Skip to main content
SpringerLink
Log in

Structural, magnetocaloric effect, critical behavior, and spin resonance analysis of monovalent-doped manganites Nd0.6Sr0.4−xMxMnO3 (x = 0.0, 0.1; M = K, Na)

  • Article
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

In-depth research of the effects of monovalent doping on magnetocaloric properties of manganites Nd0.6Sr0.4−xMxMnO3 (x = 0.0, 0.1; M = K, Na) synthesized by sol–gel were studied. The magnetization-versus-temperature curves reveal a second-order phase transition from ferromagnetic to paramagnetic at the Curie temperature. The Curie temperature is found to decrease from 276 K in the Nd0.6Sr0.4MnO3 to 250 K and 248 K in Nd0.6Sr0.3K0.1MnO3 and Nd0.6Sr0.3Na0.1MnO3, respectively. The Nd0.6Sr0.3K0.1MnO3 has the highest isothermal magnetic entropy change (5.45 J/kg.K), whereas Nd0.6Sr0.3Na0.1MnO3 has the highest relative cooling power (144.41 J/Kg), which denotes its potentiality in cooling fields. The charge difference of Sr, K, and Na influence the ratio of Mn4+/Mn3+, causing significant fluctuations in Nd0.6Sr0.4MnO3manganite.Various approaches are used to derive the critical exponents, and they are shown to be consistent with the values predicted by the tricritical mean field. This work highlights that monovalent ions doped are promising for magnetic refrigeration near room temperature.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8

Similar content being viewed by others

Data availability

This manuscript has no associated data or the data will not be deposited. (Authors’ comment: There are no associated data available).

References

  1. J. Lenz, S. Edelstein, IEEE Sens. J. 6, 631 (2006)

    Google Scholar 

  2. P. Ripka, Magnetic Sensors and Magnetometers, Second Edition (Artech House, 2021)

  3. R.U.R. Sagar, X. Zaiping, J. Iqbal, S.U. Rehman, H. Ashraf, C. Liu, J. Zeng, T. Liang, Mater. Today Phys. 20, 100460 (2021)

    CAS  Google Scholar 

  4. J. Massoudi, O. Messaoudi, S. Gharbi, T. Mnasri, E. Dhahri, K. Khirouni, E.K. Hlil, L. Alfhaid, L. Manai, A. Azhary, J. Phys. Chem. C 126, 2857 (2022)

    CAS  Google Scholar 

  5. M. Jeddi, J. Massoudi, H. Gharsallah, S.I. Ahmed, E. Dhahri, E.K. Hlil, RSC Adv. 11, 7238 (2021)

    CAS  Google Scholar 

  6. H. Tang, V.K. Pecharsky, G.D. Samolyuk, M. Zou Jr., K.A. Gschneidner, V.P. Antropov, D.L. Schlagel, T.A. Lograsso, Phys. Rev. Lett. 93, 237203 (2004)

    CAS  Google Scholar 

  7. K.A. Gschneidner, V.K. Pecharsky, E. Brück, H.G.M. Duijn, E.M. Levin, Phys. Rev. Lett. 85, 4190 (2000)

    CAS  Google Scholar 

  8. J.R. Sun, F.X. Hu, B.G. Shen, Phys. Rev. Lett. 85, 4191 (2000)

    CAS  Google Scholar 

  9. V.K. Pecharsky, K.A. Gschneidner, J. Magn. Magn. Mater. 167, 179 (1997)

    Google Scholar 

  10. F. Casanova, X. Batlle, A. Labarta, J. Marcos, L. Mañosa, A. Planes, Phys. Rev. B 66, 100401 (2002)

    Google Scholar 

  11. I.A. Radulov, K.P. Skokov, DYu. Karpenkov, T. Gottschall, O. Gutfleisch, J. Magn. Magn. Mater. 396, 228 (2015)

    CAS  Google Scholar 

  12. S. Fujieda, A. Fujita, K. Fukamichi, Appl. Phys. Lett. 81, 1276 (2002)

    CAS  Google Scholar 

  13. A. Fujita, S. Fujieda, K. Fukamichi, J. Magn. Magn. Mater. 310, e1006 (2007)

    CAS  Google Scholar 

  14. A. Boutahar, M. Phejar, V.P. Boncour, L. Bessais, H. Lassri, J Supercond. Nov. Magn. 27, 1795 (2014)

    CAS  Google Scholar 

  15. M. Phejar, V. Paul-Boncour, L. Bessais, J. Solid State Chem. 233, 95 (2016)

    CAS  Google Scholar 

  16. J. Liu, J.D. Moore, K.P. Skokov, M. Krautz, K. Löwe, A. Barcza, M. Katter, O. Gutfleisch, Scripta Mater. 67, 584 (2012)

    CAS  Google Scholar 

  17. M. Fries, L. Pfeuffer, E. Bruder, T. Gottschall, S. Ener, L.V.B. Diop, T. Gröb, K.P. Skokov, O. Gutfleisch, Acta Mater. 132, 222 (2017)

    CAS  Google Scholar 

  18. M. Yue, M.F. Xu, H.G. Zhang, D.T. Zhang, D.M. Liu, Z. Altounian, IEEE Trans. Magn. 51, 1 (2015)

    CAS  Google Scholar 

  19. W. Zhong, C.-T. Au, Y.-W. Du, Chinese Phys. B 22, 057501 (2013)

    Google Scholar 

  20. J.S. Salcedo-Gallo, D.F. Rodríguez-Patiño, J.D. Alzate-Cardona, H. Barco-Ríos, E. Restrepo-Parra, Phys. Lett. A 382, 2069 (2018)

    CAS  Google Scholar 

  21. F. Hong, Z. Cheng, J. Wang, X. Wang, S. Dou, Appl. Phys. Lett. 101, 102411 (2012)

    Google Scholar 

  22. A. Somvanshi and S. Husain, in (Bikaner, India, 2018), p. 030242.

  23. A.M. Dharmayanti, Q. Mustaghfiroh, D.R. Munazat, D.S. Razaq, B. Kurniawan, D. Nanto, D. Handoko, KEM 855, 78 (2020)

    Google Scholar 

  24. A.M.R. Dharmayanti, D.R. Munazat, D.S. Razaq, B. Kurniawan, Q. Mustaghfiroh, D. Nanto, D. Handoko, J. Phys.: Conf. Ser. 1816, 012042 (2021)

    CAS  Google Scholar 

  25. L.N. Lau, K.P. Lim, A.N. Ishak, M.M. Awang Kechik, S.K. Chen, N.B. Ibrahim, M. Miryala, M. Murakami, A.H. Shaari, Coatings 11, 361 (2021)

    CAS  Google Scholar 

  26. B. Sudakshina, K.D. Chandrasekhar, H.D. Yang, M. Vasundhara, J. Phys. D: Appl. Phys. 50, 065004 (2017)

    Google Scholar 

  27. D. Paul, K.N. Anuradha, S.V. Bhat, Appl Magn Reson 50, 1359 (2019)

    CAS  Google Scholar 

  28. L. Demkó, I. Kézsmárki, G. Mihaly, N. Takeshita, Y. Tomioka, Y. Tokura, Phys. Rev. Lett. 101, 037206 (2008)

    Google Scholar 

  29. K. Sourav, K.N. Tapan, Adv. Mater. Res. 678, 131–136 (2009)

    Google Scholar 

  30. V. Caignaert, A. Maignan, B. Raveau, Solid State Commun. 95, 357 (1995)

    CAS  Google Scholar 

  31. A.M. Ahmed, H.F. Mohamed, A.K. Diab, S.A. Mohamed, S. García-Granda, D. Martínez-Blanco, Solid State Sci. 57, 1 (2016)

    CAS  Google Scholar 

  32. I.Z. Al-Yahmadi, A.M. Gismelseed, F. Al Ma’Mari, A.D. Al-Rawas, S.H. Al-Harthi, A.Y. Yousif, H.M. Widatallah, M.E. Elzain, M.T.Z. Myint, J. Alloys and Compd 875, 159977 (2021)

    CAS  Google Scholar 

  33. N. Abdelmoula, E. Dhahri, N. Fourati, L. Reversat, J. Alloy. Compd. 365, 25 (2004)

    CAS  Google Scholar 

  34. R. Thaljaoui, W. Boujelben, M. Pękała, K. Pękała, J.-F. Fagnard, P. Vanderbemden, M. Donten, A. Cheikhrouhou, J. Magnet. Magnetic Mater. 352, 6 (2014)

    CAS  Google Scholar 

  35. S.B. Kansara, D. Dhruv, B. Kataria, C.M. Thaker, S. Rayaprol, C.L. Prajapat, M.R. Singh, P.S. Solanki, D.G. Kuberkar, N.A. Shah, Ceram. Int. 41, 7162 (2015)

    CAS  Google Scholar 

  36. G. Akça, A.O. Ayaş, S.K. Çetin, M. Akyol, A. Ekicibil, J. Supercond. Nov. Magn. 30, 1515 (2017)

    Google Scholar 

  37. R.H. Heffner, L.P. Le, M.F. Hundley, J.J. Neumeier, G.M. Luke, K. Kojima, B. Nachumi, Y.J. Uemura, D.E. MacLaughlin, S.-W. Cheong, Phys. Rev. Lett. 77, 1869 (1996)

    CAS  Google Scholar 

  38. H. E. Stanley, Phase Transitions and Critical Phenomena (Clarendon Press, Oxford, 1971)

    Google Scholar 

  39. A. Hadded, J. Massoudi, S. Gharbi, E. Dhahri, A. Tozri, M.R. Berber, RSC Adv. 11, 25664 (2021)

    CAS  Google Scholar 

  40. D.B. Wiles, R.A. Young, J. Appl. Crystallogr. 14, 149 (1981)

    CAS  Google Scholar 

  41. R.D. Shannon, C.T. Prewitt, Acta Crystallogr. B Struct. Sci. 25, 925 (1969)

    CAS  Google Scholar 

  42. V.M. Goldschmidt, Z. Phys. Chem. 133, 397 (1928)

    CAS  Google Scholar 

  43. R.D. Shannon, Acta Cryst A 32, 751 (1976)

    Google Scholar 

  44. C.R. Bernaoui, A. Bendraoua, F. Zaoui, J.J. Gallardo, J. Navas, R.A. Boudia, H. Djediai, N. el Houda, M.A. Goual, Mater. Chem. Phys. 292, 126793 (2022)

    CAS  Google Scholar 

  45. J. Massoudi, D. Bouekkeze, A. Bougoffa, K. Khirouni, E. Dhahri, L. Bessais, Adv. Powder Technol. 31, 4714 (2020)

    CAS  Google Scholar 

  46. M.H. Ehsani, M.E. Ghazi, P. Kameli, J. Moradi, J. Supercond. Novel Magn. 29, 2969 (2016)

    CAS  Google Scholar 

  47. S. Das, T.K. Dey, J. Phys. D Appl. Phys. 40, 1855 (2007)

    CAS  Google Scholar 

  48. I. Fedorov, J. Lorenzana, P. Dore, G. De Marzi, P. Maselli, P. Calvani, S.-W. Cheong, S. Koval, R. Migoni, Phys. Rev. B 60, 11875 (1999)

    CAS  Google Scholar 

  49. F. Gao, R.A. Lewis, X.L. Wang, S.X. Dou, J. Alloy. Compd. 347, 314 (2002)

    CAS  Google Scholar 

  50. F. Gao, R.A. Lewis, X.L. Wang, S.X. Dou, Physica C 341, 2235 (2000)

    Google Scholar 

  51. F. Issaoui, M. Bejar, E. Dhahri, M. Bekri, P. Lachkar, E.K. Hlil, Physica B 414, 42 (2013)

    CAS  Google Scholar 

  52. A. Mabrouki, A. Benali, T. Mnasri, E. Dhahri, M.A. Valente, M. Jemmali, J. Mater. Sci.: Mater. Electron. 31, 22749 (2020)

    CAS  Google Scholar 

  53. V. Franco, A. Conde, J.M. Romero-Enrique, J.S. Blázquez, J. Phys.: Condens. Matter. 20, 285207 (2008)

    Google Scholar 

  54. M. Triki, E. Dhahri, E.K. Hlil, J. Solid State Chem. 201, 63 (2013)

    CAS  Google Scholar 

  55. S.N. Kaul, J. Magn. Magn. Mater. 53, 5 (1985)

    CAS  Google Scholar 

  56. A. Shengelaya, G. Zhao, H. Keller, K.A. Müller, B.I. Kochelaev, Phys. Rev. B 61, 5888 (2000)

    CAS  Google Scholar 

  57. S. Misra, S.I. Andronenko, P. Padia, S. Vadnala, S. Asthana, J. Magn. Magn. Mater. 519, 167450 (2021)

    CAS  Google Scholar 

  58. T.L. Phan, N.V. Khiem, N.X. Phuc, S.C. Yu, J. Magn. Magn. Mater. 304, e334 (2006)

    CAS  Google Scholar 

  59. R. Gupta, J.P. Joshi, S.V. Bhat, A.K. Sood, C.N.R. Rao, J. Phys.: Condens. Matter. 12, 6919 (2000)

    CAS  Google Scholar 

  60. J. Massoudi, M. Smari, K. Nouri, E. Dhahri, K. Khirouni, S. Bertaina, L. Bessais, E.K. Hlil, RSC Adv. 10, 34556 (2020)

    CAS  Google Scholar 

  61. S.L. Yuan, G. Li, Y. Jiang, J.Q. Li, X.Y. Zeng, Y.P. Yang, Z. Huang, S.Z. Jin, J. Phys.: Condens. Matter 12, L109 (2000)

    CAS  Google Scholar 

  62. R. Das, U. Chaudhuri, A. Chanda, R. Mahendiran, ACS Omega 5, 17611 (2020)

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Physique Appliquée, Faculté Des Sciences, Université de Sfax, B. P. 1171, 3000, Sfax, Tunisia

    Rim Ahmed Lassoued, Jalel Massoudi, Marwa Jeddi & Essebti Dhahri

  2. CMTR, ICMPE, UMR 7182 CNRS-UPEC, 2 Rue Henri Dunant, 94320, Thiais, France

    Lotfi Bessais

Authors
  1. Rim Ahmed Lassoued
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jalel Massoudi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Marwa Jeddi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Essebti Dhahri
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Lotfi Bessais
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Rim Ahmed Lassoued or Jalel Massoudi.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 2896.5 kb)

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lassoued, R.A., Massoudi, J., Jeddi, M. et al. Structural, magnetocaloric effect, critical behavior, and spin resonance analysis of monovalent-doped manganites Nd0.6Sr0.4−xMxMnO3 (x = 0.0, 0.1; M = K, Na). Journal of Materials Research 38, 4559–4572 (2023). https://doi.org/10.1557/s43578-023-01171-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/s43578-023-01171-x

Keywords

Search

Navigation