Skip to main content
SpringerLink
Log in

Analysis of CH4 Adsorption Isotherms onto MIL-101 (Cr) Metal-Organic Framework and Its Derivatives with Alkali Ion Dopants

  • PHYSICOCHEMICAL PROCESSES AT THE INTERFACES
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

In this paper, methane (CH4) adsorption isotherms for metal-organic framework (MOF) adsorbents in the subcritical regions have been reported. Virgin MIL i-101 i-i (Cr) MOF and its derivatives doped with alkali ions, are used to study the impact of alkali dopants on CH4 adsorption isotherms. The CH4 adsorption isotherms have been analyzed by Langmuir, Toth and Dubinin–Astakohv adsorption models to determine the adsorption parameters. It has been observed that the isosteric heat of adsorption diminishes with increasing alkali dopant size, while the induced surface structural heterogeneity increases with increasing alkali dopant size.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Konstas, K., Osl, T., Yang, Y., Batten, M., Burke, N., and Hill, A.J., J. Mater. Chem., 2012, vol. 22, p. 16698.

    Article  CAS  Google Scholar 

  2. Thamsiriroj, T., Smyth, H., and Murphy, J.D., Renewable Sustainable Energy Rev., 2011, vol. 15, p. 4642.

    Article  CAS  Google Scholar 

  3. He, Y., Zhou, W., Qian, G., and Chen, B., Chem. Soc. Rev., 2014, vol. 43, p. 5657.

    Article  CAS  Google Scholar 

  4. Waller, M.G., Williams, E.D., Matteson, S.W., and Trabold, T.A., Appl. Energy, 2014, vol. 127, p. 55.

    Article  Google Scholar 

  5. Banfield, G.R. and Fairbairn, G.W., Proc. Inst. Mech. Eng., Part E, 1990, vol. 204, p. 25.

    Google Scholar 

  6. Nwaoha, T.C., Yang, Z., Wang, J., and Bonsall, S., Proc. Inst. Mech. Eng., Part E, 2010, vol. 225, p. 40.

    Google Scholar 

  7. Ma, S. and Zhou, H.C., Chem. Commun., 2010, vol. 46, p. 44.

    Article  CAS  Google Scholar 

  8. Li, J.R., Kuppler, R.J., and Zhou, H.C., Chem. Soc. Rev., 2009, vol. 38, p. 1477.

    Article  CAS  Google Scholar 

  9. Menon, V.C. and Komarneni, S., J. Porous Mater., 1998, vol. 5, p. 43.

    Article  CAS  Google Scholar 

  10. Ruthven, D.M., Principles of Adsorption and Adsorption Processes, New York: Wiley, 1984.

    Google Scholar 

  11. Alcaniz-Monge, J., Lozano-Castello, D., Cazorla-Amoros, D., and Linares-Solano, A., Microporous Mesoporous Mater., 2009, vol. 124, p. 110.

    Article  CAS  Google Scholar 

  12. Wegrzyn, J. and Gurevich, M., Appl. Energy, 1996, vol. 55, p. 71.

    Article  CAS  Google Scholar 

  13. Mason, J.A., Veenstra, M., and Long, J.R., Chem. Sci., 2014, vol. 5, p. 32.

    Article  CAS  Google Scholar 

  14. He, Y., Zhou, W., Krishna, R., and Chen, B., Chem. Commun., 2012, vol. 48, p. 11813.

    Article  CAS  Google Scholar 

  15. Lee, J.S., Jhung, S.H., Yoon, J.W., Hwang, Y.K., and Chang, J.S., J. Ind. Eng. Chem., 2009, vol. 15, p. 674.

    Article  CAS  Google Scholar 

  16. Peng, Y., Krungleviciute, V., Eryazici, I., Hupp, J.T., Farha, O.K., and Yildirim, T., J. Am. Chem. Soc., 2013, vol. 135, p. 11887.

    Article  CAS  Google Scholar 

  17. Duren, T., Sarkisov, L., Yaghi, O.M., and Snurr, R.Q., Langmuir, 2004, vol. 20, p. 2683.

    Article  Google Scholar 

  18. Knyazeva, M.K., Tsivadze, A.Yu., Solovtsova, O.V., Fomkin, A.A., Pribylov, A.A., Shkolin, A.V., et al., Prot. Met. Phys. Chem. Surf., 2019, vol. 55, p. 9.

    Article  CAS  Google Scholar 

  19. Knyazeva, M.K., Tsivadze, A.Yu., Fomkin, A.A., Shkolin, A.V., Solovtsova, O.V., Pribylov, A.A., et al., Prot. Met. Phys. Chem. Surf., 2020, vol. 56, p. 682.

    Article  Google Scholar 

  20. Fomkin, A.A., Tsivadze, A.Yu., Aksyutin, O.E., Ishkov, A.G., Pribylov, A.A., Shkolin, A.V., et al., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, p. 347.

    Article  CAS  Google Scholar 

  21. Matranga, K.R., Myers, A.L., and Glandt, E.D., Chem. Eng. Sci., 1992, vol. 47, p. 1569.

    Article  CAS  Google Scholar 

  22. Anuchin, K.M., Fomkin, A.A., Korotych, A.P., and Tolmachev, A.M., Prot. Met. Phys. Chem. Surf., 2014, vol. 50, p. 173.

    Article  CAS  Google Scholar 

  23. Kayal, S., Sun, B., and Chakraborty, A., Energy, 2015, vol. 91, p. 772.

    Article  CAS  Google Scholar 

  24. Aijaz, A., Karkamkar, A., Choi, Y.J., Tsumori, N., Ronnebro, E., Autrey, T., et al., J. Am. Chem. Soc., 2012, vol. 134, p. 13926.

    Article  CAS  Google Scholar 

  25. Sun, B., Chakraborty, A., Ali, S.M., and Kayal, S., Appl. Therm. Eng., 2016, vol. 93, p. 1175.

    Article  CAS  Google Scholar 

  26. Sircar, S., Adsorption, 2017, vol. 23, p. 121.

    Article  CAS  Google Scholar 

  27. Loh, W.S., Rahman, K.A., Chakraborty, A., Saha, B.B., Choo, Y.S., Khoo, B.C., et al., J. Chem. Eng. Data, 2010, vol. 55, p. 2840.

    Article  CAS  Google Scholar 

  28. Rahman, K.A., Loh, W.S., Yanagi, H., Chakraborty, A., Saha, B.B., Chun, W.G., et al., J. Chem. Eng. Data, 2010, vol. 55, p. 4961.

    Article  CAS  Google Scholar 

  29. Do, D.D., Adsorption Analysis: Equilibria and Kinetics, London: Imperial College Press, 1998.

    Book  Google Scholar 

  30. Dubinin, M.M., Chem. Rev., 1960, vol. 60, p. 235.

    Article  CAS  Google Scholar 

  31. Abdulsalam, J., Mulopo, J., Bada, S.O., and Oboirien, B., ACS Omega, 2020, vol. 5, p. 32530.

    Article  CAS  Google Scholar 

  32. Aristov, Y., Appl. Therm. Eng., 2014, vol. 72, p. 166.

    Article  Google Scholar 

  33. Jagiello, J. and Thommesi, M., Carbon, 2004, vol. 42, p. 1227.

    Article  CAS  Google Scholar 

  34. Amankwah, K.A.G. and Schwarz, J.A., Carbon, 1995, vol. 33, p. 1313.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Centre for Sustainable Technology and Product Development, Department of Metallurgical and Materials Engineering, School of Engineering, O. P. Jindal University (OPJU), 496109, Punjipathra, Raigarh, India

    Ayushi Singh & Sibnath Kayal

Authors
  1. Ayushi Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Sibnath Kayal
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sibnath Kayal.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Singh, A., Kayal, S. Analysis of CH4 Adsorption Isotherms onto MIL-101 (Cr) Metal-Organic Framework and Its Derivatives with Alkali Ion Dopants. Prot Met Phys Chem Surf 58, 478–485 (2022). https://doi.org/10.1134/S2070205122030200

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205122030200

Keywords:

Search

Navigation