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Temperature Dependence of Luminescent Properties of a Novel Rhodium(III) Crown-Porphyrinate in Polysterene Matrix

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Abstract

In the interaction of tetra-15-crown-5-porphyrin (H2TCP) with rhodium(III) chloride in benzonitrile, the corresponding rhodium(III) porphyrinate (RhCl-TCP) containing a chloride ion as an axial anion in the Rh3+ cation coordination sphere was obtained and isolated. The structure of the obtained compound was determined based on the data of 1H NMR spectroscopy, electronic absorption spectroscopy, and mass spectrometry. The luminescent characteristics of RhCl-TCP in a polymer matrix (polystyrene) were analyzed at temperatures of 298 and 77 K. It was found that the resulting complex can be considered as a luminescent sensor for temperature determination based on a change in the ratio of the phosphorescence and fluorescence intensities, as well as a change in the phosphorescence lifetime with temperature changing.

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ACKNOWLEDGMENTS

MALDI TOF mass spectra, electronic absorption spectra, 1H NMR spectra, and luminescence spectra were measured on instruments of the Center of Collective Use of the Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences.

Funding

This work was financially supported by Program of Basic Research of the Presidium of the Russian Academy of Sciences no. 34 “Topical Problems of Surface Physical Chemistry and Development of New Composite Materials.”

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    A. Yu. Chernyad’ev, V. A. Kotenev & A. Yu. Tsivadze

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  1. A. Yu. Chernyad’ev
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  2. V. A. Kotenev
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  3. A. Yu. Tsivadze
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Correspondence to A. Yu. Chernyad’ev.

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Translated by G. Levit

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Chernyad’ev, A.Y., Kotenev, V.A. & Tsivadze, A.Y. Temperature Dependence of Luminescent Properties of a Novel Rhodium(III) Crown-Porphyrinate in Polysterene Matrix. Prot Met Phys Chem Surf 55, 1113–1117 (2019). https://doi.org/10.1134/S2070205119060066

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  • DOI: https://doi.org/10.1134/S2070205119060066

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