Skip to main content
SpringerLink
Log in

Excess and Absolute Adsorption from Binary Liquid Solution by Microporous Crystalline Adsorbents: Cumene + n-Octane/Zeolite NaX

  • PHYSICOCHEMICAL PROCESSES AT THE INTERFACES
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

The excess adsorption isotherms of cumene from solutions in n-octane in zeolite NaX have been measured at 303.15, 338.15 and 363.15 K using the conventional static method. The absolute (limiting) adsorption values of the pure components have been measured by the pycnometric method. The absolute adsorption isotherms for the system have been calculated using a non-fitting three parameter equation, based on the modified Dubinin–Radushkevich one. The detailed derivation of the formulas for these calculations is given. The absolute adsorption data are then used for estimation of average adsorbate density and other characteristics of the adsorbed phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.
Fig. 10.
Fig. 11.

Similar content being viewed by others

REFERENCES

  1. Larionov, O.G. and Yakubov, E.S., Zh. Fiz. Khim., 1995, vol. 69, no. 7, p. 1327.

    Google Scholar 

  2. Yakubov, E.S., Sorbtsionnye Khromatog. Protsessy, 2017, vol. 17, no. 4, p. 564.

    Google Scholar 

  3. Larionov, O.G. and Jakubov, E.S., Langmuir, 1988, vol. 4, no. 6, p. 1223.

    Article  Google Scholar 

  4. Larionov, O.G. and Jakubov, E.S., Proc. 3rd Int. Conference on Fundamentals of Adsorption, Mersmann, A.B. and Scholl, S.E., Eds., New York: Upstate Electrical Technologies, 1991, p. 475.

  5. Larionov, O.G. and Yakubov, E.S., Zh. Fiz. Khim., 1995, vol. 69, no. 11, p. 1998.

    Google Scholar 

  6. Farhadpour, F.A. and Bono. A., J. Colloid Interface Sci., 1988, vol. 124, no. 1, p. 209.

    Article  Google Scholar 

  7. Jakubov, E.S. and Larionov, O.G., Adsorpt. Sci. Technol., 1998, vol. 16, no. 7, p. 547.

    Article  Google Scholar 

  8. Ościk, J., Adsorption, Warszawa: PWN, Chichester: Ellis Horwood, 1982.

    Google Scholar 

  9. Yakubov, E.S., Cand. Sci. (Chem.) Dissertation, Moscow: Institute of Physical Chemistry Russ. Acad. Sci., 2001.

  10. Rakhmukov, B.Kh., Seliverstova, I.I., Serpinskii, V.V., and Fomkin, A.A., Izv. Akad. Nauk SSSR, Ser. Khim., 1979, vol. 28, no. 11, p. 2419.

    Google Scholar 

  11. Breck, D.W., Zeolite Molecular Sieves: Structure, Chemistry, and Use, New York: John Wiley and Sons, 1973.

    Google Scholar 

  12. Jakubov, E.S., Jakubov, T.S., and Larionov, O.G., Colloid J., 2007, vol. 69, no. 5, p. 671.

    Article  Google Scholar 

  13. Fomkin, A.A., Serpinskii, V.V., and Bering, B.P., Izv. Akad. Nauk SSSR, Ser. Khim., 1975, vol. 24, no. 6, p. 1244.

    Google Scholar 

  14. Chkhaidze, E.V., Fomkin, A.A., Serpinskii, V.V., and Tsitsishvili, G.V., Izv. Akad. Nauk SSSR, Ser. Khim., 1985, vol. 34, no. 5, p. 974.

    Google Scholar 

  15. Seliverstova, I.I., Fomkin, A.A., Serpinskii, V.V., and Dubinin, M.M., Izv. Akad. Nauk SSSR, Ser. Khim., 1983, vol. 32, no. 3, p. 493.

    Google Scholar 

  16. Seliverstova, I.I., Fomkin, A.A., and Serpinskii, V.V., Izv. Akad. Nauk SSSR, Ser. Khim., 1986, vol. 35, no. 6, p. 1231.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    Eduard S. Jakubov

Authors
  1. Eduard S. Jakubov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Eduard S. Jakubov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jakubov, E.S. Excess and Absolute Adsorption from Binary Liquid Solution by Microporous Crystalline Adsorbents: Cumene + n-Octane/Zeolite NaX. Prot Met Phys Chem Surf 55, 451–459 (2019). https://doi.org/10.1134/S2070205119040294

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205119040294

Keywords:

Search

Navigation