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Dynamic Analysis of Adsorption-Desorption Equilibrium of Sublimed Aromatic Molecules Using Polarized Optical Waveguide Spectroscopy

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Abstract

The adsorption-desorption equilibrium of sublimed molecules has been analyzed dynamically by optical waveguide (OWG) spectroscopy. Dynamic change of the transition moment during adsorption behavior was successfully detected using polarized incident light. With this technique, sublimed planer aromatic molecules, such as azobenzene, were revealed to stack parallel to the solid surface at the initial stage followed by adsorption with relatively random orientation.

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Authors and Affiliations

  1. Optical Application Research, System Instruments Co., Ltd., 776-2 Komiya, Hachioji, Tokyo, 192-0031, Japan

    Hiromi Takahashi

  2. Department of Pathophysiology School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo, 192-0392, Japan

    Kyoko Fujita

  3. Department of Biotechnology, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo, 184-8588, Japan

    Hiroyuki Ohno

Authors
  1. Hiromi Takahashi
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  2. Kyoko Fujita
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  3. Hiroyuki Ohno
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Correspondence to Hiromi Takahashi.

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Takahashi, H., Fujita, K. & Ohno, H. Dynamic Analysis of Adsorption-Desorption Equilibrium of Sublimed Aromatic Molecules Using Polarized Optical Waveguide Spectroscopy. ANAL. SCI. 33, 465–467 (2017). https://doi.org/10.2116/analsci.33.465

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  • DOI: https://doi.org/10.2116/analsci.33.465

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