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Composites Based on Isotactic Polypropylene and High-Pressure Polyethylene with Zinc-Containing Nanofillers

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Inorganic Materials: Applied Research Aims and scope

Abstract

The effect of nanofiller (NF) additives containing zinc oxide nanoparticles stabilized by a polymer matrix of high pressure polyethylene obtained by the mechanochemical method on the structure and properties of metal-containing nanocomposites based on isotactic polypropylene (PP) and high pressure polyethylene (PE) using differential thermal (DTA) and X-ray phase (XRD) analyses was studied. The improvement of strength, deformation, and rheological parameters, as well as thermal-oxidative stability of the obtained nanocomposites, was revealed, which, apparently, is associated with the synergistic effect of interfacial interaction of zinc-containing nanoparticles in the PE matrix with the components of the PP/PE polymer composition. It is shown that nanocomposites based on PP/PE/NF can be processed both by the pressing method and by the injection molding and extrusion methods, which expands the scope of its application.

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Authors and Affiliations

  1. Institute of Polymer Materials, Azerbaijan National Academy of Sciences, AZ5004, Sumgait, Azerbaijan

    N. I. Kurbanova, S. K. Ragimova, N. A. Alimirzoeva, N. Ya. Ishenko & V. V. Medyakov

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  1. N. I. Kurbanova
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  2. S. K. Ragimova
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  3. N. A. Alimirzoeva
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  4. N. Ya. Ishenko
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  5. V. V. Medyakov
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Correspondence to N. I. Kurbanova.

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The effect of a zinc oxide nanofiller stabilized by a high-pressure polyethylene matrix, obtained by a mechanochemical method, on the properties of composites based on PP/PE was investigated.

XRD patterns confirm the presence of zinc oxide nanoparticles in the composites based on PP/PE.

An improvement in the strength, deformation, and rheological parameters, as well as the thermal-oxidative stability of the obtained nanocomposites, has been revealed.

It is shown that nanocomposites based on PP/PE/NN can be processed both by pressing and by injection molding and extrusion.

It has been shown that it is promising to use as an additive to PP/PE a nanofiller containing NPs of zinc oxides stabilized by a matrix of high-pressure polyethylene, obtained by a mechanochemical method, which contributes to the creation of a fine-crystalline structure of the composition, in connection with which its properties are improved and, thus, the fields of application of the obtained nanocomposite are expanded.

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Translated by M. Drozdova

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Kurbanova, N.I., Ragimova, S.K., Alimirzoeva, N.A. et al. Composites Based on Isotactic Polypropylene and High-Pressure Polyethylene with Zinc-Containing Nanofillers. Inorg. Mater. Appl. Res. 13, 485–488 (2022). https://doi.org/10.1134/S2075113322020253

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  • DOI: https://doi.org/10.1134/S2075113322020253

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