Abstract
Solid-oxide fuel cells (SOFCs) are an energy conversion technology with unique potential to have the highest energy conversion efficiency with the least environmental impact, as well as broad fuel flexibility from renewable to conventional fuels. Lowering the SOFC operating temperature will further lower system and operational costs, increase long-term durability, and allow more rapid start-up, providing feasibility for load following and transportation applications. Unfortunately, at reduced temperatures, the thermally activated nature of ionic conduction and electrochemical reactions increase polarization resistances, thus decreasing cell and system performance. However, lower operating temperatures also create the opportunity to employ nanostructured materials with higher surface area-to-volume ratios and greater interphase and interfacial regions, which can greatly enhance electrochemical performance. Here, we review recent progress in the development of various nanostructured electrodes and electrolytes and discuss their effects on the enhancement of the electrocatalytic activity of oxygen reduction and fuel oxidation, as well as oxygen-ion conduction, in order to achieve high-performance low-temperature SOFCs.
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References
E.D. Wachsman, K.T. Lee, Science 334, 935 (2011).
B.C.H. Steele, A. Heinzel, Nature 414, 345 (2001).
E.P. Murray, T. Tsai, S.A. Barnett, Nature 400, 649 (1999).
S.D. Park, J.M. Vohs, R.J. Gorte, Nature 404, 265 (2000).
Y.H. Huang, R.I. Dass, Z.L. Xing, J.B. Goodenough, Science 312, 254 (2006).
L. Yang, S.Z. Wang, K. Blinn, M.F. Liu, Z. Liu, Z. Cheng, M.L. Liu, Science 326, 126 (2009).
K.T. Lee, C.M. Gore, E.D. Wachsman, J. Mater. Chem. 22, 22405 (2012).
C.S. Song, Catal. Today 77, 17 (2002).
K.T. Lee, H.S. Yoon, E.D. Wachsman, J. Mater. Res. 27, 2063 (2012).
E.D. Wachsman, C.A. Marlowe, K.T. Lee, Energy Environ. Sci. 5, 5498 (2012).
D.J.L. Brett, A. Atkinson, N.P. Brandon, S.J. Skinner, Chem. Soc. Rev. 37, 1568 (2008).
A.S. Arico, P. Bruce, B. Scrosati, J.M. Tarascon, W. Van Schalkwijk, Nat. Mater. 4, 366 (2005).
S.B. Adler, Chem. Rev. 104, 4791 (2004).
C.R. Xia, W. Rauch, F.L. Chen, M.L. Liu, Solid State Ionics 149, 11 (2002).
K. Sasaki, J. Tamura, H. Hosoda, T.N. Lan, K. Yasumoto, M. Dokiya, Solid State Ionics 148, 551 (2002).
T. Ishihara, T. Kudo, H. Matsuda, Y. Takita, J. Electrochem. Soc. 142, 1519 (1995).
M. Mogensen, S. Skaarup, Solid State Ionics 86–8, 1151 (1996).
M. Godickemeier, K. Sasaki, L.J. Gauckler, I. Riess, Solid State Ionics 86–8, 691 (1996).
N.Q. Minh, J. Am. Ceram. Soc. 76, 563 (1993).
E.P. Murray, T. Tsai, S.A. Barnett, Solid State Ionics 110, 235 (1998).
S.P. Yoon, J. Han, S.W. Nam, T.H. Lim, I.H. Oh, S.A. Hong, Y.S. Yoo, H.C. Lim, J. Power Sources 106, 160 (2002).
S.P. Jiang, J. Power Sources 124, 390 (2003).
N.P. Brandon, S. Skinner, B.C.H. Steele, Annu. Rev. Mater. Res. 33, 183 (2003).
C.W. Tanner, K.Z. Fung, A.V. Virkar, J. Electrochem. Soc. 144, 21 (1997).
E.P. Murray, S.A. Barnett, Solid State Ionics 143, 265 (2001).
K.T. Lee, D.W. Jung, H.S. Yoon, A.A. Lidie, M.A. Camaratta, E.D. Wachsman, J. Power Sources 220, 324 (2012).
F. Deganello, V. Esposito, M. Miyayama, E. Traversa, J. Electrochem. Soc. 154, A89 (2007).
F. Han, R. Muecke, T. Van Gestel, A. Leonide, N.H. Menzler, H.P. Buchkremer, D. Stover, J. Power Sources 218, 157 (2012).
Z.P. Shao, S.M. Haile, Nature 431, 170 (2004).
A. Petric, P. Huang, F. Tietz, Solid State Ionics 135, 719 (2000).
A. Mai, M. Becker, W. Assenmacher, F. Tietz, D. Hathiramani, E. Ivers-Tiffee, D. Stover, W. Mader, Solid State Ionics 177, 1965 (2006).
E. Bucher, A. Egger, G.B. Caraman, W. Sitte, J. Electrochem. Soc. 155, B1218 (2008).
D. Oh, D. Gostovic, E.D. Wachsman, J. Mater. Res. 27, 1992 (2012).
X.J. Chen, S.H. Chan, K.A. Khor, Electrochim. Acta 49, 1851 (2004).
V.M. Janardhanan, V. Heuveline, O. Deutschmann, J. Power Sources 178, 368 (2008).
W. Zhu, D. Ding, C. Xia, Electrochem. Solid-State Lett. 11, B83 (2008).
L.A. Chick, L.R. Pederson, G.D. Maupin, J.L. Bates, L.E. Thomas, G.J. Exarhos, Mater. Lett. 10, 6 (1990).
S.G. Huang, C.Q. Peng, Z. Zong, J. Power Sources 176, 102 (2008).
K.T. Lee, B.W. Lee, B.A. Camaratta, E.D. Wachsman, RSC Adv. 3, 19866 (2013).
W.S. Jang, S.H. Hyun, S.G. Kim, J. Mater. Sci. 37, 2535 (2002).
Y. Zhen, S.P. Jiang, J. Power Sources 180, 695 (2008).
K. Sato, T. Kinoshita, H. Abe, M. Naito, J. Ceram. Soc. Jpn. 117, 1186 (2009).
Q.A. Zhen, G.M. Kale, G. Shi, R. Li, W.M. He, J.Q. Liu, Solid State Ionics 176, 2727 (2005).
K.T. Lee, D.W. Jung, M.A. Camaratta, H.S. Yoon, J.S. Ahn, E.D. Wachsman J. Power Sources 205, 122 (2012).
K.T. Lee, A.A. Lidie, S.Y. Jeon, G.T. Hitz, S.J. Song, E.D. Wachsman, J. Mater. Chem. A 1, 6199 (2013).
A. Hagiwara, N. Hobara, K. Takizawa, K. Sato, H. Abe, M. Naito, Solid State Ionics 178, 1123 (2007).
L. Baque, A. Caneiro, M.S. Moreno, A. Serquis, Electrochem. Commun. 10, 1905 (2008).
S.P. Jiang, Mater. Sci. Eng. A 418, 199 (2006).
J.M. Vohs, R.J. Gorte, Adv. Mater. 21, 943 (2009).
Z.Y. Jiang, C.R. Xia, F.L. Chen, Electrochim. Acta 55, 3595 (2010).
S.P. Jiang, Int. J. Hydrogen Energy 37, 449 (2012).
T.Z. Sholklapper, C. Lu, C.P. Jacobson, S.J. Visco, L.C. De Jonghe, Electrochem. Solid-State Lett. 9, A376 (2006).
T.Z. Sholklapper, H. Kurokawa, C.P. Jacobson, S.J. Visco, L.C. De Jonghe, Nano Lett. 7, 2136 (2007).
F. Zhao, R. Peng, C. Xia, Mater. Res. Bull. 43, 370 (2008).
M.E. Lynch, L. Yang, W.T. Qin, J.J. Choi, M.F. Liu, K. Blinn, M.L. Liu, Energy Environ. Sci. 4, 2249 (2011).
C.C. Kan, H.H. Kan, F.M. Van Assche, E.N. Armstrong, E.D. Wachsman, J. Electrochem. Soc. 155, B985 (2008).
C.C. Kan, E.D. Wachsman, Solid State Ionics 181, 338 (2010).
E.N. Armstrong, K.L. Duncan, D.J. Oh, J.F. Weaver, E.D. Wachsman, J. Electrochem. Soc. 158, B492 (2011).
E.N. Armstrong, K.L. Duncan, E.D. Wachsman, Phys. Chem. Chem. Phys. 15, 2298 (2013).
M.J. Zhi, N. Mariani, R. Gemmen, K. Gerdes, N.Q. Wu, Energy Environ. Sci. 4, 417 (2011).
M. Zhi, S. Lee, N. Miller, N.H. Menzler, N. Wu, Energy Environ. Sci. 5, 7066 (2012).
J. Sacanell, A.G. Leyva, M.G. Bellino, D.G. Lamas, J. Power Sources 195, 1786 (2010).
J. Sacanell, M.G. Bellino, D.G. Lamas, A.G. Leyva, Physica B 398, 341 (2007).
M.G. Bellino, J.G. Sacanell, D.G. Lamas, A.G. Leyva, N.E. Walsoe de Reca, J. Am. Chem. Soc. 129, 3066 (2007).
Y. Gong, D. Palacio, X. Song, R.L. Patel, X. Liang, X. Zhao, J.B. Goodenough, K. Huang, Nano Lett. 13, 4340 (2013).
C.W. Sun, U. Stimming, J. Power Sources 171, 247 (2007).
S. Zha, Z. Cheng, M. Liu, J. Electrochem. Soc. 154, B201 (2007).
K. Eguchi, H. Kojo, T. Takeguchi, R. Kikuchi, K. Sasaki, Solid State Ionics 152, 411 (2002).
H. Kurokawa, T.Z. Sholklapper, C.P. Jacobson, L.C. De Jonghe, S.J. Visco, Electrochem. Solid-State Lett. 10, B135 (2007).
S. Park, R.J. Gorte, J.M. Vohs, J. Electrochem. Soc. 148, A443 (2001).
M.D. Gross, J.M. Vohs, R.J. Gorte, J. Mater. Chem. 17, 3071 (2007).
J. Pena-Martinez, D. Marrero-Lopez, J.C. Ruiz-Morales, C. Savaniu, P. Nunez, J.T.S. Irvine, Chem. Mater. 18, 1001 (2006).
Q.X. Fu, F. Tietz, D. Stover, J. Electrochem. Soc. 153, D74 (2006).
S. Shen, L. Guo, H. Liu, Int. J. Hydrogen Energy 38, 1967 (2013).
T. Ishihara, T.H. Shin, P. Vanalabhpatana, K. Yonemoto, M. Matsuka, Electrochem. Solid-State Lett. 13, B95 (2010).
S.P. Jiang, X.J. Chen, S.H. Chan, J.T. Kwok, K.A. Khor, Solid State Ionics 177, 149 (2006).
S.P. Jiang, L. Liu, K.P. Ong, P. Wu, H. Li, H. Pu, J. Power Sources 176, 82 (2008).
T.H. Shin, Y. Okamoto, S. Ida, T. Ishihara, Chem. Eur. J. 18, 11695 (2012).
A.M. Hussain, J.V.T. Hogh, W. Zhang, P. Blennow, N. Bonanos, B.A. Boukamp, Electrochim. Acta 113, 635 (2013).
S.P. Jiang, X.J. Chen, S.H. Chan, J.T. Kwok, J. Electrochem. Soc. 153, A850 (2006).
S.P. Jiang, Y. Ye, T. He, S.B. Ho, J. Power Sources 185, 179 (2008).
J.S. Ahn, H. Yoon, K.T. Lee, M.A. Camaratta, E.D. Wachsman, Fuel Cells 9, 643 (2009).
N. Ai, Z. Lu, K.F. Chen, X.Q. Huang, X.B. Du, W.H. Su, J. Power Sources 171, 489 (2007).
R.E. Williford, L.A. Chick, G.D. Maupin, S.P. Simner, J.W. Stevenson, J. Electrochem. Soc. 150, A1067 (2003).
A.A.E. Hassan, N.H. Menzler, G. Blass, M.E. Ali, H.P. Buchkremer, D. Stover, Adv. Eng. Mater. 4, 125 (2002).
J.R. Kong, K.N. Sun, D.R. Zhou, N.Q. Zhang, J. Mu, J.S. Qiao, J. Power Sources 166, 337 (2007).
K.T. Lee, N.J. Vito, H.S. Yoon, E.D. Wachsman, J. Electrochem. Soc. 159, F187 (2012).
K.T. Lee, N.J. Vito, E.D. Wachsman, J. Power Sources 228, 220 (2013).
K.T. Lee, H.S. Yoon, J.S. Ahn, E.D. Wachsman, J. Mater. Chem. 22, 17113 (2012).
Z.L. Zhan, S.A. Barnett, Science 308, 844 (2005).
W. Wang, S.P. Jiang, A.I.Y. Tok, L. Luo, J. Power Sources 159, 68 (2006).
A. Babaei, S.P. Jiang, J. Li, J. Electrochem. Soc. 156, B1022 (2009).
T. Ishihara, H. Matsuda, Y. Takita, Solid State Ionics 79, 147 (1995).
K.Q. Huang, R.S. Tichy, J.B. Goodenough, J. Am. Ceram. Soc. 81, 2565 (1998).
Z. Zhan, D.M. Bierschenk, J.S. Cronin, S.A. Barnett, Energy Environ. Sci. 4, 3951 (2011).
D. Beckel, A. Bieberle-Huetter, A. Harvey, A. Infortuna, U.P. Muecke, M. Prestat, J.L.M. Rupp, L.J. Gauckler, J. Power Sources 173, 325 (2007).
Y. Matsuzaki, M. Hishinuma, I. Yasuda, Thin Solid Films 340, 72 (1999).
S.Y. Wang, W. Wang, Q.C. Liu, M. Zhang, Y.T. Qian, Solid State Ionics 133, 211 (2000).
J.H. Shim, C.-C. Chao, H. Huang, F.B. Prinz, Chem. Mater. 19, 3850 (2007).
J.S. Park, Y.B. Kim, J.H. Shim, S. Kang, T.M. Guer, F.B. Prinz, Chem. Mater. 22, 5366 (2010).
J.S. Park, T.P. Holme, J.H. Shim, F.B. Prinz, MRS Commun. 2, 107 (2012).
C.-C. Chao, C.-M. Hsu, Y. Cui, F.B. Prinz, ACS Nano 5, 5692 (2011).
C.-C. Chao, J.S. Park, X. Tian, J.H. Shim, T.M. Guer, F.B. Prinz, ACS Nano 7, 2186 (2013).
J.H. Shim, S. Kang, S.-W. Cha, W. Lee, Y.B. Kim, J.S. Park, T.M. Guer, F.B. Prinz, C.-C. Chao, J. An, J. Mater. Chem. A 1, 12695 (2013).
J. An, Y.-B. Kim, J. Park, T.M. Guer, F.B. Prinz, Nano Lett. 13, 4551 (2013).
J.H. Joo, G.M. Choi, Solid State Ionics 177, 1053 (2006).
U.P. Muecke, D. Beckel, A. Bernard, A. Bieberle-Huetter, S. Graf, A. Infortuna, P. Mueller, J.L.M. Rupp, J. Schneider, L.J. Gauckler, Adv. Funct. Mater. 18, 3158 (2008).
C.-W. Kwon, J.-W. Son, J.-H. Lee, H.-M. Kim, H.-W. Lee, K.-B. Kim, Adv. Funct. Mater. 21, 1154 (2011).
K.-R. Lee, J.-H. Lee, H.-I. Yoo, Phys. Chem. Chem. Phys. 15, 15632 (2013).
J.L. Hertz, H.L. Tuller, J. Electroceram. 13, 663 (2004).
S. Rey-Mermet, Y. Yan, C. Sandu, G. Deng, P. Muralt, Thin Solid Films 518, 4743 (2010).
K. Kerman, B.-K. Lai, S. Ramanathan, Adv. Energy Mater. 2, 656 (2012).
A. Evans, A. Bieberle-Huetter, J.L.M. Rupp, L.J. Gauckler, J. Power Sources 194, 119 (2009).
J. Fleig, H.L. Tuller, J. Maier, Solid State Ionics 174, 261 (2004).
M. Aoki, Y.M. Chiang, I. Kosacki, I.J.R. Lee, H. Tuller, Y.P. Liu, J. Am. Ceram. Soc. 79, 1169 (1996).
S.P.S. Badwal, S. Rajendran, Solid State Ionics 70, 83 (1994).
A. Bernasik, K. Kowalski, A. Sadowski, J. Phys. Chem. Solids 63, 233 (2002).
R. Gerhardt, A.S. Nowick, M.E. Mochel, I. Dumler, J. Am. Ceram. Soc. 69, 647 (1986).
H.L. Tuller, Solid State Ionics 131, 143 (2000).
K.L. Kliewer, J.S. Koehler, Phys. Rev. 140, 1226 (1965).
J. Maier, Prog. Solid State Chem. 23, 171 (1995).
J. Maier, Solid State Ionics 23, 59 (1987).
J. Maier, Phys. Chem. Chem. Phys. 11, 3011 (2009).
A.L. Despotuli, V.I. Nikolaichik, Solid State Ionics 60, 275 (1993).
J. Schoonman, Solid State Ionics 157, 319 (2003).
J. Maier, Solid State Ionics 157, 327 (2003).
J. Maier, Nat. Mater. 4, 805 (2005).
J. Maier, Chem. Mater. 26, 348 (2014).
C. Leon, J. Santamaria, B.A. Boukamp, MRS Bull. 38, 1056 (2013).
P. Mondal, A. Klein, W. Jaegermann, H. Hahn, Solid State Ionics 118, 331 (1999).
S.S. Jiang, W.A. Schulze, V.R.W. Amarakoon, G.C. Stangle, J. Mater. Res. 12, 2374 (1997).
X. Guo, E. Vasco, S.B. Mi, K. Szot, E. Wachsman, R. Waser, Acta Mater. 53, 5161 (2005).
I. Kosacki, T. Suzuki, V. Petrovsky, H.U. Anderson, Solid State Ionics 136, 1225 (2000).
I. Kosacki, C.M. Rouleau, P.F. Becher, J. Bentley, D.H. Lowndes, Solid State Ionics 176, 1319 (2005).
S. Azad, O.A. Marina, C.M. Wang, L. Saraf, V. Shutthanandan, D.E. McCready, A. El-Azab, J.E. Jaffe, M.H. Engelhard, C.H.F. Peden, S. Thevuthasan, Appl. Phys. Lett. 86, 131906 (2005).
A. Peters, C. Korte, D. Hesse, N. Zakharov, J. Janek, Solid State Ionics 178, 67 (2007).
G. Knoner, K. Reimann, R. Rower, U. Sodervall, H.E. Schaefer, Proc. Natl. Acad. Sci. U.S.A. 100, 3870 (2003).
R.A. De Souza, M.J. Pietrowski, U. Anselmi-Tamburini, S. Kim, Z.A. Munir, M. Martin, Phys. Chem. Chem. Phys. 10, 2067 (2008).
J. Garcia-Barriocanal, A. Rivera-Calzada, M. Varela, Z. Sefrioui, E. Iborra, C. Leon, S.J. Pennycook, J. Santamaria, Science 321, 676 (2008).
X. Guo, Science 324, 465 (2009).
R.A. De Souza, A. Ramadan, S. Hoerner, Energy Environ. Sci. 5, 5445 (2012).
B. Zhu, Int. J. Energy Res. 33, 1126 (2009).
Y. Zhao, C. Xia, L. Jia, Z. Wang, H. Li, J. Yu, Y. Li, Int. J. Hydrogen Energy 38, 16498 (2013).
R. Chockalingam, V.R.W. Amarakoon, H. Giesche, J. Eur. Ceram. Soc. 28, 959 (2008).
Q.X. Fu, S.W. Zha, W. Zhang, D.K. Peng, G.Y. Meng, B. Zhu, J. Power Sources 104, 73 (2002).
G.Y. Meng, Q.X. Fu, S.W. Zha, C.R. Xia, X.Q. Liu, D.K. Peng, Solid State Ionics 148, 533 (2002).
B. Zhu, X.G. Liu, P. Zhou, X.T. Yang, Z.G. Zhu, W. Zhu, Electrochem. Commun. 3, 566 (2001).
S.-S. Baek, N. Lee, B.-K. Kim, H. Chang, S.-J. Song, J.-Y. Park, Int. J. Hydrogen Energy 37, 16823 (2012).
X. Wang, Y. Ma, R. Raza, M. Muhammed, B. Zhu, Electrochem. Commun. 10, 1617 (2008).
B. Zhu, S. Li, B.E. Mellander, Electrochem. Commun. 10, 302 (2008).
X. Wang, Y. Ma, S. Li, A.-H. Kashyout, B. Zhu, M. Muhammed, J. Power Sources 196, 2754 (2011).
Y. Ma, X. Wang, S. Li, M.S. Toprak, B. Zhu, M. Muhammed, Adv. Mater. 22, 1640 (2010).
C. Xia, Y. Li, Y. Tian, Q. Liu, Z. Wang, L. Jia, Y. Zhao, Y. Li, J. Power Sources 195, 3149 (2010).
C. Xia, L. Li, Y. Tian, Q. Liu, Y. Zhao, L. Jia, Y. Li, J. Power Sources 188, 156 (2009).
Y. Zhao, C. Xia, Y. Wang, Z. Xu, Y. Li, Int. J. Hydrogen Energy 37, 8556 (2012).
D. Ding, B. Liu, Z. Zhu, S. Zhou, C. Xia, Solid State Ionics 179, 896 (2008).
J. Huang, Z. Gao, Z. Mao, Int. J. Hydrogen Energy 35, 4270 (2010).
R. Raza, X. Wang, Y. Ma, X. Liu, B. Zhu, Int. J. Hydrogen Energy 35, 2684 (2010).
A.S.V. Ferreira, C.M.C. Soares, F.M.H.L.R. Figueiredo, F.M.B. Marques, Int. J. Hydrogen Energy 36, 3704 (2011).
R. Chockalingam, S. Basu, Int. J. Hydrogen Energy 36, 14977 (2011).
M.A. Khan, R. Raza, R.B. Lima, M.A. Chaudhry, E. Ahmed, G. Abbas, Int. J. Hydrogen Energy 38, 16524 (2013).
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Lee, K.T., Wachsman, E.D. Role of nanostructures on SOFC performance at reduced temperatures. MRS Bulletin 39, 783–791 (2014). https://doi.org/10.1557/mrs.2014.193
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DOI: https://doi.org/10.1557/mrs.2014.193