Abstract
Organic films with a thickness of few nanometers are potentially useful components in many practical and commercial applications such as sensors, detectors, displays and electronic circuit components. In this context, the Langmuir-Blodgett (LB) method is one the most promising techniques for preparing these films.
In this work, we report the synthesis and characterization of three new amphiphilic organometallic compounds with ferrocene units, which consist of one ferrocenyl aminocarbene with the general formula FcC=Cr(CO)5NH(CH2)15CH3, and two ferrocenyl amides with the general formula FcC=MNH(CH2)15CH3 where M = S or Se. These new derivatives have been synthesized to study the influence of long alkyl side chain and the hydrophilic head on the film organization behavior at the air-water interface.
The Langmuir-Blodgett (LB) technique was focused for building ordered nanostructures in molecular assemblies of ferrocenyl derivatives, which are apt to form a stable and transferable monolayer film. The π-A isotherm, hysteresis, Brewster angle microscopy (BAM) and film stability were used to characterize the behavior of a monolayer film at the air-water interface. Z- type LB films were prepared from molecular monolayers which were transferred onto glass substrates. These films were characterized by atomic force microscopy (AFM), UV-Visible spectra and X-ray diffraction (DRX) techniques.
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References
P. Dynarowicz-Latka, A. Dhanabalan, O.N. Oliveira, Adv. Colloid Interface 91, 221 (2001).
W. A. Amer., J. Inorg. Organomet. Polym. 20, 605 (2010).
S. Fery-Forgues and B. Delavaux-Nicot, J. Photoch. Photobiol. A. 132, 137 (2000).
K. Sakakibara, et al., Biomacromolecules 8, 1657 (2007).
M. Singh, K. C. Bhahada, Y.K. Vijay, Indian Journal or Pure & Applied Physics 43, 129 (2005).
P. D. Beer, J. J. Davis, D. A. Drillsma-Milgrom, F. Szemes, Chem commu. 21, 1716 (2002).
E. Haro-Poniatowski Optics Letters. 17, 252 (1992).
C. Sandoval-Sánchez, et al., J. Organomet. Chem. 694, 3692 (2009).
A. I. Gutiérrez-Hernández, et al., J. Med. Chem. 2, A-L (2012).
J.G. López-Cortés, et al., J. Organomet. Chem. 690, 2229 (2005).
J.J. Giner-Casares, G. Brezesinski, Formatex Research Center, Badajoz, Spain, 1007 (2012).
C. Ybert, W. Lu, G. Möller, C.M. Knobler, J. Phys. Chem. B. 106, 2004 (2002).
H.E. Ries.Jr., H. Swif, Langmuir3, 853 (1987).
Acknowledgements
Authors thank Martín Cruz (ICN-UNAM), Carlos Flores, Adriana Tejeda (IIM-UNAM), Margarita Romero (F. Q.) for their technical assistance, and DGAPA-PAPIIT IN111711 and IB200312 projects. R.E. Lazo-Jiménez thanks CONACYT for the scholarship 104243.
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Lazo-Jiménez, R.E., López- Cortés, J.G., Chávez-Carvayar, J.A. et al. Organized Molecular Assemblies based on Ferrocenyl Derivatives. MRS Online Proceedings Library 1767, 23–33 (2015). https://doi.org/10.1557/opl.2015.223
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DOI: https://doi.org/10.1557/opl.2015.223