.

Additional information

Original Russian Text © M.V. Fedorischeva, A.A. Klopotov, A.I. Potekaev, E.S. Marchenko, A.A. Popov, R.A. Kozireva, 2018, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2018, Vol. 82, No. 7, pp. 958–960.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fedorischeva, M.V., Klopotov, A.A., Potekaev, A.I. et al. Features of the Order–Disorder Phase Transition during the Ordering of Ni4Mo and Ni4W Alloys with D1a Superstructure. Bull. Russ. Acad. Sci. Phys. 82, 867–869 (2018). https://doi.org/10.3103/S1062873818070183

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1062873818070183

Search

Navigation