Skip to main content
Log in

Evaluating the Extender Characteristics of Some Local Materials in Akure, Ondo State, Nigeria for Applications in the Paints Industry

  • Published:
MRS Advances Aims and scope Submit manuscript

Abstract

Soil samples were obtained from three different locations; Ijapo, Ibule and FUTA North Gate in Akure, Ondo State, Nigeria. The materials were dried, crushed and calcined by heating the samples in a muffle furnace to 850 °C, holding for three hours and and then brought out of the furnace to cool in the laboratory so that the organic and volatile matter escaped, and the oxide content increased. The calcined materials were milled with a ball mill and then sieved with 75 μm mesh size British standard sieves. The samples that passed through the sieves were collected for analysis to determine their extender characteristics through x-ray flouresence (XRF) spectroscopy, x-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), specific gravity, oil absorption, pH and refractive index measurements as well as the determination of their resistance to chemicals. XRF results showed that materials are kaolinite in nature. XRD results showed the phase compositions of each sample as materials suitable for applications as extenders in the paints industry. SEM micrographs showed the homogeneity of the samples from Ijapo and FUTA North Gate while the sample from Ibule showed segregation of the phase compositions. The specific gravity, pH, oil absorption and refractive index of each material were within the range of those of commercial extenders used in the paints industry. The calcined materials were found to be resistant to various chemical media. The characterized materials will be suitable as extenders and pigments in the paints industry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. P. N. Opara, “Production of textcoat and emulsion paints stainless for youth skill and entrepreneurship empowerment program”, Journal of Educational Policy and Entrepreneurial Research , vol. 1, no. 1, pp. 96–102, 2014.

    Google Scholar 

  2. C. Iwelunmo. (2017). Paint manufacturers decry high cost, scarcity of raw materials, [The Daily Times, September 30]. Available: https://dailytimes.ng/paint-manufacturers-decry-high-cost-scarcity-raw-materials/ [Accessed: 1 March 2018].

  3. A. Okon. (2017). Paint manufacturers lament high cost, raw materials scarcity, [The Punch, September 29]. Available: https://punchng.com/paints-manufacturers-lament-high-cost-raw-materials-scarcity/ [Accessed: 1 March 2018].

  4. N. M. Ahmed, “Comparative study on the role of kaolin, calcined kaolin and chemically treated kaolin in alkyd-based paint for protection of steel”, Pigment and Resin, vol. 42, pp. 3–14, 2013.

    Article  CAS  Google Scholar 

  5. I. O. Igwe, G. Osuoha and C. Nwapa, “Characterization and utilization of Eziulo clay as an extender in emulsion paint formulations”, Journal of Minerals and Materials Characterization and Engineering, vol. 5, pp. 174–184, 2017.

    Article  CAS  Google Scholar 

  6. C. M. Ewulonu, I. O. Igwe and G. N. Onyeagoro, “Performance of local clay—titanuim dioxide core—shell extender pigments in alkyd paints”, Advances in Nanoparticles, vol. 5, pp. 90–102, 2016.

    Article  CAS  Google Scholar 

  7. I. C. Chukwujike, and I. O. Igwe, “Extender properties of some Nigerian clays”, Journal of Minerals and Materials Characterization and Engineering, vol. 4, pp. 297–291, 2016.

    Article  Google Scholar 

  8. I. C. Chukwujike, I. O. Igwe and G. N. Onyeagoro, “Performance evaluation of local clay-extender pigment on alkyd paint formulations”, International Journal of Modern Research in Engineering and Technology, vol. 3, no. 3, pp. 30–41, 2016.

    Google Scholar 

  9. I. C. Chukwujike, J. L. Chukwuneke, S. C. Nwanonenyi and I. E. Digitemie, “Effect of particle sized clay extender pigment on alkyd paint formulations”, Covenant Journal of Engineering Technology, vol. 1, no. 1, pp. 31–46, 2018.

    Google Scholar 

  10. I. O. Igwe, C. M. Ewulonu, A. N. Chikei and B. Nicholas, “Performance evaluation of Aro-Ndizuogu local clay in alkyd paint production”, International Journal of Engineering and Technologies, vol. 7, pp. 87–93, 2016.

    Article  CAS  Google Scholar 

  11. A. A. Raheem and O. A. Olowu, “Production of household paint using clay materials”, International Journal of Engineering Research and Applications, vol. 3, no. 2, pp. 085–093, 2013.

    Google Scholar 

  12. T. O. Odozi, R. Dore and C. O. Onu, “Paint extenders based upon an indigenous clay”, Journal of Nigerian Society of Chemical Engineers, vol. 5, pp. 34–40, 1986.

    Google Scholar 

  13. ASTM International, ASTM D 153 - 84, “Standard test methods for specific gravity of pigments”, in Annual Book of ASTM Standards, ASTM International, West Conshohocken, USA, 1984.

  14. ASTM International, ASTM D 281- 12(2016), “Standard test method for oil absorption of pigments by spatula rub-out”, in Annual Book of ASTM Standards, ASTM International, West Conshohocken, USA, 2016.

  15. ASTM International, ASTM D 34 – 08 “Standard Guide for Chemical Analysis of White Pigments”, in Annual Book of ASTM Standards, ASTM International, West Conshohocken, USA, 2014.

  16. ASTM International, ASTM D 1208- 96, “Standard Test Methods for Common Properties of Certain Pigments”, in Annual Book of ASTM Standards, ASTM International, West Conshohocken, USA, 1996.

  17. R. Lambourne, “Paint composition and applications — a general introduction”, in Paint and Surface Coatings Theory and Practice, R. Lambourne and T. Strivens (Eds.), 2nd ed. Abington, Cambridge CB1 6AH, England: Woodhead Publishing Limited., 1999, ch. 1, pp. 1 – 18.

    Chapter  Google Scholar 

  18. M. D. Clark, “Paints and pigment”, (H. Wansbrough, Ed.), [The New Zeland Institute of Chemistry]. Available: https://nzic.org.nz/ChemProcesses/polymers/10D.pdf [Accessed: 28 February 2018].

  19. R. Woodridge, Principles of Paint Formulation. New York: Chapman and Hall, 1991, pp. 51–52.

    Book  Google Scholar 

  20. S. Tiwari and M. Saxena, “Use of fly ash in high performance industrial coating”, British Corrosion Journal, vol. 34, pp. 184–191, 1999.

    Article  CAS  Google Scholar 

  21. C. K. Anyiam and I. O. Igwe, “Studies on the use of an industrial waste clay in alkyd paint formulations”, International Journal of Academic Research, vol. 4, p. 306, 2012

    Google Scholar 

  22. I. O. Igwe and L. U. Ezeamaku, “The use of local clays in alkyd paint formulations”, Malysian PolymerJournal, vol. 5, pp. 81–94, 2010.

    Google Scholar 

  23. J. C. Miranda-Trevino and C. A. Coles, “Kaolinite properties, structure and influence of metal retention on pH”, Applied Clay Science, vol. 23, pp. 133–139, 2003.

    Article  CAS  Google Scholar 

  24. BASF the Chemical company. (2018) Performance minerals extenders for coatings and inks. [USA: BASF The Chemical Company]. Available: https://kaolin.basf.com/resources/downloads [Accessed: 15 July, 2018].

    Google Scholar 

  25. H. H. Murray. “Industrial applications of Kaolin”, Clay and Clay Minerals, vol. 10, no 1, pp. 291–298, 1961.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Umunakwe, I.J., Umunakwe, R., Popoola, V.A. et al. Evaluating the Extender Characteristics of Some Local Materials in Akure, Ondo State, Nigeria for Applications in the Paints Industry. MRS Advances 4, 2355–2365 (2019). https://doi.org/10.1557/adv.2019.258

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/adv.2019.258

Navigation