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Synthesis and electrical properties of new perovskite-like AMn3V4O12 (A = Ca, Ce, and Sm) compounds

  • Proceedings of the Interdisciplinary Symposium “Ordering in Minerals and Alloys” OMA-18 and Proceedings of the International Interdisciplinary Symposium “Order, Disorder, and Properties of Oxides” ODPO-18
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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

AMn3V4O12 (A = Ca, Ce, and Sm) compounds with a perovskite structure are synthesized at high pressures and temperatures. The crystalline structure of these compounds (space group \(Im\bar 3\) Z = 2) is determined via X-ray analysis. If ions in the A sublattice are changed in the order Ca2+–Sm3+–Ce3+, the valence is redistributed from Ca2+Mn 2+3 V 4+4 O12 to Sm3+Mn 2+3 V 3.75+4 O12, and to Ce3+Mn 2+3 V 3.75+4 O12. The temperature dependences of the electrical resistivity are studied.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    N. I. Kadyrova, Yu. G. Zaynulin & A. P. Tyutyunnik

  2. Institute of Natural Sciences, Ural Federal University, Yekaterinburg, 620000, Russia

    N. V. Melnikova & A. A. Mirzorakhimov

Authors
  1. N. I. Kadyrova
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  2. Yu. G. Zaynulin
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  3. A. P. Tyutyunnik
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  4. N. V. Melnikova
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  5. A. A. Mirzorakhimov
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Corresponding author

Correspondence to N. I. Kadyrova.

Additional information

Original Russian Text © N.I. Kadyrova, Yu.G. Zaynulin, A.P. Tyutyunnik, N.V. Melnikova, A.A. Mirzorakhimov, 2016, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2016, Vol. 80, No. 6, pp. 687–690.

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Kadyrova, N.I., Zaynulin, Y.G., Tyutyunnik, A.P. et al. Synthesis and electrical properties of new perovskite-like AMn3V4O12 (A = Ca, Ce, and Sm) compounds. Bull. Russ. Acad. Sci. Phys. 80, 620–623 (2016). https://doi.org/10.3103/S1062873816060149

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  • DOI: https://doi.org/10.3103/S1062873816060149

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