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Preparation and Electrochemical Properties of Heterogeneous Bipolar Membranes with a Catalyst for the Water Dissociation Reaction

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Abstract

A method for producing an aMB-2m heterogeneous bipolar membrane modified with a KF-1 catalyst with phosphoric acid groups is developed. A mathematical model is proposed for describing the current–voltage characteristics of the modified heterogeneous membranes. The electrochemical characteristics of the produced aMB-2m membrane and a commercial MB-3 heterogeneous bipolar membrane are studied by impedance spectroscopy. The electrodialysis process of recovery of sulfuric acid and sodium hydroxide from a solution of sodium sulfate in electrodialyzers with a modified aMB-2m bipolar membrane and an MB-3 membrane is studied. The use of a modified aMB-2m bipolar membrane in the electrodialyzer makes it possible to obtain solutions with higher concentrations of sulfuric acid and sodium hydroxide and lower concentrations of salt ions in the acid and alkali compared to the use of a commercial MB-3 heterogeneous bipolar membrane.

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Funding

This study was financially supported by the Kuban Science Foundation within scientific project no. MFI-20.1/124 (agreement no. MFI-20.1-27/20).

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Authors and Affiliations

  1. Kuban State University, 350040, Krasnodar, Russia

    N. V. Kovalev, T. V. Karpenko, N. V. Sheldeshov & V. I. Zabolotsky

Authors
  1. N. V. Kovalev
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  2. T. V. Karpenko
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  3. N. V. Sheldeshov
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  4. V. I. Zabolotsky
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Corresponding author

Correspondence to N. V. Sheldeshov.

Additional information

Translated by E. Boltukhina

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Kovalev, N.V., Karpenko, T.V., Sheldeshov, N.V. et al. Preparation and Electrochemical Properties of Heterogeneous Bipolar Membranes with a Catalyst for the Water Dissociation Reaction. Membr. Membr. Technol. 3, 231–244 (2021). https://doi.org/10.1134/S251775162104003X

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  • DOI: https://doi.org/10.1134/S251775162104003X

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