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Morphology and Properties of Coatings Obtained by Plasma-Electrolytic Oxidation of Titanium Alloys in Pyrophosphate Electrolytes

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Abstract

By means of scanning electron microscopy, atomic-force microscopy, X-ray fluorescence analysis, and X-ray spectral microanalysis it was shown that, under plasma-electrolytic oxidation (PEO) of titanium alloys in pyrophosphate electrolytes, well-adhered oxide coatings with microglobular morphology result. It was demonstrated that the chemical and phase composition of the coatings, as well as the surface topography and grain size, can be controlled by changing the concentration of a pyrophosphate electrolyte and a PEO current density. It was established that the resulting oxide layer is highly resistant to abrasive wear and enhances the titanium corrosion resistance in model media (Ringer’s solution) substantially, which suggests that the coatings are promising for use in biological applications.

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References

  1. Gordienko, P.S. and Gnedenkov, S.V., Plazmennoelektroliticheskoe oksidirovanie titana i ego splavov (Plasma and Electrolytic Oxidation of Titanium and its Alloys), Vladivostok: Dal’nauka, 1997.

    Google Scholar 

  2. Chernenko, V.I., Snezhko, L.A., and Papanova, I.I., Poluchenie pokrytii anodno-iskrovym elektrolizom (Coatings Synthesized by means of Anode-Spark Electrolysis), Leningrad: Khimiya, 1991.

    Google Scholar 

  3. Barros, A.D., Albertin, K.F., Miyoshi, I., et al., Microelectron. Eng., 2010, vol. 87, p.443.

    Article  Google Scholar 

  4. Yerokhin, A.L., Nie, X., Leyland, A., et al., Surf. Coat. Technol., 1999, vol. 122, p.73.

    Article  Google Scholar 

  5. Suminov, I.V., Belkin, P.N., Epel’fel’d, A.V., et al., Plazmenno-elektroliticheskoe modifitsirovanie poverkhnosti metallov i splavov (Plasma and Electrolytic Modification for Metal and Alloy Surfaces), Moscow: Tekhnosfera, 2011.

    Google Scholar 

  6. Wang, Y.M., Iiang, B.L., Lei, T.Q., et al., Appl. Surf. Sci., 2005, vol. 246, nos. 1–3, p.214.

    Article  Google Scholar 

  7. Terleeva, O.P., Belevantsev, V.I., Slonova, A.I., et al., Prot. Met., 2006, vol. 42, no. 3, p.272.

    Article  Google Scholar 

  8. Bykanova, V.V., Sakhnenko, N.D., and Ved’, M.V., Surf. Eng. Appl. Electrochem., 2015, vol. 51, no. 3, p.276.

    Article  Google Scholar 

  9. Sakhnenko, N., Ved, M., and Bykanova, V., Funct. Mater., 2014, vol. 21, no. 4, p.492.

    Article  Google Scholar 

  10. Brunett, D.M., Tengvall, P., Textor, M., et al., Titanium in Medicine: Material Science, Surface Science, Engineering, Biological Responses and Medical Applications (Engineering Materials), Berlin, Heidelberg, New York: Springer, 2001, p.673.

    Book  Google Scholar 

  11. Kasuga, T., Kondo, H., and Nodami, M., J. Cryst. Growth, 2002, vol. 235, p.235.

    Article  Google Scholar 

  12. Zhakenova, S.S. and Amangaliev, A.B., Vestn. Khir., 2011, no. 3, p.93.

    Google Scholar 

  13. Rudnev, V.S., Yarovaya, T.P., Kon’shin, V.V., et al., Prot. Met., 2003, vol. 39, no. 2, p.160.

    Article  Google Scholar 

  14. Kassman, Å., Iacobson, S., Ericson, L., et al., Surf. Coat. Technol., 1991, vol. 50, no. 1, p.75.

    Article  Google Scholar 

  15. Lakel, S., Almi, K., and Berriche, Y., Rom. Rep. Phys., 2007, vol. 59, no. 1, p.113.

    Google Scholar 

  16. Ved’, M.V., Sakhnenko, N.D., and Nikiforov, K.V., J. Adhes. Sci. Technol., 1998, vol. 12, no. 2, p.175.

    Article  Google Scholar 

  17. Lunarska, E., Cherniayeva, O., Ved’, M., et al., Ochr. Koroz., 2007, no. 11A, p.265.

    Google Scholar 

  18. Rudnev, V.S., Yarovaya, T.P., Egorkin, V.S., et al., Russ. J. Appl. Chem., 2010, vol. 83, no. 4, p.664.

    Article  Google Scholar 

  19. Snizhko, L.O., Prot. Met. Phys. Chem. Surf., 2014, vol. 50, no. 6, p.705.

    Article  Google Scholar 

  20. Long, M. and Rack, H.I., Biomaterials, 1998, vol. 19, no. 18, p. 1621.

    Article  Google Scholar 

  21. Cao, H. and Liu, X., Surf. Coat. Technol., 2013, vol. 233, p.57.

    Article  Google Scholar 

  22. Podchernyaeva, I.A., Panashenko, V.M., Vereshchaka, V.M., et al., Mater. Sci., 2009, vol. 45, no. 5, p.734.

    Article  Google Scholar 

  23. Aver’yanov, E.E., Spravochnik po anodirovaniyu (Handbook on Anodization), Moscow: Mashinostroenie, 1988, pp. 82–83.

    Google Scholar 

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Authors and Affiliations

  1. National Technical University Kharkiv Polytechnic Institute, Kharkiv, 61002, Ukraine

    N. D. Sakhnenko, M. V. Ved’ & A. V. Karakurkchi

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  1. N. D. Sakhnenko
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  2. M. V. Ved’
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  3. A. V. Karakurkchi
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Correspondence to A. V. Karakurkchi.

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Original Russian Text © N.D. Sakhnenko, M.V. Ved’, A.V. Karakurkchi, 2017, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2017, Vol. 53, No. 6, pp. 637–645.

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Sakhnenko, N.D., Ved’, M.V. & Karakurkchi, A.V. Morphology and Properties of Coatings Obtained by Plasma-Electrolytic Oxidation of Titanium Alloys in Pyrophosphate Electrolytes. Prot Met Phys Chem Surf 53, 1082–1090 (2017). https://doi.org/10.1134/S207020511706020X

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  • DOI: https://doi.org/10.1134/S207020511706020X

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