Abstract
By means of the X-ray microspectral analysis and scanning and transmission electron microscopy, we investigate the composition of hardening phase particles—nitrides—after internal nitriding and subsequent heat treatment in the Ni–Co–Cr–W–Ti system of grade VZh171. The particles differ significantly in chemical composition: the main forming element—titanium or chromium—is proportionally replaced by the other alloy components. The nitride compositions at the surface and in the center of the sample differ in the element ratio. After annealing in vacuum, the content of chromium, tungsten, and cobalt in nitrides decreases, also less becomes the difference in the precipitate composition in the surface and the central layers of the sample; this phenomenon can be used to improve the alloy properties.
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Funding
This study is supported by the Russian Foundation for Basic Research, project no. 18-02-00760 in the study of the kinetics of particle growth in a nitrided alloy during isothermal annealing, and within the State Assignment, reg. no. AAAA-A19-119100800130-0, in the study of the heat-resistant alloy microstructure.
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Ovsepyan, S.V., Kolobov, Y.R., Akhmedzyanov, M.V. et al. Investigation of the Nitride Phase in a Heat-Resistant VZh171 Alloy of the Ni–Co–Cr–W–Ti System, Hardened by Internal Nitriding. Inorg. Mater. Appl. Res. 13, 828–834 (2022). https://doi.org/10.1134/S2075113322030297
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DOI: https://doi.org/10.1134/S2075113322030297