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ZnO:Al Thin Films by Successive Chemical Solution Deposition for Transistors Applications

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Here, we show results on the deposition of ZnO:Al thin films by the successive ionic layer adsorption and reaction method. The growing of the films was performed by sequentially immersing glass and SiO2/Si substrates in water at temperatures close to the boiling point, a precursor reaction solution, water at room temperature and ultrasonic water bath. The resulting ZnO:Al films were transparent and well adhered to the substrates. From X-ray diffraction analysis was determined that the ZnO:Al films had hexagonal wurtzite structure with preferential orientation along the c-axis. Changes in the morphology of the films were obtained from ellipsoidal-shaped aggregates for the undoped ZnO films to spherical-shaped aggregates for the ZnO:Al films. The optical transparency and bandgap of the ZnO:Al films was about 85% and 3.28 eV, respectively. Thin film transistors were fabricated with ZnO:Al films as active layers. The characterized device had a saturation mobility of 0.048 cm2/V-s, threshold voltage of approximately 16.1 V and a drain current on-to-off ratio (Ion/Ioff) in the order of 103.

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References

  1. X.-A. Zhang, J.-W. Zhang, W.-F. Zhang, D. Wang, Z. Bi, X.-M. Bian, and X. Hou, “Enhancement-mode thin film transistor with nitrogen-doped ZnO channel layer deposited by laser molecular beam epitaxy,” Thin Solid Films, vol. 516, pp. 3305–3308, Mar. 2008.

    Article  CAS  Google Scholar 

  2. D.-H. Lee, K.-H. Park, S. Kim, and S. Y. Lee, “Effect of Ag doping on the performance of ZnO thin film transistor,” Thin Solid Films, vol. 520, pp. 1160–1164, Nov. 2011.

    Article  CAS  Google Scholar 

  3. O. Lupan, S. Shishiyanu, V. Ursaki, H. Khallaf, L. Chow, T. Shishiyanu, and V. Sontea, “Synthesis of nanostructured Al-doped zinc oxide films on Si for solar cells applications,” Sol. Energy Mater. Sol. Cells, vol. 93, pp. 1417–1422, 2009.

    Article  CAS  Google Scholar 

  4. S. P. Shrestha, R. Ghimire, J. J. Nakarmi, and Y. Kim, “Properties of ZnO: Al Films Prepared by Spin Coating of Aged Precursor Solution,” Bull. Korean Chem. Soc., vol. 31, no. 1, pp. 112–115, 2010.

    Article  CAS  Google Scholar 

  5. P. Yao, S. Hang, M. Wu, and W. Hsiao, “Effects of post-deposition heat treatment on the microstructure and properties of Al-doped ZnO thin films prepared by aqueous phase deposition,” Thin Solid Films, vol. 520, pp. 2846–2854, 2012.

    Article  CAS  Google Scholar 

  6. P. P. Sahay and R. K. Nath, “Al-doped ZnO thin films as methanol sensors,” Sensors Actuators B Chem., vol. 134, pp. 654–659, 2008.

    Article  CAS  Google Scholar 

  7. A. Suzuki, T. Matsushita, N. Wada, Y. Sakamoto, and M. Okuda, “Transparent Conducting Al-Doped ZnO Thin Films Prepared by Pulsed Laser Deposition,” J. Appl. Phys., vol. 35, pp. L56–L59, 1996.

    Article  CAS  Google Scholar 

  8. A. E. Rakhshani, “Al-doped zinc oxide films grown by successive chemical solution deposition,” Appl. Phys. A, vol. 92, pp. 413–416, May 2008.

    Article  CAS  Google Scholar 

  9. X. D. Gao, X. M. Li, and W. D. Yu, “Synthesis and optical properties of ZnO nanocluster porous films deposited by modified SILAR method,” Appl. Surf. Sci., vol. 229, pp. 275–281, 2004.

    Article  CAS  Google Scholar 

  10. B. D. Cullity, The determination of crystal structure in Elements of X-Ray Diffraction. Massachusetts: Adisson-Wesley Publishing Company, 1956, pp. 309–310.

    Google Scholar 

  11. X.D. T. Gao, X. M. Li, and W. D. Yu, “Structural and morphological evolution of ZnO cluster film prepared by the ultrasonic irradiation assisted solution route,” Thin Solid Films, vol. 484, pp. 160–164, 2005.

    Article  CAS  Google Scholar 

  12. B. G. Svensson, S. Pearton and P. Jagadish, Oxide Semiconductors, 1st Ed. Academic Press, 2013

    Google Scholar 

Download references

acknowledgments

This work was supported by CONACYT-Mexico through the becas program and project with reference number CB-2009-01-134572

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González, L.A., Ramírez, S.E. & Pech-Canul, M.I. ZnO:Al Thin Films by Successive Chemical Solution Deposition for Transistors Applications. MRS Online Proceedings Library 1731, 61–66 (2014). https://doi.org/10.1557/opl.2015.468

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