Abstract
The photoelectrochemical (PEC) performance of TiO2 nano-photoanode films was seriously limited due to week photoresponse, effortless recombination of photogenerated electrons/holes, and instability. In this work, we used narrow bandgap semiconductor CdS quantum dots that decorated TiO2 nanotube arrays to enhance its PEC performance. In addition, ultra-thin transparent grapheme oxide (GO) spreads on the surface of TiO2 photoanode film to avoid its light corrosion and improve the stability. Scanning electron microscope (SEM) images showed that the layer GO is well distributed on the surface of CdS/TiO2 film, and composite film GO/CdS/TiO2 has good PEC stability.
References
Z. Liu, X. Yuan, S. Zhang, J. Wang, Q. Huang, N. Yu, Y. Zhu, L. Fu, F. Wang, Y. Chen, Y. Wu, Three-dimensional ordered porous electrode materials for electrochemical energy storage. NPG Asia Mater. 11, 12 (2019)
E.S. Jung, M.A. Basit, M.A. Abbas, I. Ali, D.W. Kim, Y.M. Park, J.H. Bang, T.J. Park, Improved CdS quantum dot distribution on a TiO2 photoanode by an atomic-layer-deposited ZnS passivation layer for quantum dot-sensitized solar cells. Sol. Energy Mater. Sol. Cells 218, 2–58 (2020)
Q. Wang, J. Qiao, J. Zhou, Fabrication of Ag@Ag2S core-shell nanoparticles sensitized TiO2 nanotube arrays with high photoelectrochemical properties. Phys. Rev. Lett. 3, Q157–Q161 (2014)
D. Jiang, H. Yu, H. Yu, Modified g-C3N4/TiO2 nanosheets/ZnO ternary facet coupled heterojunction for photocatalytic degradation of p-toluenesulfonic acid (p-TSA) under visible light. Physica E 85, 1–6 (2017)
S.A. Pawar, D.S. Patil, A.C. Lokhande, M.G. Gang, J.C. Shin, P.S. Patil, J.H. Kim, Chemical synthesis of CdS onto TiO2 nanorods for quantum dot sensitized solar cells. Opt. Mater. 58, 46–50 (2016)
J. Liu, H. Zhang, F. Navarro-Pardo, G.S. Selopal, S. Sun, Z.M. Wang, H. Zhao, F. Rosei, Hybrid surface passivation of PbS/CdS quantum dots for efficient photoelectrochemical hydrogen generation. Appl. Surf. Sci. 530, 64–89 (2020)
N. Zhao, Y. Hu, J. Du, G. Liu, B. Dong, Y. Yang, J. Peng, J. Li, M. Zhai, Ti3C2Tx MXene-derived amorphous TiO2-C nanosheetcocatalysts coupled CdS nanostructures for enhanced photocatalytic hydrogen evolution. Appl. Surf. Sci. 530, 60–63 (2020)
X. Zheng, S. Liu, Y. Gu, S. Das, J. Zhao, Y. Gao, Optimization of photoelectrochemical performance of Ag2S/TiO2 interface by successive ionic layer adsorption and reaction. MRS Commun. 10, 194–199 (2020)
X. Zheng, S. Das, Y. Gu, S. Liu, J. Borovilas, J. Zhao, Cadmium sulfide/lead sulfide co-sensitized TiO2 enhances photoelectrochemical performance and corrosion resistance of 304 stainless steel. MRS Commun. 25 1361–1369 (2019)
M. Moztahida, D.S. Lee, Photocatalytic degradation of methylene blue with P25/graphene/polyacrylamide hydrogels: Optimization using response surface methodology. J. Hazard. Mater. 400, 12331 (2020)
Zhang, Y., Zhu, M., Zhang, S., Cai, Y., Lv, Z., Fang, M., Tan, X., and Wang, X.: Highly efficient removal of U(VI) by the photoreduction of SnO2/CdCO3/CdS nanocomposite under visible light irradiation. Applied Catalysis B-Environmental 279 (2020).
Z. Wang, Y. Chen, L. Zhang, B. Cheng, J. Yu, J. Fan, Step-scheme CdS/TiO2 nanocomposite hollow microsphere with enhanced photocatalytic CO2 reduction activity. J. Mater. Sci. Technol. 56, 143–150 (2020)
X. Cheng, Y. Lu, Y.-X. Liu, G. Tian, X.-Y. Yang, One-pot synthesis of hierarchical CdS/MoS2/rGO with enhanced (photo) electrocatalytic activities. Chem. Phys. Lett. (2020). https://doi.org/10.1016/j.cplett.2020.138047
X. Zheng, S. Das, Y. Gu, S. Liu, J. Zhao, Optimal engineering of CdS/PbS co-sensitized TiO2 nanotube arrays for enhanced photoelectrochemical performance. Ceram. Int. 46, 12050–12058 (2020)
B.R. Sankapal, D.B. Salunkhe, S. Majumder, D.P. Dubal, Solution-processed CdS quantum dots on TiO2: light-induced electrochemical properties. RSC Adv. 6, 83175–83184 (2016)
Yao, X., Hu, X., Zhang, W., Gong, X., Wang, X., Pillai, S.C., Dionysiou, D.D., and Wang, D.: Mie resonance in hollow nanoshells of ternary TiO2-Au-CdS and enhanced photocatalytic hydrogen evolution. Applied Catalysis B-Environmental 276 (2020).
D.M. Tobaldi, D. Dvoranova, L. Lajaunie, N. Rozman, B. Figueiredo, M.P. Seabra, A.S. Skapin, J.J. Calvino, V. Brezova, J.A. Labrincha, Graphene-TiO2 hybrids for photocatalytic aided removal of VOCs and nitrogen oxides from outdoor environment. Chem. Eng. J. (Lausanne, Switzerland : 1996) 405, 126651–126651 (2021)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hong, K., Zhou, J., Tong, H. et al. A stable photoelectrochemical graphene/CdS/TiO2 film for nano-photoanode. MRS Communications 11, 57–61 (2021). https://doi.org/10.1557/s43579-021-00013-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/s43579-021-00013-3