Skip to main content
Log in

Deposition routes of Cs2AgBiBr6 double perovskites for photovoltaic applications

  • Published:
MRS Advances Aims and scope Submit manuscript

Abstract

The lead free double perovskite Cs2AgBiBr6 is an upcoming alternative to lead based perovskites as absorber material in perovskite solar cells. So far, the majority of investigations on this interesting material have focused on polycrystalline powders and single crystals. We present vapor and solution based approaches for the preparation of Cs2AgBiBr6 thin films. Sequential vapor deposition processes starting from different precursors are shown and their weaknesses are discussed. Single source evaporation of Cs2AgBiBr6 and sequential deposition of Cs3Bi2Br9 and AgBr result in the formation of the double perovskite phase. Additionally, we show the possibility of the preparation of planar Cs2AgBiBr6 thin films by spin coating.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. Kojima, K. Teshima, Y. Shirai, and T. Miyasaka, J. Am. Chem. Soc. 131 6050–6051 (2009).

    CAS  Google Scholar 

  2. National Renewable Energy Laboratory (NREL) Efficiency Chart. Available at: https://www.nrel.gov/pv/assets/images/efficiency-chart.png (accessed 30 October 2017).

  3. T.M. Brenner, D.A. Egger, L. Kronik, G. Hodes, and D. Cahen, Nat. Rev. Mater. 1 15007 (2016).

    CAS  Google Scholar 

  4. J.H. Noh, S.H. Im, J.H. Heo, T.N. Mandal, and S.I. Seok, Nano. Lett. 13, 1764 (2013).

  5. S.D. Stranks, G.E. Eperon, G. Grancini, C. Menelaou, M.J.P. Alcocer, T. Leijtens, L.M. Herz, A. Petrozza, H.J. Snaith, Science 342, 341–344 (2013).

  6. R.E. Brandt, V. Stevanovic, D.S. Ginley, and T. Buonassisi, MRS Commun. 5, 265–275 (2015).

  7. I. Anusca, S. Balciunas, P. Gemeiner, S. Svirskas, M. Sanlialp, G. Lackner, C. Fettkenhauer, J. Belovickis, V. Samulionis, M. Ivanov, B. Dkhil, J. Banys, V.V. Shvartsman, and D.C. Lupascu, Adv. Energy Mater. 7, 1700600 (2017).

  8. C. Wehrenfennig, G.E. Eperon, M.B. Johnston, H.J. Snaith, and L.M. Herz, Adv. Mater. 26, 1584–1589 (2014).

  9. N. Aristidou, I. Sanchez-Molina, T. Chotchuangchutchaval, M. Brown, L. Martinez, T. Rath, and S.A. Haque, Angew. Chem., Int. Ed. 54, 8208–8212 (2015).

  10. A. Babayigit, A. Ethirajan, M. Muller, and B. Conings, Nat. Mater. 15, 247– 251 (2016).

  11. Zheng Zhang, Xiaowei Li, Xiaohong Xia, Zhuo Wang, Zhongbing Huang, Binglong Lei, and Yun Gao, J. Phys. Chem. Lett. 8 (17), 4300–4307 (2017).

  12. A.H. Slavney, Te Hu, A.M. Lindenberg, and H.I. Karunadasa, J. Am. Chem. Soc. 138 (7), 2138–2141 (2016).

  13. E.T. Mcclure, M.R. Ball, W. Windl, and P.M. Woodward, Chem. Mater. 28, 1348–1354 (2016).

  14. G. Volonakis, M.R. Filip, A.A. Haghighirad, N. Sakai, B. Wenger, H. J. Snaith, and F. Giustino, J. Phys. Chem. Lett. 7, 1254–1259 (2016).

  15. E. Greul, M.L. Petrus, A. Binek, P. Docampo, and T. Bein, J. Mater. Chem. A. 5, 19972 (2017).

  16. Z. Xiao, W. Meng, J. Wang, Y. Yan, ChemSusChem 9, 2628–2633 (2016)

    CAS  Google Scholar 

  17. I.M. Smallwood, Handbook of organic solvent properties (Arnold, London, 1996) p. 253.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pantaler, M., Fettkenhauer, C., Nguyen, H.L. et al. Deposition routes of Cs2AgBiBr6 double perovskites for photovoltaic applications. MRS Advances 3, 1819–1823 (2018). https://doi.org/10.1557/adv.2018.151

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/adv.2018.151

Navigation