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Crucible Atomizers Open Up New Opportunities for the Atomic Absorption Analysis of Trace Elements in Solid Samples with the Use of Fractional Evaporation

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Abstract

The atomic absorption analysis of trace elements in natural solid samples with the use of an improved crucible atomizer with several condensation/evaporation zones is shown to be advantageous. A new approach to fractional preconcentration is proposed, including two stages of thermal decomposition (high-temperature and low-temperature) of solid sample components when elements are evaporated and their vapors are condensed in heated and unheated zones. This approach facilitates the efficient suppression of non-selective interferences and matrix effects. It also improves the metrological characteristics of the element analysis of samples of complex composition.

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REFERENCES

  1. L’vov, B.V., J. Anal. Chem., 2005, vol. 60, no. 4, p. 382.

    Article  CAS  Google Scholar 

  2. Pupyshev, A.A., Atomno-absorbtsionnyi spektral’nyi analiz (Atomic Absorption Spectral Analysis), Moscow: Tekhnosfera, 2009.

  3. Volynskii, A.B., J. Anal. Chem., 2011, vol. 66, no. 11, p. 1049.

    Article  CAS  Google Scholar 

  4. Kuz’min, N.M. and Zolotov, Yu.A., Kontsentrirovanie sledov elementov (Preconcentration of Trace Elements), Moscow: Nauka, 1988.

  5. Spektral’nyi analiz chistykh veshchestv (Spectral Analysis of Pure Substances), Zil’bershtein, Kh.I., Ed., Leningrad: Khimiya, 1971.

  6. Belyaev, Yu.I., Oreshkin, V.N., and Vnukovskaya, G.L., Zh. Anal. Khim., 1975, vol. 30, no. 3, p. 503.

    CAS  Google Scholar 

  7. Rcheulishvili, A.N., Zh. Anal. Khim., 1981, vol. 36, no. 10, p. 1889.

    CAS  Google Scholar 

  8. Alekseenko, A.N., Guletskii, N.N., Korennoi, E.P., and Turkin, Yu.I., Zh. Prikl. Spectrosk., 1984, vol. 41, no. 3, p. 377.

    Google Scholar 

  9. Rettberg, T.M. and Holcombe, J.A., Spectrochim. Acta, Part B, 1984, vol. 39, nos. 2–3, p. 249.

    Article  Google Scholar 

  10. Oreshkin, V.N., Belyaev, Yu.I., and Vnukovskaya, G.L., Zavod. Lab., 1990, vol. 56, no. 12, p. 50.

    CAS  Google Scholar 

  11. Hocqullet, P., Spectrochim. Acta, Part B, 1992, vol. 47, no. 5, p. 719.

    Article  Google Scholar 

  12. Oreshkin, V.N., Vnukovskaya, G.L., and Tsizin, G.I., Geokhimiya, 1998, vol. 36, no. 1, p. 108.

    Google Scholar 

  13. Grinshtein, I.L., Vilpan, Y.A., Saraev, A.V., and Vasilieva, L.A., Spectrochim. Acta, Part B, 2001, vol. 56, no. 3, p. 261.

    Article  Google Scholar 

  14. Nagulin, K.Yu., Gil’mutdinov, A.Kh., and Grishin, L.F., J. Anal. Chem., 2003, vol. 58, no. 4, p. 389.

    Article  CAS  Google Scholar 

  15. Oreshkin, V.N. and Tsizin, G.I., J. Anal. Chem., 2012, vol. 67, no. 10, p. 830.

    Article  CAS  Google Scholar 

  16. Zakharov, Yu.A., Kokorina, O.E., Lysogorskii, Yu.V., and Staroverov, A.E., J. Anal. Chem., 2012, vol. 67, no. 8, p. 714.

    Article  CAS  Google Scholar 

  17. Oreshkin, V.N. and Tsizin, G.I., J. Anal. Chem., 2014, vol. 69, no. 3, p. 290.

    Article  CAS  Google Scholar 

  18. Oreshkin, V.N. and Tsizin, G.I., Moscow Univ. Chem. Bull. (Engl. Transl.), 2015, vol. 70, no. 4, p. 162.

  19. Govindaraju, K., Geostand. Newslett., 1989, vol. 13, special no. 1, p. 1.

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FUNDING

G. Tsisin thanks the Russian Foundation for Basic Research (project no. 18-03-00289-a) for supporting the element preconcentration study with the use of the DETATA sorbent.

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Authors and Affiliations

  1. Pushchino Research Center for Biological Studies, Institute of Basic Biological Problems, Russian Academy of Sciences, 142290, Pushchino, Moscow Region, Russia

    V. N. Oreshkin

  2. Department of Analytical Chemistry, Moscow State University, 119991, Moscow, Russia

    G. I. Tsisin

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    G. I. Tsisin

Authors
  1. V. N. Oreshkin
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  2. G. I. Tsisin
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Correspondence to G. I. Tsisin.

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Translated by A. Boutanaev

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Oreshkin, V.N., Tsisin, G.I. Crucible Atomizers Open Up New Opportunities for the Atomic Absorption Analysis of Trace Elements in Solid Samples with the Use of Fractional Evaporation. Moscow Univ. Chem. Bull. 74, 111–115 (2019). https://doi.org/10.3103/S002713141903009X

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  • DOI: https://doi.org/10.3103/S002713141903009X

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