Abstract
The passivating power of the aqueous solutions of certain trialkoxysilanes towards low-carbon steel has been studied. It has been established that aminoalkoxysilanes, as opposed to vinyltrimethoxysilane, are capable of passivating low-carbon steel in a neutral chloride-containing buffer solution. Aminoethylaminopropyltrimethoxysilane induces the passivation of steel most effectively. Its adsorption on the reduced or oxidized surface of the St3 steel studied via an ellipsometric method can be adequately described by the Frumkin equation.
Similar content being viewed by others
References
Kuznetsov, Yu.I., Korroz.: Mater., Zashch., 2011, no. 1, pp. 1–10.
Plueddenmann, E.P., Silane Coupling Agents, New York: Plenum, 1991, 2nd ed.
Osterholtz, F.D. and Pohl, E.R., J. Adhesion Sci. Technol., 1992, vol. 6, pp. 127.
Pohl, E.R., Chaves, A., Danehey, C.T., et al., in Silanes and Other Coupling Agents, Mittal K.L., Ed., Utrecht, Netherlands: VSP, 2000, vol. 2.
Subramanian, V. and van Ooij, W.J., Corrosion, 1998, vol. 54, p. 204.
Men’shikov, V.V., Kalinkina, A.A., Mazurova, D.V., et al., Korroz.: Mater., Zashch., 2010, no. 4, pp. 30–37.
Stratmann, M., Furberh, W., Grundmeier, G., et al., in Corrosion Mechanisms in Theory and Practice, Marcus, P. and Oudar, J., Ed., New York: Marcel Dekker, 1995, pp. 373–420.
Sugimura, H., Hozumi, A., Kameyama, T., and Takai, O., Organosilane self-assembled monolayers formed at the vapor/solid interface, Surf. Interface Anal., 2002, vol. 34, no. 1, pp. 550–554.
Kuznetsov, Yu.I., Andreev, N.N., Goncharova, O.A., and Agafonkin, A.V., Korroz.: Mater., Zashch., 2009, no. 10, pp. 29–33.
Andreeva, N.P., Korroz.: Mater., Zashch., 2007, no. 2, pp. 41–46.
Chirkunov, A.A., Gorbachev, A.S., Kuznetsov, Yu.I., and Shikhaliev, Kh.S., Korroz.: Mater., Zashch., 2011, no. 6, pp. 22–26.
Hanch, C. and Leo, A., Substituent Constants for Correlation Analysis in Chemistry and Biology, New York: Wiley, 1979.
Scherrer, R.A. and Howard, S.M., J. Med. Chem., 1977, vol. 20, no. 1, pp. 53–58.
Damaskin, B.B., Petrii, O.A., and Batrakov, V.V., Adsorbtsiya organicheskikh soedinenii na elektrodakh (Adsorption of Organic Compounds on Electrodes), Moscow: Nauka, 1968.
McCrackin, F.L., A Fortran program for analysis of ellipsometer measurements, in NBS Technical Note 479, Washington DC: U.S. Gov. Print. Off., 1969.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Chirkunov, A.M. Semiletov, Yu.I. Kuznetsov, N.P. Andreeva, 2013, published in Korroziya: Materialy, Zashchita, 2013, No. 11, pp. 27–34.
Rights and permissions
About this article
Cite this article
Chirkunov, A.A., Semiletov, A.M., Kuznetsov, Y.I. et al. Passivation of steel with aqueous solutions of trialkoxysilanes. Prot Met Phys Chem Surf 51, 1154–1159 (2015). https://doi.org/10.1134/S2070205115070059
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070205115070059