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Electrochemical Study of Corrosion Inhibition Behavior of Dehydroabietylamine Against Mild Steel in 1 M HCl

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Abstract

Using potentiodynamic polarization technique, this study analyzed the corrosion inhibitory effect of dehydroabietylamine (DHAA) against mild steel in 1 M HCl. The inhibitor concentration and temperature effects were studied as well. According to these results, the efficiency of inhibition increased with the increase in the concentration of corrosion inhibitor and declined when the temperature increased. A calculation was made to determine the activation and kinetic parameters of the corrosion reaction and adsorption. The inhibitor surficial adsorption on the mild steel followed the Frumkin adsorption isotherm. A physical adsorption mechanism was suggested given the activation energy Ea and Gibbs free energy of adsorption \(\Delta G_{{{\text{ads}}}}^{^\circ }\) values. Atomic force microscopy (AFM) and energy-dispersive X-ray spectroscopy (EDX) techniques were used to investigate the mild steel surface after and before being exposed to 1 M HCl in absence/presence of an inhibitor.

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ACKNOWLEDGMENTS

Authors would like to acknowledge Young Researchers and Elites Club, North Tehran Branch, Islamic Azad University, Tehran, Iran for providing experimental facilitates.

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Authors and Affiliations

  1. Young Researchers and Elites Club, North Tehran Branch, Islamic Azad University, Tehran, Iran

    S. H. Ettefagh Far

  2. Technology Team, Battery Energy Power Solutions Pty Ltd, 2165, Fairfield, NSW, Australia

    M. Glenn

  3. Materials and Metallurgical Engineering Department, Faculty of Engineering, Ferdowsi University of Mashhad (FUM), Mashhad, Iran

    A. Davoodi

  4. Electrochemistry and Inhibitors Group, Environmental Protection Department, Research Institute of Petroleum Industry (RIPI), Tehran, Iran

    A. Rahimi

Authors
  1. S. H. Ettefagh Far
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  2. M. Glenn
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  3. A. Davoodi
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  4. A. Rahimi
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Correspondence to S. H. Ettefagh Far.

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Ettefagh Far, S.H., Glenn, M., Davoodi, A. et al. Electrochemical Study of Corrosion Inhibition Behavior of Dehydroabietylamine Against Mild Steel in 1 M HCl. Prot Met Phys Chem Surf 58, 190–199 (2022). https://doi.org/10.1134/S2070205122010099

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  • DOI: https://doi.org/10.1134/S2070205122010099

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