Skip to main content
SpringerLink
Log in

Particle-Loaded Monolithic Materials for Separations via Planar Electrochromatography

  • Original Research Papers
  • Published:
JPC – Journal of Planar Chromatography – Modern TLC Aims and scope Submit manuscript

Summary

The synthesis and characterization of novel stationary phases for analytical applications as well as for planar electrochromatography are presented. The stationary phases are C8-functionalized silica-based monoliths, which are supported by silica particles in order to avoid shrinkage and to increase mechanical stability. After optimizing the separation conditions in capillaries for capillary electrochromatography (CEC), the novel materials were implemented in a planar test cell and tested for the electrochromatochraphic separation of polyaromatic hydrocarbons (PAHs). Although the change of geometries implied a scale-up of the filling procedure, high separation performances with theoretical plate numbers of up to 30,000 m−1 and throughputs of 50 mL h−1 could be achieved.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. Nurok, J. Chromatogr. A 1044 (2004) 83–96.

    Article  CAS  Google Scholar 

  2. T. Dzido, P. Plocharz, P. Slazak, A. Halka, Anal. Bioanal. Chem. 391 (2008) 2111–2118.

    Article  CAS  Google Scholar 

  3. A. Halka-Grysnska, P. Plocharz, E. Skwarek, W. Janusz, T. Dzido, J. Planar Chromatogr. 28 (2015) 133–138.

    Article  Google Scholar 

  4. D. Nurok, J. Koers, M. Carmichael, W.m. Liao, T. Dzido, J. Planar Chromatogr. 15 (2002) 320–323.

    Article  CAS  Google Scholar 

  5. Y. Cui, Z. Ge, D. Wang, B. Yuan, J. Planar Chromatogr. 23 (2010) 426–433.

    Article  CAS  Google Scholar 

  6. A. Halka, P. Plocharz, A. Torbicz, T. Dzido, J. Planar Chromatogr. 23 (2010) 420–425.

    Article  CAS  Google Scholar 

  7. J. Sherma, Anal. Chem. 82 (2010) 4895–4910.

    Article  CAS  Google Scholar 

  8. R. Laskowski, H.J. Bart, H. Gruber-Wölfler, P. Feenstra, M.G. Braunbruck, J. Khinast, Procedia Eng. 42 (2012) 1611–1623.

    Article  Google Scholar 

  9. T.H. Dzido, P.W. Plocharz, P. Slazak, Anal. Chem. 78 (2006) 4713–4721.

    Article  CAS  Google Scholar 

  10. P.A. Tate, J.G. Dorsey, J. Chromatogr. A 1079 (2005) 317–327.

    Article  CAS  Google Scholar 

  11. A. Walcarius, M.M. Collinson, Annu. Rev. Anal. Chem. 2 (2009) 121–143.

    Article  CAS  Google Scholar 

  12. P.A. Tate, J.G. Dorsey, J. Chromatogr. A 1103 (2006) 150–157.

    Article  CAS  Google Scholar 

  13. R. Laskowski, H.J. Bart, Chem. Eng. Technol. 36 (2013) 950–958.

    Article  CAS  Google Scholar 

  14. D. Allen, Z. El Rassi, Electrophoresis 24 (2003) 408–420.

    Article  CAS  Google Scholar 

  15. D. Allen, Z. El Rassi, Electrophoresis 24 (2003) 3962–3976.

    Article  CAS  Google Scholar 

  16. N. Deng, Y.z. He, L. Wang, X.k. Wang, Q.d. Su, Anal. Chem. 77 (2005) 5622–5627.

    Article  CAS  Google Scholar 

  17. M. Wu, R. Wu, Z. Zhang, H. Zou, Electrophoresis 32 (2011) 105–115.

    Article  Google Scholar 

  18. M.T. Dulay, R.P. Kulkarni, R.N. Zare, Anal. Chem. 70 (1998) 5103–5107.

    Article  CAS  Google Scholar 

  19. Q.S. Qu, X.Q. Tang, C.Y. Wang, G.J. Yang, X.Y. Hu, X. Lu, Y. Liu, C. Yan, J. Sep. Sci. 29 (2006) 2098–2102.

    Article  CAS  Google Scholar 

  20. L.A. Colon, G. Burgos, T.D. Maloney, J.M. Cintron, R.L. Rodriguez, Electrophoresis 21 (2000) 3965–3993.

    Article  CAS  Google Scholar 

  21. G. Guiochon, J. Chromatogr. A 1168 (2007) 101–168.

    Article  CAS  Google Scholar 

  22. A. Maruska, O. Kornysova, J. Biochem. Biophys. Methods 59 (2004) 1–48.

    Article  CAS  Google Scholar 

  23. A.L. Novotny, D. Nurok, R.W. Replogle, G.L. Hawkins, R.E. Santini, Anal. Chem. 78 (2006) 2823–2831.

    Article  CAS  Google Scholar 

  24. S.D. Woodward, I. Urbanova, D. Nurok, F. Svec, Anal. Chem. 82 (2010) 3445–3448.

    Article  CAS  Google Scholar 

  25. Y. Han, P. Levkin, I. Abarientos, H. Liu, F. Svec, J.M.J. Frechet, Anal. Chem. 82 (2010) 2520–2528.

    Article  CAS  Google Scholar 

  26. G.S. Ding, Z.L. Da, R.J. Yuan, J.J. Bao, Electrophoresis 27 (2006) 3363–3372.

    Article  CAS  Google Scholar 

  27. J.D. Hayes, A. Malik, Anal. Chem. 72 (2000) 4090–4099.

    Article  CAS  Google Scholar 

  28. M.H. Wu, R.A. Wu, Z.B. Zhang, H.F. Zou, Electrophoresis 32 (2011) 105–115.

    Article  Google Scholar 

  29. L.J. Yan, Q.H. Zhang, H. Zhang, L.Y. Zhang, T. Li, Y.Q. Feng, L.H. Zhang, W.B. Zhang, Y.K. Zhang, J. Chromatogr. A 1046 (2004) 255–261.

    Article  CAS  Google Scholar 

  30. Speed and Performance in Monolithic Form.Chromolith® HPLC Columns, https://www.vwrsp.com/literature/products/pdf/05420_chromatography.pdf, accessed June 15th 2015 (2010).

  31. L.J. Yan, Q.H. Zhang, Y.Q. Feng, W.B. Zhang, T. Li, L.H. Zhang, Y.K. Zhang, J. Chromatogr. A 1121 (2006) 92–98.

    Article  CAS  Google Scholar 

  32. M.-G. Braunbruck, PhD Thesis, Graz University of Technology, 2013.

  33. K. Sing, J. Porous Mater. 2 (1995) 5–8.

    Article  CAS  Google Scholar 

  34. Q. Tang, N. Wu, M.L. Lee, J. Microcolumn Sep. 12 (2000) 6–12.

    Article  CAS  Google Scholar 

  35. M.M. Zheng, B. Lin, Y.Q. Feng, J. Chromatogr. A 1164 (2007) 48–55.

    Article  CAS  Google Scholar 

  36. M. Ruike, M. Houzouji, A. Motohashi, N. Murase, A. Kinoshita, K. Kaneko, Langmuir 12 (1996) 4828–4831.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Process and Particle Engineering, Graz University of Technology, Inffeldgasse 13, A-8010, Graz, Austria

    Heidrun Gruber-Woelfler, Marie G. Braunbruck, Peter W. Feenstra & Johannes G. Khinast

  2. Chair of Separation Science and Technology, Technische Universität Kaiserslautern, PF 3049, 67653, Kaiserslautern, Germany

    Rene Laskowski & Hans-Jörg Bart

Authors
  1. Heidrun Gruber-Woelfler
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Marie G. Braunbruck
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Rene Laskowski
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Peter W. Feenstra
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Johannes G. Khinast
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Hans-Jörg Bart
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Heidrun Gruber-Woelfler.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gruber-Woelfler, H., Braunbruck, M.G., Laskowski, R. et al. Particle-Loaded Monolithic Materials for Separations via Planar Electrochromatography. JPC-J Planar Chromat 29, 15–21 (2016). https://doi.org/10.1556/1006.2016.29.1.2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1556/1006.2016.29.1.2

Key Words

Search

Navigation