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Fine structure of the X-ray photoelectron Ni 2 p spectrum in Ni1–x Co x Cr2O4 compounds

  • Proceedings of the International Symposium “Ordering in Minerals and Alloys” OMA-17 and Proceedings of the International Symposium “Order, Disorder, and Properties of Oxides” ODPO-17
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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

An interpretation of the components of the fine structure of X-ray photoelectron Ni \({2_{{p_{3/1,1/2}}}}\) spectra of Ni1–x Co x Cr2O4 solid solutions (x = 0.8, 0.5, 0.3, 0.02, 0.01, 0.005, 0.0) is given. It is shown that the A and B components of the fine structure in Ni \({2_{{p_{3/2}}}}\) spectra originate from the Ni2+ ions located in the octahedral and tetrahedral environments, respectively. The fraction of Ni2+ ions that occupy octahedral positions in ceramics of different composition is determined.

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Authors and Affiliations

  1. Research Institute of Physics, Southern Federal University, Rostov-on-Don, 344090, Russia

    A. T. Kozakov, K. A. Googlev, A. V. Nikolskii & S. I. Shevcova

  2. Rostov State Transport University, Rostov-on-Don, 344038, Russia

    A. G. Kochur

  3. Department of Physics, Southern Federal University, Rostov-on-Don, 344006, Russia

    V. I. Torgashev

Authors
  1. A. T. Kozakov
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  2. A. G. Kochur
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  3. K. A. Googlev
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  4. A. V. Nikolskii
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  5. V. I. Torgashev
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  6. S. I. Shevcova
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Corresponding author

Correspondence to A. T. Kozakov.

Additional information

Original Russian Text © A.T. Kozakov, A.G. Kochur, K.A. Googlev, A.V. Nikolskii, V.I. Torgashev, S.I. Shevcova, 2015, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2015, Vol. 79, No. 11, pp. 1560–1564.

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Kozakov, A.T., Kochur, A.G., Googlev, K.A. et al. Fine structure of the X-ray photoelectron Ni 2 p spectrum in Ni1–x Co x Cr2O4 compounds. Bull. Russ. Acad. Sci. Phys. 79, 1371–1375 (2015). https://doi.org/10.3103/S106287381511012X

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  • DOI: https://doi.org/10.3103/S106287381511012X

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