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Thermo-Optical Study of Short-Range Polar Order in a Ferroelectric Phase: The Ca2+ Impurity-Induced Ferroelectric Phase in SrTiO3

  • Proceedings of the XXI National Conference on Magnetoelectrics Physics
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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

The magnitudes and temperature dependences of the root-mean-square of polarization fluctuations, which characterizes short-range ordering below TC, are determined for the first time for Sr0.986Ca0.014TiO3 single crystals, using temperature measurements of light refraction made in a manner developed by the authors. Ab initio calculations of the equilibrium structures and total energies of three lowtemperature phases for SrTiO3 and CaTiO3 are performed and the symmetry of the ground state of their solid solution is identified on the basis of the obtained results. Features of short- and long-range ordering in the Ca2+-induced ferroelectric phase of the Sr1 − xCa x TiO3 system are discussed.

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References

  1. Di Domeniko, M. and Wemple, S.H., J. Appl. Phys., 1969, vol. 40, p.720.

    Article  ADS  Google Scholar 

  2. Sonin, A.S. and Vasilevskaya, A.S., Elektroopticheskie kristally (Electrooptic Crystals), Moscow: Atomizdat, 1971.

    Google Scholar 

  3. Burns, G. and Dacol, F.H., Ferroelectrics, 1981, vol. 37, p.661.

    Article  Google Scholar 

  4. Kleemann, W., Schafer, F.J., and Fontana, M.D., Phys. Rev. B, 1984, vol. 30, p. 1148.

    Article  ADS  Google Scholar 

  5. Kleemann, W., Schafer, F.J., and Rytz, D., Phys. Rev. B, 1986, vol. 34, p. 7873.

    Article  ADS  Google Scholar 

  6. Pisarev, R.V., Markovin, P.A., Shermatov, B.N., et al., Ferroelectrics, 1989, vol. 96, p.181.

    Article  Google Scholar 

  7. Burns, G. and Dacol, F.H., Solid State Commun., 1983, vol. 48, p.853.

    Article  ADS  Google Scholar 

  8. Korshunov, O.Yu., Markovin, P.A., and Pisarev, R.V., Ferroelectr., Lett. Sect., 1992, vol. 13, p.137.

    Article  Google Scholar 

  9. Guzhva, M.E., Lemanov, V.V., Markovin, P.A., and Kleemann, W., Phys. Solid State, 1997, vol. 39, no. 4, p.618.

    Article  ADS  Google Scholar 

  10. Vugmeister, B.E. and Glinchuk, M.D., Rev. Mod. Phys., 1990, vol. 62, p.993.

    Article  ADS  Google Scholar 

  11. Samara, G.A., J. Phys.: Condens. Matter, 2003, vol. 15, p. R367.

    ADS  Google Scholar 

  12. Kvyatkovskii, O.E., Phys. Solid State, 2001, vol. 43, no. 8, p. 1401.

    ADS  Google Scholar 

  13. Itoh, M., Wang, R., Inaguma, Y., et al., Phys. Rev. Lett., 1999, vol. 82, p. 3540.

    Article  ADS  Google Scholar 

  14. Bednorz, J.G. and Mueller, K.A., Phys. Rev. Lett., 1984, vol. 52, no. 25, p. 2289.

    Article  ADS  Google Scholar 

  15. Trepakov, V.A., Savinov, M.E., Prosandeev, S.A., et al., Phys. Status Solidi (c), 2005, vol. 2, no. 1, p.145.

    Article  ADS  Google Scholar 

  16. Kleemann, W., Bianchi, U., Buergel, A., et al., Phase Transitions, 1995, vol. 55, p.57.

    Article  Google Scholar 

  17. Kleemann, W., Schafer, F.J., and Rytz, D., Phys. Rev. Lett., 1985, vol. 54, p. 2038.

    Article  ADS  Google Scholar 

  18. Markovin, P.A., Kleemann, W., Linder, R., et al., J. Phys.: Condens. Matter, 1996, vol. 8, p. 2377.

    ADS  Google Scholar 

  19. Kleemann, W., Albertini, A., Kuss, M., et al., Ferroelectrics, 1997, vol. 203, p.57.

    Article  Google Scholar 

  20. Kleemann, W., Schafer, F.J., Miiller, K.A., et al., Ferroelectrics, 1988, vol. 80, p.297.

    Article  Google Scholar 

  21. Markovin, P.A., Trepakov, V.A., Tagantsev, A.K., Deineka, A., and Andreev, D.A., Phys. Solid State, 2016, vol. 58, no. 1, p.134.

    Article  ADS  Google Scholar 

  22. Markovin, P.A., Trepakov, V.A., Guzhva, M.E., et al., Mater. Res. Express, 2016, vol. 3, p. 115705.

    Article  ADS  Google Scholar 

  23. Markovin, P.A. and Pisarev, R.V., Sov. Phys. JETP, 1979, vol. 50, no. 6, p. 1190.

    ADS  Google Scholar 

  24. Muller, K.A., Berlinger, W., Capizzi, M., et al., Solid State Commun., 1970, vol. 8, p.549.

    Article  ADS  Google Scholar 

  25. Bianchi, U., PhD Thesis, Duisburg: Gerhard Mercator Univ. of Duisburg, 1996.

  26. Yamanaka, A., Kataoka, M., Inaba, Y., et al., Europhys. Lett., 2000, vol. 50, no. 5, p.688.

    Article  ADS  Google Scholar 

  27. Kvyatkovskii, O.E., Solid State Commun., 2001, vol. 117, p.455.

    Article  ADS  Google Scholar 

  28. Kvyatkovskii, O.E., Phys. Solid State, 2002, vol. 44, no. 6, p. 1135.

    Article  ADS  Google Scholar 

  29. Sai, N. and Vanderbilt, D., Phys. Rev. B, 2000, vol. 62, no. 21, p. 13942.

    Article  ADS  Google Scholar 

  30. Evarestov, R.A., Blokhin, E., Gryaznov, D., et al., Phys. Rev. B, 2011, vol. 83, no. 13, p. 134108.

    Article  ADS  Google Scholar 

  31. http://www.quantum-espresso.org.

  32. Perdew, J.P., Burke, K., and Ernzerhof, M., Phys. Rev. Lett., 1996, vol. 77, p. 3865.

    Article  ADS  Google Scholar 

  33. Monkhorst, H.J. and Pack, J.D., Phys. Rev. B, 1976, vol. 13, p. 5188.

    Article  ADS  MathSciNet  Google Scholar 

  34. Giannozzi, P., Baroni, S., Bonini, N., et al., J. Phys.: Condens. Matter, 2009, vol. 21, p. 395502. http://arxiv.org/abs/0906.2569.

    Google Scholar 

  35. Markovin, P.A. and Guzhva, M.E., Phys. Solid State, 2016, vol. 58, no. 1, p.140.

    Article  ADS  Google Scholar 

  36. Fuji, Y. and Sakudo, T., J. Appl. Phys., 1970, vol. 41, no. 10, p. 4118.

    Article  ADS  Google Scholar 

  37. Geusiz, J.E., Kuttz, S.K., Van Uitert, L.G., et al., Appl. Phys. Lett., 1964, vol. 4, no. 8, p. 141.

    Article  ADS  Google Scholar 

Download references

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Authors and Affiliations

  1. Ioffe Institute, St. Petersburg, 194021, Russia

    P. A. Markovin, V. A. Trepakov, M. E. Guzhva & O. E. Kvyatkovskii

  2. St. Petersburg Mining University, St. Petersburg, 199106, Russia

    M. E. Guzhva

  3. St. Petersburg Polytechnic University, St. Petersburg, 195251, Russia

    M. E. Guzhva & D. A. Andreev

Authors
  1. P. A. Markovin
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  2. V. A. Trepakov
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  3. M. E. Guzhva
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  4. O. E. Kvyatkovskii
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  5. D. A. Andreev
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Corresponding author

Correspondence to P. A. Markovin.

Additional information

Original Russian Text © P.A. Markovin, V.A. Trepakov, M.E. Guzhva, O.E. Kvyatkovskii, D.A. Andreev, 2018, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2018, Vol. 82, No. 3, pp. 316–322.

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Markovin, P.A., Trepakov, V.A., Guzhva, M.E. et al. Thermo-Optical Study of Short-Range Polar Order in a Ferroelectric Phase: The Ca2+ Impurity-Induced Ferroelectric Phase in SrTiO3. Bull. Russ. Acad. Sci. Phys. 82, 273–279 (2018). https://doi.org/10.3103/S1062873818030127

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  • DOI: https://doi.org/10.3103/S1062873818030127

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