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Shear Hardening in the Rheology of Structured Systems

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Moscow University Chemistry Bulletin Aims and scope

Abstract

A structural rheological model is presented that describes the phenomenon of shear solidification in structured systems, namely, in concentrated suspensions, micellar solutions, and solutions of associated polymers. The reason for shear hardening (SH) is the appearance of a structure under the action of shear as a result of an increase in the cohesion force between particles or macromolecules. The integral characteristic of the structure is the total number of particles in the aggregates. The kinetic equation describing the process of formation-destruction of aggregates contains four rate constants and leads to a rheological equation with two coefficients.

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REFERENCES

  1. Barnes, H.A., J. Rheol., 1989, vol. 33, p. 329.

    Article  CAS  Google Scholar 

  2. Kirsanov, E.A. and Matveenko, V.N., Nen’yutonovskoe techenie dispersnykh, polimernykh i zhidkokristallicheskikh sistem. Strukturnyi podkhod (Non-Newtonian Flow of Dispersed, Polymeric, and Liquid Crystal Systems: Structural Approach), Moscow: Tekhnosfera, 2016.

  3. Kalman, D.P., Schein, J.B., Houghton, J.M., Laufer, C.H.N., Wetzel, E.D., and Wagner, N.J., Proc. Society for the Advancement of Materiel and Process Engineering (SAMPE), Baltimore, 2007, p. 1.

    Google Scholar 

  4. Raghavan, S.R. and Khan, S.A., J. Colloid Interface Sci., 1997, vol. 185, p. 57.

    Article  CAS  Google Scholar 

  5. Raghavan, S.R., Walls, H.J., and Khan, S.A., Langmuir, 2000, vol. 16, p. 7920. https://doi.org/10.1021/la991548q

    Article  CAS  Google Scholar 

  6. Hartmann, V. and Cressely, R., J. Phys. II, 1997, vol. 7, p. 1087. https://doi.org/10.1051/jp2:1997173

    Article  CAS  Google Scholar 

  7. Guo, X., Abdala, Ah.A., May, B.L., Lincoln, S.F., Khan, S.A., and Prud’homme, R.K., Polymer, 2006, vol. 47, p. 2976. https://doi.org/10.1016/J.POLYMER.2006.03.006

    Article  CAS  Google Scholar 

  8. English, R.J., Gulati, H.S., Jenkins, R.D., and Khan Saad, A., J. Rheol., 1997, vol. 41, p. 427. https://doi.org/10.1122/1.550017

    Article  CAS  Google Scholar 

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Funding

This study was financially supported as part of the state funding of the Department of Chemistry, Moscow State University, no. CITiS: 121031300084-1.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    V. N. Matveenko & E. A. Kirsanov

Authors
  1. V. N. Matveenko
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  2. E. A. Kirsanov
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All authors made an equivalent contribution to the preparation of the article.

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Correspondence to V. N. Matveenko.

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The authors declare that they have no conflicts of interest.

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Translated by P. Kuchina

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Matveenko, V.N., Kirsanov, E.A. Shear Hardening in the Rheology of Structured Systems. Moscow Univ. Chem. Bull. 77, 231–241 (2022). https://doi.org/10.3103/S0027131422050078

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  • DOI: https://doi.org/10.3103/S0027131422050078

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