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Synthesis and Characterization of Hydroxyapatite/TiO2 Coatings on the β-Type Titanium Alloys with Different Sintering Parameters using Sol-Gel Method

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Abstract

In this study, hydroxyapatite (HA) based composite films were successfully syntheses on the β-type Ti29Nb13Ta4.6Zr (TNTZ). The solutionized TNTZ substrates coated with HA and HA/Titania (TiO2) bioactive composite coatings by sol-gel method under various sintering parameters related to sintering temperatures and heating ramp rates. Microstructural observations of the coatings revealed that apatite was formed on the substrates. The hardness values of the coatings increase with increasing both the sintering temperature and the TiO2 concentration in the coatings layer. However, it was found that the heating ramp rate of the sintering was not affecting the hardness values so much. Also, the hardness values of the HA/TiO2 composite coatings at all sintering temperatures were higher than only HA coated TNTZ samples due to the existence TiO2 phases in the HA matrix. Results indicating that the doping of HA with TiO2, improve the physical consistency between the coating layer and the substrates and provide a better inter-particle bonding due to the existence TiO2 phases in the HA.

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Authors and Affiliations

  1. Ataturk University, Dept. of Metallurgical and Materials Engineering, Erzurum, 25240, Turkey

    B. Dikici

  2. Tohoku University, Institute for Materials Research, Sendai, Miyagi, 980-8577, Japan

    M. Niinomi

  3. Yuzuncu Yil University, Department of Mechanical Engineering, Van, 65080, Turkey

    M. Topuz

  4. Munzur University, Metallurgical and Materials Engineering, Tunceli, 62000, Turkey

    Y. Say

  5. Yildiz Technical University, Materials Science and Engineering, Istanbul, 34220, Turkey

    B. Aksakal & H. Yilmazer

  6. Kindai University, Science and Engineering, Mechanical Engineering, Osaka, 577-8502, Japan

    M. Nakai

Authors
  1. B. Dikici
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  2. M. Niinomi
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  3. M. Topuz
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  4. Y. Say
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  5. B. Aksakal
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  6. H. Yilmazer
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  7. M. Nakai
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Correspondence to B. Dikici.

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Dikici, B., Niinomi, M., Topuz, M. et al. Synthesis and Characterization of Hydroxyapatite/TiO2 Coatings on the β-Type Titanium Alloys with Different Sintering Parameters using Sol-Gel Method. Prot Met Phys Chem Surf 54, 457–462 (2018). https://doi.org/10.1134/S2070205118030255

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  • DOI: https://doi.org/10.1134/S2070205118030255

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