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Magnetic Properties of Fe + Ni-Containing TiO2-Layer/Ti Composites

  • NANOSCALE AND NANOSTRUCTURED MATERIALS AND COATINGS
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Abstract

Oxide layers on titanium have been formed via the method of plasma electrolytic oxidation (PEO) in electrolyte–suspensions containing colloidal particles of iron and nickel hydroxides with a ratio of Fe3+/Ni2+ = 3 : 1 for 5–15 min. The average concentrations of iron, nickel, and titanium in the composition of the coatings were 6.1, 2.2, and 3.5 at %, respectively. For all the composites, the values of coercive force Hс at 300 K did not exceed 59 Oe, which can be attributed to soft magnetic materials. At 2 K, an increase of the magnetization values and a significant increase of Hc up to 496–679 Oe have been observed for all the samples. It has been hypothesized that the contribution to the magnetic behavior of the samples at room temperature is made by the bulk of coatings, whereas at helium temperature it was the contribution of microsized formations with an increased content of iron and nickel found in the pores. Increasing the duration of the PEO process up to 15 min leads to a decrease of Hс values by almost 100 Oe at 2 K, which can result from a decrease of the proportion of iron in the composition of crystallites and the appearance of spherical particles with an increased concentration of phosphorus, titanium, and oxygen in the pores. It has been established that, after long-term storage of the samples in air, the coercive force measured at 2 K decreased by almost twice, which could have been the result of the oxidation of metallic Fe+Ni-containing particles localized in open pores on the coating surface.

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Funding

The synthesis of composites and the study of their phase, elemental composition, and magnetic characteristics was carried out in the framework of a State Order to the Institute of Chemistry of the Far East Branch of the Russian Academy of Sciences, project no. FWFN(0205)-2022-0001.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    M. V. Adigamova, I. V. Lukiyanchuk, I. A. Tkachenko & V. P. Morozova

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  1. M. V. Adigamova
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  2. I. V. Lukiyanchuk
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  3. I. A. Tkachenko
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  4. V. P. Morozova
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Correspondence to M. V. Adigamova.

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Translated by D. Marinin

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Adigamova, M.V., Lukiyanchuk, I.V., Tkachenko, I.A. et al. Magnetic Properties of Fe + Ni-Containing TiO2-Layer/Ti Composites. Prot Met Phys Chem Surf 58, 510–518 (2022). https://doi.org/10.1134/S2070205122030029

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