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Chemical Composition and Mechanical Properties of Coatings Based on TiN Formed Using a Condensation with Ion Bombardment

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Abstract

The morphology, composition, and chemical state of coating elements based on titanium nitride (TiN) formed by the method of condensation with ion bombardment at different modes on Hadfield steel substrates (110G13L grade) have been studied by the methods of SEM, EDX, and XPS. It has been established that, in the formed coatings, the highest titanium content was in the composition of nitride and oxynitride, whereas there was also a certain amount of titanium and titanium oxides chemically bonded to carbon. It has been shown that titanium in the metallic state was absent for all the studied modes of coating formation and, therefore, the drop macrofraction formation did not proceed at these conditions. XPS layer-by-layer analysis demonstrated that coatings had a heterogeneous composition over depth. The microhardness of samples was studied by the Vickers test. The highest microhardness values were observed for the samples with coatings formed for 35 and 50 min, presumably as the result of higher content of compounds of the TiNxCyOz type with higher hardness than that of TiN.

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ACKNOWLEDGMENTS

The authors are grateful to K. Ivlev, a colleague at the Omsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, for carrying out research of samples by the SEM method, and also to the management of Omsk Regional Core Facility Center of Siberian Branch of the Russian Academy of Sciences for providing the equipment for the study of samples by SEM and EDX methods.

Funding

This work was partially supported by research project of Omsk State Technical University no. 19074B (in the part of the study of the coating formed at 15 min) and by the Ministry of Education and Science of the Russian Federation as part of a state order, project no. 0806-2018-0012.

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Authors and Affiliations

  1. Omsk State Technical University, 644050, Omsk, Russia

    P. M. Korusenko, S. N. Nesov & S. N. Povoroznyuk

  2. Omsk Scientific Center, Siberian Branch, Russian Academy of Sciences, 644024, Omsk, Russia

    S. N. Povoroznyuk

  3. Siberian State Automobile and Highway University, 644080, Omsk, Russia

    P. V. Orlov, D. N. Korotaev & K. N. Poleshchenko

Authors
  1. P. M. Korusenko
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  2. S. N. Nesov
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  3. S. N. Povoroznyuk
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  4. P. V. Orlov
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  5. D. N. Korotaev
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  6. K. N. Poleshchenko
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Corresponding author

Correspondence to P. M. Korusenko.

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Translated by D. Marinin

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Korusenko, P.M., Nesov, S.N., Povoroznyuk, S.N. et al. Chemical Composition and Mechanical Properties of Coatings Based on TiN Formed Using a Condensation with Ion Bombardment. Prot Met Phys Chem Surf 56, 539–548 (2020). https://doi.org/10.1134/S2070205120030193

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  • DOI: https://doi.org/10.1134/S2070205120030193

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