Abstract
Hybrid organic-inorganic halide perovskites have been recently explored as memristive devices that can be programmed to two or more stable conductance states for analog computing. The wide variety and range of optoelectronic phenomena these materials portray offer immense potential to develop scaled-in neuromorphic devices and architectures with multibit memory storage and multimodal accessibility. This article provides a general summary of the structural and optoelectronic characteristics of this material class that could be utilized for neuromorphic computing, discusses insights into the underlying switching mechanisms, and reviews recent developments in the field of halide perovskite-based neuromorphic devices.
Similar content being viewed by others
References
M.A. Zidan, J.P. Strachan, W.D. Lu, Nat. Electron. 1, 22 (2018).
Z. Wang, L. Wang, M. Nagai, L. Xie, M. Yi, W. Huang, Adv. Electron. Mater. 3, 1600510 (2017).
Y. van de Burgt, A. Melianas, S.T. Keene, G. Malliaras, A. Salleo, Nat. Electron. 1, 386 (2018).
R.E. Brandt, V. Stevanovic, D.S. Ginley, T. Buonassisi, MRS Commun. 5, 265 (2015).
R.A. John, N. Yantara, Y.F. Ng, G. Narasimman, E. Mosconi, D. Meggiolaro, M.R. Kulkarni, P.K. Gopalakrishnan, C.A. Nguyen, F. De Angelis, Adv. Mater. 30, 1805454 (2018).
B. Saparov, D.B. Mitzi, Chem. Rev. 116, 4558 (2016).
S. Tao, I. Schmidt, G. Brocks, J. Jiang, I. Tranca, K. Meerholz, S. Olthof, Nat. Commun. 10, 1 (2019).
Q. Wang, Y. Shao, H. Xie, L. Lyu, X. Liu, Y. Gao, J. Huang, Appl. Phys. Lett. 105, 163508 (2014).
Y. Yuan, J. Huang, Acc. Chem. Res. 49, 286 (2016).
B. Febriansyah, Y. Lekina, B. Ghosh, P.C. Harikesh, T.M. Koh, Y. Li, Z. Shen, N. Mathews, J. England, ChemSusChem 13, 2693 (2020).
H. Lin, C. Zhou, Y. Tian, T. Siegrist, B. Ma, ACS Energy Lett. 3, 54 (2018).
C.C. Stoumpos, D.H. Cao, D.J. Clark, J. Young, J.M. Rondinelli, J.I. Jang, J.T. Hupp, M.G. Kanatzidis, Chem. Mater. 28, 2852 (2016).
G. Grancini, M.K. Nazeeruddin, Nat. Rev. Mater. 4, 4 (2019).
X. Li, W. Ke, B. Traoré, P. Guo, I. Hadar, M. Kepenekian, J. Even, C. Katan, C.C. Stoumpos, R.D. Schaller, M.G. Kanatzidis, J. Am. Chem. Soc. 141, 12880 (2019).
R. Swartwout, M.T. Hoerantner, V. Bulovic, Energy Environ. Mater. 2, 119 (2019).
Z. Xiao, J. Huang, Adv. Electron. Mater. 2, 1600100 (2016).
W. Xu, H. Cho, Y.-H. Kim, Y.-T. Kim, C. Wolf, C.-G. Park, T.-W. Lee, Adv. Mater. 28, 5916 (2016).
H. Tian, L. Zhao, X. Wang, Y.-W. Yeh, N. Yao, B.P. Rand, T.-L. Ren, ACS Nano 11, 12247 (2017).
B. Hwang, J.-S. Lee, Adv. Mater. 29, 1701048 (2017).
K. Kang, H. Ahn, Y. Song, W. Lee, J. Kim, Y. Kim, D. Yoo, T. Lee, Adv. Mater. 31, 1804841 (2019).
B. Pradhan, S. Das, J. Li, F. Chowdhury, J. Cherusseri, D. Pandey, D. Dev, A. Krishnaprasad, E. Barrios, A. Towers, A. Gesquiere, L. Tetard, T. Roy, J. Thomas, Sci. Adv. 6, eaay5225 (2020).
H. Kim, M.-J. Choi, J.M. Suh, J.S. Han, S.G. Kim, Q.V. Le, S.Y. Kim, H.W. Jang, NPG Asia Mater. 12, 1 (2020).
Y. Zhu, P. Cheng, J. Shi, H. Wang, Y. Liu, R. Xiong, H. Ma, H. Ma, Adv. Electron. Mater. 6, 1900754 (2020).
S. Lee, H. Kim, D.H. Kim, W.B. Kim, J.M. Lee, J. Choi, H. Shin, G.S. Han, H.W. Jang, H.S. Jung, ACS Appl. Mater. Interfaces 12, 17039 (2020).
L. Zhao, R.A. Kerner, Z. Xiao, Y.L. Lin, K.M. Lee, J. Schwartz, B.P. Rand, ACS Energy Lett. 1, 595 (2016).
S. Svanström, T.J. Jacobsson, G. Boschloo, E.M.J. Johansson, H. Rensmo, U.B. Cappel, ACS Appl. Mater. Interfaces 12, 7212 (2020).
J.-M. Yang, S.-G. Kim, J.-Y. Seo, C. Cuhadar, D.-Y. Son, D. Lee, N.-G. Park, Adv. Electron. Mater. 4, 1800190 (2018).
S. Lee, J. Choi, J.B. Jeon, B.J. Kim, J.S. Han, T.L. Kim, H.S. Jung, H.W. Jang, Adv. Electron. Mater. 5, 1800586 (2019).
T.-Y. Yang, G. Gregori, N. Pellet, M. Grätzel, J. Maier, Angew. Chem. Int. Ed. 54, 7905 (2015).
A. Senocrate, J. Maier, J. Am. Chem. Soc. 141, 8382 (2019).
D.J. Kim, Y.J. Tak, W.-G. Kim, J.K. Kim, J.H. Kim, H.J. Kim, Adv. Mater. Interfaces 4, 1601035 (2017).
A. Senocrate, I. Moudrakovski, G.Y. Kim, T.-Y. Yang, G. Gregori, M. Grätzel, J. Maier, Angew. Chem. Int. Ed. Engl. 56, 7755 (2017).
M.H. Futscher, J.M. Lee, L. McGovern, L.A. Muscarella, T. Wang, M.I. Haider, A. Fakharuddin, L. Schmidt-Mende, B. Ehrler, Mater. Horiz. 6, 1497 (2019).
Y. Yuan, J. Chae, Y. Shao, Q. Wang, Z. Xiao, A. Centrone, J. Huang, Adv. Energy Mater. 5, 1500615 (2015).
Z. Xiao, Y. Yuan, Y. Shao, Q. Wang, Q. Dong, C. Bi, P. Sharma, A. Gruverman, J. Huang, Nat. Mater. 14, 193 (2015).
P.C. Harikesh, B. Wu, B. Ghosh, R.A. John, S. Lie, K. Thirumal, L.H. Wong, T.C. Sum, S. Mhaisalkar, N. Mathews, Adv. Mater. 30, 1802080 (2018).
C. Cuhadar, S.-G. Kim, J.-M. Yang, J.-Y. Seo, D. Lee, N.-G. Park, ACS Appl. Mater. Interfaces 10, 29741 (2018).
P.C. Harikesh, A. Surendran, B. Ghosh, R.A. John, A. Moorthy, N. Yantara, T. Salim, K. Thirumal, W.L. Leong, S. Mhaisalkar, N. Mathews, Adv. Mater. 32, 1906976 (2020).
P.S. Whitfield, N. Herron, W.E. Guise, K. Page, Y.Q. Cheng, I. Milas, M.K. Crawford, Sci. Rep. 6, 1 (2016).
J. Choi, J.S. Han, K. Hong, S.Y. Kim, H.W. Jang, Adv. Mater. 30, 1704002 (2018).
L. Pedesseau, J.-M. Jancu, A. Rolland, E. Deleporte, C. Katan, J. Even, Opt. Quantum Electron. 46, 1225 (2014).
X. Hong, T. Ishihara, A.V. Nurmikko, Phys. Rev. B 45, 6961 (1992).
E.A. Muljarov, S.G. Tikhodeev, N.A. Gippius, T. Ishihara, Phys. Rev. B 51, 14370 (1995).
S.-I. Kim, Y. Lee, M.-H. Park, G.-T. Go, Y.-H. Kim, W. Xu, H.-D. Lee, H. Kim, D.-G. Seo, W. Lee, T.-W. Lee, Adv. Electron. Mater. 5, 1900008 (2019).
B. Febriansyah, T.M. Koh, R.A. John, R. Ganguly, Y. Li, A. Bruno, S.G. Mhaisalkar, J. England, Chem. Mater. 30, 5827 (2018).
A.E. Maughan, J.A. Kurzman, J.R. Neilson, Inorg. Chem. 54, 370 (2015).
M.V. Kovalenko, L. Protesescu, M.I. Bodnarchuk, Science 358, 745 (2017).
M. Era, K. Miyake, Y. Yoshida, K. Yase, Thin Solid Films 393, 24 (2001).
W.-Q. Liao, D. Zhao, Y.-Y. Tang, Y. Zhang, P.-F. Li, P.-P. Shi, X.-G. Chen, Y.-M. You, R.-G. Xiong, Science 363, 1206 (2019).
H. Lu, J. Wang, C. Xiao, X. Pan, X. Chen, R. Brunecky, J.J. Berry, K. Zhu, M.C. Beard, Z.V. Vardeny, Sci. Adv. 5, eaay0571 (2019).
A.O. Polyakov, A.H. Arkenbout, J. Baas, G.R. Blake, A. Meetsma, A. Caretta, P.H.M. van Loosdrecht, T.T.M. Palstra, Chem. Mater. 24, 133 (2012).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Harikesh, P., Febriansyah, B., John, R.A. et al. Hybrid organic—inorganic halide perovskites for scaled-in neuromorphic devices. MRS Bulletin 45, 641–648 (2020). https://doi.org/10.1557/mrs.2020.193
Published:
Issue Date:
DOI: https://doi.org/10.1557/mrs.2020.193