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Shear-Driven Flow Ice Chromatography as a Possible Tool Probing Ice/Water Interface

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Abstract

Although ice chromatography is a useful probe of ice interfaces, its low separation efficiency has often made difficult to access the ice/water interface. Coupling of this method with shear-driven flow chromatography, which has high separation potential, solves the problems involved in ice chromatography. This paper reports on shear-driven flow ice chromatographic instrumentation, and discusses the separation performance. Electrostatic separation of positively and negatively charged dyes is demonstrated with an OH--doped ice plate as a stationary phase.

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Acknowledgments

This work was supported by a Grant-in-aid for Scientific Research from the Japan Society for Promotion of Science. The authors thank Prof. Desmet for his helpful discussions on this work.

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Authors and Affiliations

  1. Department of Chemistry, Tokyo Institute of Technology, Meguro, Tokyo, 152-8551, Japan

    Masaya Shimizu, Makoto Harada, Akihide Hibara & Tetsuo Okada

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  1. Masaya Shimizu
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  2. Makoto Harada
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  3. Akihide Hibara
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  4. Tetsuo Okada
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Correspondence to Tetsuo Okada.

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Shimizu, M., Harada, M., Hibara, A. et al. Shear-Driven Flow Ice Chromatography as a Possible Tool Probing Ice/Water Interface. ANAL. SCI. 32, 805–808 (2016). https://doi.org/10.2116/analsci.32.805

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  • DOI: https://doi.org/10.2116/analsci.32.805

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