Skip to main content
SpringerLink
Log in

New 1212-Molybdo-Cuprate phases using High pressure and high temperature synthesis

  • Published:
MRS Advances Aims and scope Submit manuscript

Abstract

New 1212- type Molybdo-Cuprates of with composition Mo0.5Cu0.5Sr2RECu2O7.5 (RE = Rare Earth) have been prepared by High Pressure and High Temperature (HPHT) synthesis. Their crystal structures are characterized by combining the X-Ray/Neutron powder diffraction and electron diffraction techniques. All the materials show tetragonal symmetry, crystallizing in the P4/mmm space group (S.G.). The chain oxygens are randomly distributed in the two different oxygen sites, which are not completely filled and the defect induced by oxygen vacancies in fact makes the chain fragmented and disordered. The microstructure of these compounds is interpreted by a well-known diagonal cell √2ap × √2ap × 3ap, as confirmed by the Electron diffraction (ED) and transmission electron microscope (TEM). X-ray photoelectron spectroscopy (XPS) studies show the predominance of the non magnetic MoVI state over the MoV one. At the same time oxidation state of copper is found to be dominated by CuII.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Tokura Y., Takagi H. and Uchida S. Nature 1989, 337, 345. See also: Alario-Franco M. A. Adv. Mater. 1994, 7(2), 229.

    Article  CAS  Google Scholar 

  2. Joshi D. G., Subbrarao M. V., Shah A. N., Kuberkar D. G. and Kulkarni R.G. Applied superconductivity 1998 6, 7–9, pp. 471–481.

    Article  CAS  Google Scholar 

  3. Bauernfeind L., Widder W. and Braun H. F. Physica C 1995, 254, 151–158.

    Article  CAS  Google Scholar 

  4. J. Lynn W., Keimer B., Ulrich C., Bernhard C., and Tallon J. L. Phys Rev. B. 2000, 61, R14964.

    Article  Google Scholar 

  5. Felner I., Asaf U., Reich S. and Tsabba Y. Physica C 1999, 311, 163.

    Article  CAS  Google Scholar 

  6. Pringle J. D., Tallon J. L., Walker B. G. and Trodahl H. J. Phys Rev. B. 1999, 59, R11679.

    Article  CAS  Google Scholar 

  7. Rukang L., Yingjie Z., Daoyuang Z., Chen X., Yitai Q., Zuyao C. and Guien Z. J. Alloy Compd. 1992, 185, 45.

    Article  Google Scholar 

  8. Mclaughlin A. C., Morrice D. and Sher F. J. Solid State Chem. 2005, 178, 2274.

    Article  CAS  Google Scholar 

  9. Adachi S., Kubo K –I., Takano S. and Yamauchi H. Physica C 1992, 191, 174.

    Article  CAS  Google Scholar 

  10. Eder M. H. and Gritzner G. Supercond. Sci. Technol. 2005, 18, 87.

    Article  CAS  Google Scholar 

  11. Dos santos-Garcia A. J., Aguirre M. H., Saez Puche R. and Alario-Franco M. A. J. Solid State Chem. 2006, 179, 1296.

    Article  CAS  Google Scholar 

  12. Dos santos-Garcia A. J., Van Duijn J. and Alario-Franco M. A. J. Solid State Chem. 2008, 181, 3317–3321.

    Article  CAS  Google Scholar 

  13. Takayama-Muromachi, E. Chem. Mater. 1998, 10, 2686.

    Article  CAS  Google Scholar 

  14. Ruiz-Bustos R., Gallardo-Amores J. M., Saez-Puche R.; Moran E. and Alario-Franco M. A. Physica C 2002, 382, 395–400.

    Article  CAS  Google Scholar 

  15. Ruiz-Bustos R., Aguirre M. H. and Alario-Franco, M. A. Inorg. Chem. 2005, 44, 3063–3069.

    Article  CAS  Google Scholar 

  16. Alario-Franco, M. A., Ruiz-Bustos R. and Dos santos-Garcia A. J. Inorg. Chem. 2008, 47, 6475–6481.

    Article  CAS  Google Scholar 

  17. Felner I. and Galstyan E. Phys. Rev. B 2004, 69, 024512.

    Article  CAS  Google Scholar 

  18. Balchev N., Nenkov K., Mihova G., Kunev B., Pirov J. and Dimitrov D. A. JMMM 2009, 321, 388–391.

    Article  CAS  Google Scholar 

  19. Marik S., Moran E., Labrugere C., Toulemonde O. and Alario-Franco M. A. J. Solid State Chem. 2012, 191, 40–45.

    Article  CAS  Google Scholar 

  20. Marik S., Dos santos-Garcia A. J., Moran E., Labrugere C., Toulemonde O. and Alario-Franco M. A. Supercond. Science and technology 2015, 28, 045007.

    Article  CAS  Google Scholar 

  21. Marik S., Moran E., Dos santos-Garcia A. J., Toulemonde O. and Alario-Franco M. A. JPCM. 2013, 25, 165704.

    Google Scholar 

  22. Marik S., Moran E., Dos santos-Garcia A. J., Toulemonde O. and Alario-Franco M. A. J Supercond Nov Magn 2013, 26, 1151–1154.

    Article  CAS  Google Scholar 

  23. Tsay H. L., Shih C. R., Chen Y. C., Lee W. H., Meen T. H. and Yang H. D. Physica C 1995, 252, 79–86.

    Article  CAS  Google Scholar 

  24. Tsay H. L., Chen Y. C., Weng S. S., Chang C. F. and Yang H. D. Phys. Rev. B 1999-I, 59, 636–640.

    Article  CAS  Google Scholar 

  25. Rodriguez-Carvajal J An introduction to the programme FULL-PROF, 2001, Labratoire Leon Brillouin, CEA-CNRS: Saclay, France.

    Google Scholar 

  26. William T. A., Harrison S. R., Vaughey J. T., Liu L. and Jacobson A. J. J. Solid State Chem. 1995, 119, 115–119.

    Article  Google Scholar 

  27. Antipov E. V., Abukamov A. M. and Putilin S. N. Supercond. Sci.Technol. 2002, 15, R31–R49.

    Article  CAS  Google Scholar 

  28. Putilin S. N., Antipov E. V., Chmaissem O. and Marezio M. Nature (London) 1993, 362, 226.

    Article  CAS  Google Scholar 

  29. Balagurov A. M., Sheptyakov D. V., Aksenov V. L., Antipov E. V., Putilin, S. N., Radaelli P. G. and Marezio M. Phys. ReV. B: Solid State 1999, 59(10) 7209.

    Article  CAS  Google Scholar 

  30. Shannon R. D. Acta Crystallogr. 1976, A 32, 751.

    Article  Google Scholar 

  31. Poole C., Creswick R. C. and Farach H. Handbook of Superconductivity; Elsevier: Amsterdam, 1999, p 136.

    Google Scholar 

  32. Vegas, A., Vallet-Regi M., Gonzalez-Calbet J. and Alario-Franco, M. A . Acta Crystallogr. 1986, B42, 167.

    Article  CAS  Google Scholar 

  33. Alario- Franco M. A., Vallet-Regi, M. and Gonzalez-Calbet, J. Cryst. Lattice Defects Amorphous Mater. 1987, 16, 387.

    CAS  Google Scholar 

  34. Alario- Franco M. A., Joubert J. C. and Levi J. P. Mater. Res. Bull. 1982, 21, 733.

    Article  Google Scholar 

  35. Alario-Franco M. A., Henche M. J. R., Vallet M., Calbet J. M., Grenier J. C., Wattiaux, A. and Hagenmuller P. J. Solid State Chem. 1983, 46, 23–40.

    Article  CAS  Google Scholar 

  36. Aguirre M., Ruiz-Bustos R. and Alario-Franco M. A. J. Mater. Chem. 2003, 13, 1156–1160.

    Article  CAS  Google Scholar 

  37. Garcia-Martin S., Alario-Franco M. A., Ehrenberg H. and Amador U. J. Am. Chem. Soc. 2004. 224 3587.

    Article  CAS  Google Scholar 

  38. Hiena T. D., Mana N. K. and Gargb K.B. JMMM. 2003, 262, 508–513

    Article  CAS  Google Scholar 

  39. Katrib A., Logie V., Peter M., Wehrer P., Hilaire L. and Maire G. J. Chim. Phys. Phys.-Chim. Biol. 1997, 94, 1923.

    Article  CAS  Google Scholar 

  40. Jalili H., Heinig N. F. and Leung K. T. Phys. Rev. B 2009, 79, 174427.

    Article  CAS  Google Scholar 

  41. Larsson S. Chem. Phys. Lett. 1976, 40, 362.

    Article  CAS  Google Scholar 

  42. Van der Laan G., Westra C., Haas C. and Sawatzky G. A. Phys. Rev. B 1981, 23, 4369.

    Article  Google Scholar 

  43. Parmigiani F. and Sangaletti L. J. Electron Spectrosc. Relat. Phenom.1994, 66, 223.

    Article  CAS  Google Scholar 

  44. Vasquez R. P., Novikov D. L., Freeman A. J. and Siegal M. P. Phys. Rev. B 1997-I, 55, 21.

    Article  Google Scholar 

  45. Parmigiani F., Depero L. E., Minerva T. and Torrance J. B. J. Electron Spectrosc. Relat. Phenom. 1992, 58, 315.

    Article  CAS  Google Scholar 

  46. Parmigiani F. and Sangaletti L. J. Electron Spectrosc. Relat. Phenom. 1994, 66, 223.

    Article  CAS  Google Scholar 

  47. Parmigiani F., Pacchioni G., Illas F. and P.S. Bagus J. Electron Spectrosc. Relat. Phenom. 1992, 59, 255.

    Article  CAS  Google Scholar 

  48. Parmigiani F., Shen Z. X., Mitzi D. B., Lindau I., Spicer W.E. and Kapitulnik A. Phys. Rev. B 1991, 43, 3085.

    Article  CAS  Google Scholar 

  49. Fink J., Niicker N., PeUegrin E., Romberg H., Alexander M. and Knupfer M. J. Electron Spectrosc. Relat. Phenom. 1994, 66, 395.

    Article  CAS  Google Scholar 

  50. Martinho H., Martin A. A., Moreno N. O., Sanjurjo J. A., Rettori C., Oseroff S. B., Fisk Z., Pagliuso P. G. and Sarrao J. L. Physica B 2001, 305, 48–55.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dpto. Química Inorgánica Facultad de CC.Químicas, Universidad Complutense de Madrid, 28040, Madrid, Spain

    Sourav Marik, A. J. Dos santos-Garcia, Emilio Morán, O. Toulemonde & M. A. Alario-Franco

  2. CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr. A. Schweitzer, F-33608, Pessac, France

    Sourav Marik & O. Toulemonde

  3. Dpto. Química Industrial y Polímeros E. U. I. T. I, Universidad Politécnica de Madrid, 28012, Madrid, Spain

    A. J. Dos santos-Garcia

Authors
  1. Sourav Marik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. J. Dos santos-Garcia
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Emilio Morán
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. Toulemonde
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. A. Alario-Franco
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. A. Alario-Franco.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Marik, S., Dos santos-Garcia, A., Morán, E. et al. New 1212-Molybdo-Cuprate phases using High pressure and high temperature synthesis. MRS Advances 1, 1215–1225 (2016). https://doi.org/10.1557/adv.2016.138

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/adv.2016.138

Search

Navigation