Abstract
In this work, the effects of different preparation methods on the microstructures and properties of the Ti45.7Zr33Ni3Cu5.8Be12.5 alloy were systematically studied by both experimental and numerical ways. It is found that the heating methods and the cooling rate during the process of preparation have great influences not only on the morphology and crystalline structure of the solid solutions but also on the thermal stability of the amorphous phase. Furthermore, the different crystalline structures and micromorphologies of the ductile phase will also influence the mechanical properties. And the uniaxial compression tests at room temperature verify that the Ti45.7Zr33Ni3Cu5.8Be12.5 samples obtained by different preparation methods possess different degrees of plasticity. The better comprehensive properties were found for samples with a larger size under the copper mold cooling conditions. The variation of the morphology of the solid solution phase under different preparation conditions is believed to be the vital factor that leads to the diversity in properties.
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References
J. Qiao: In-situ dendrite/metallic glass matrix composites: A review. J. Mater. Sci. Technol. 29, 685 (2013).
D.C. Hofmann, J.Y. Suh, A. Wiest, M.L. Lind, M.D. Demetriou, and W.L. Johnson: Development of tough, low-density titanium-based bulk metallic glass matrix composites with tensile ductility. Proc. Natl. Acad. Sci. U. S. A. 105, 20136 (2008).
D.C. Hofmann, J-Y. Suh, A. Wiest, G. Duan, M-L. Lind, M.D. Demetriou, and W.L. Johnson: Designing metallic glass matrix composites with high toughness and tensile ductility. Nature 451, 1085 (2008).
Y.S. Oh, C.P. Kim, S. Lee, and N.J. Kim: Microstructure and tensile properties of high-strength high-ductility Ti-based amorphous matrix composites containing ductile dendrites. Acta Mater. 59, 7277 (2011).
D.J. Ha, C.P. Kim, and S. Lee: Tensile deformation behavior of two Ti-based amorphous matrix composites containing ductile beta dendrites. Mater. Sci. Eng., A 552, 404 (2012).
J.W. Qiao, A.C. Sun, E.W. Huang, Y. Zhang, P.K. Liaw, and C.P. Chuang: Tensile deformation micromechanisms for bulk metallic glass matrix composites: From work-hardening to softening. Acta Mater. 59, 4126 (2011).
J.W. Qiao, Y. Zhang, P.K. Liaw, and G.L. Chen: Micromechanisms of plastic deformation of a dendrite/Zr-based bulk-metallic-glass composite. Scr. Mater. 61, 1087 (2009).
G. He, J. Eckert, and W. Loser: Stability, phase transformation and deformation behavior of Ti-base metallic glass and composites. Acta Mater. 51, 1621 (2003).
S. Pauly, S. Gorantla, G. Wang, U. Kuhn, and J. Eckert: Transformation-mediated ductility in CuZr-based bulk metallic glasses. Nat. Mater. 9, 473 (2010).
Y.A. Wu, Y.H. Xiao, G.L. Chen, C.T. Liu, and Z.P. Lu: Bulk metallic glass composites with transformation-mediated work-hardening and ductility. Adv. Mater. 22, 2770 (2010).
J.W. Qiao, J.T. Zhang, F. Jiang, Y. Zhang, P.K. Liaw, Y. Ren, and G.L. Chen: Development of plastic Ti-based bulk-metallic-glass-matrix composites by controlling the microstructures. Mater. Sci. Eng., A 527, 7752 (2010).
J. Mu, Z. Zhu, R. Su, Y. Wang, H. Zhang, and Y. Ren: In situ high-energy X-ray diffraction studies of deformation-induced phase transformation in Ti-based amorphous alloy composites containing ductile dendrites. Acta Mater. 61, 5008 (2013).
R.L. Narayan, P.S. Singh, D.C. Hofmann, N. Hutchinson, K.M. Flores, and U. Ramamurty: On the microstructure-tensile property correlations in bulk metallic glass matrix composites with crystalline dendrites. Acta Mater. 60, 5089 (2012).
J-L. Cheng, G. Chen, C-T. Liu, and Y. Li: Innovative approach to the design of low-cost Zr-based BMG composites with good glass formation. Sci. Rep. 3, 2097 (2013).
M. Tang, Z. Zhu, H. Fu, A. Wang, H. Li, H. Zhang, G. Ma, H. Zhang, and Z. Hu: Ti-based amorphous composites with quantitatively controlled in-situ formation of dendrites. Acta Metall. Sin. 48, 861 (2012).
P.F. Sha, Z.W. Zhu, H.M. Fu, H. Li, A.M. Wang, H.W. Zhang, H.F. Zhang, and Z.Q. Hu: Effects of casting temperature on the microstructure and mechanical properties of the TiZr-based bulk metallic glass matrix composite. Mater. Sci. Eng., A 589, 182 (2014).
M.Q. Tang: Glass-forming ability of Ti-based amorphous alloys and in-situ composites. PhD Thesis, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 2012, p. 71.
K. Zheng: Numerical simulation of the temperature field and investigation on the parameters for plasma arc melting of titanium alloy. Master Thesis, Harbin Institute of Technology, Harbin, 2006, p. 35.
J.L. Cheng, G. Chen, F. Xu, Y.L. Du, Y.S. Li, and C.T. Liu: Correlation of the microstructure and mechanical properties of Zr-based in-situ bulk metallic glass matrix composites. Intermetallics 18, 2425 (2010).
C. Jeon, C.P. Kim, S.H. Joo, H.S. Kim, and S. Lee: High tensile ductility of Ti-based amorphous matrix composites modified from conventional Ti-6Al-4V titanium alloy. Acta Mater. 61, 3012 (2013).
J. Mao: Influence of solidification conditions on formation and properties of bulk metallic glasses. PhD Thesis, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 2010, p. 68.
G. Lütjering and J.C. Williams: Titanium, 2nd ed. (Springer, Berlin, Heidelberg, New York, USA, 2007), pp. 15, 52.
Y.Q. Cheng and E. Ma: Atomic-level structure and structure-property relationship in metallic glasses. Prog. Mater. Sci. 56, 379 (2011).
P.F. Sha, Z.W. Zhu, M.Q. Tang, H.M. Fu, Z.K. Li, H. Li, A.M. Wang, H.W. Zhang, H.F. Zhang, and Z.Q. Hu: Effects of quasicrystal formation on the crystallization of (Ti36.1Zr33.2Ni5.8Be24.9)(100-x)Cu-x (x=5, 7, 9, 11, 13, 15, 17) metallic glasses. J. Appl. Phys. 113, 033508 (2013).
J.N. Mei, J.L. Soubeyroux, J.J. Blandin, J.S. Li, H.C. Kou, H.Z. Fu, and L. Zhou: Structural relaxation of Ti40Zr25Ni8Cu9Be18 bulk metallic glass. J. Non-Cryst. Solids 357, 110 (2011).
Z. Evenson and R. Busch: Equilibrium viscosity, enthalpy recovery and free volume relaxation in a Zr44Ti11Ni10Cu10Be25 bulk metallic glass. Acta Mater. 59, 4404 (2011).
D.V. Louzguine and A. Inoue: Comparison of the long-term thermal stability of various metallic glasses under continuous heating. Scr. Mater. 47, 887 (2002).
Z.W. Zhu, H.F. Zhang, H. Wang, B.Z. Ding, and Z.Q. Hu: Influence of casting temperature on the thermal stability of Cu- and Zr-based metallic glasses: Theoretical analysis and experiments. J. Mater. Res. 23, 2714 (2008).
M.T. Clavaguera-Mora, N. Clavaguera, D. Crespo, and T. Pradell: Crystallisation kinetics and microstructure development in metallic systems. Prog. Mater. Sci. 47, 559 (2002).
L. Anand and C. Su: A theory for amorphous viscoplastic materials undergoing finite deformations, with application to metallic glasses. J. Mech. Phys. Solids 53, 1362 (2005).
W.F. Wu, C.Y. Zhang, Y.W. Zhang, K.Y. Zeng, and Y. Li: Stress gradient enhanced plasticity in a monolithic bulk metallic glass. Intermetallics 16, 1190 (2008).
A.L. Greer, Y.Q. Cheng, and E. Ma: Shear bands in metallic glasses. Mater. Sci. Eng., R 74, 71 (2013).
J.Y. Lee, K.H. Han, J.M. Park, K. Chattopadhyay, W.T. Kim, and D.H. Kim: Deformation and evolution of shear bands under compressive loading in bulk metallic glasses. Acta Mater. 54, 5271 (2006).
L.H. Dai and Y.L. Bai: Basic mechanical behaviors and mechanics of shear banding in BMGs. Int. J. Impact Eng. 35, 704 (2008).
H. Bei, S. Xie, and E.P. George: Softening caused by profuse shear banding in a bulk metallic glass. Phys. Rev. Lett. 96, 105503 (2006).
X. Lei, Y. Wei, Z. Hu, and W-H. Wang: Strength softening at shear bands in metallic glasses. Philos. Mag. Lett. 93, 221 (2013).
ACKNOWLEDGMENTS
The authors gratefully acknowledge the financial support from National Basic Research Program of China (973 Program, Grant No. 2011CB606301), the National Natural Science Foundation of China (51434008), and The Program of “One Hundred Talented People” of The Chinese Academy of Sciences.
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Meng, Y., Sha, P.F., Zhu, Z.W. et al. The influence of different preparation methods on the microstructures and properties of the in situ bulk-metallic-glass-matrix composites. Journal of Materials Research 30, 512–520 (2015). https://doi.org/10.1557/jmr.2014.406
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DOI: https://doi.org/10.1557/jmr.2014.406