Skip to main content
SpringerLink
Log in

Temperature dependence of gas chromatography retention indices as one of the main factors determining their interlaboratory reproducibility

  • Investigation Methods for Physicochemical Systems
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

Temperature dependence of gas chromatography retention indices should be considered one of the main sources of their interlaboratory irreproducibility. The regularities of this dependence for packed and capillary columns or individual compounds allow revealing and characterizing other factors affecting reproducibility of the indices. These include the ratio of amounts of target analytes and reference compounds, as well as their polarity. Considering the anomalies in temperature dependences of retention indices of polar compounds on nonpolar phases allows assuming that it can be one of the causes of the asymmetry of the sets of reference data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Golovnya, R.V. and Arsen’ev, Yu.N., Usp. Khim., 1973, vol. 42, p. 2221.

    Article  Google Scholar 

  2. Zenkevich, I.G., in 100 Let khromatografii (To the 100th Anniversary of Chromatographic Analysis), Moscow: Nauka, 2003, p. 311.

    Google Scholar 

  3. The NIST 14 Mass Spectral Library (NIST11/2014/EPA/NIH). Software/Data Version (NIST14). NIST Standard Reference Database, Number 69, August 2011, Gaithersburg, MD: Natl. Inst. Standards Technol., 2011.

  4. Zenkevich, I.G., Anal. Bioanal. Chem., 2013, vol. 405, p. 3075.

    Article  Google Scholar 

  5. Zenkevich, I.G., in Encyclopedia of Chromatography, Cazes, J., Ed., Boca Raton: CRC Press, 2010, p. 1304.

  6. Mitra, G.D. and Saha, N.C., Chromatographia, 1973, vol. 6, p. 93.

    Article  Google Scholar 

  7. Bangjie, C. and Shaoyi, P., Chromatographia, 1988, vol. 25, p. 731.

    Article  Google Scholar 

  8. Zenkevich, I.G., Babushok, V.I., Linstrom, P.J. et al., J. Chromatogr. A, 2009, vol. 1216, p. 6651.

    Article  Google Scholar 

  9. Zenkevich, I.G. and Ukolova, E.S., J. Chromatogr. A, 2012, vol. 1265, p. 122.

    Article  Google Scholar 

  10. Leblon-Aguilar, R., Quintanilla-Lopez, J.E., Tello, A.M., and Santiuste, J.M., J. Chromatogr. A, 2007, vol. 1160, p. 276.

    Article  Google Scholar 

  11. Zenkevich, I.G. and Pavlovsky, A.A., Anal. Kontrol’, 2014, vol. 18, no. 2, p. 171.

    Google Scholar 

  12. Zenkevich, I.G. and Pavlovsky, A.A., Zh. Anal. Khim., 2015, vol. 70, no. 9, p. 1140.

    Google Scholar 

  13. Makarov, A.A. and Zenkevich, I.G., in The 3rd Int. Symp. on Computer Application and Chemometrics in Analytical Chemistry, Abstracts of Papers, Hungary, 2006, p. 1.

    Google Scholar 

  14. Zenkevich, I.G., Chromatographia, 2012, vol. 75, p. 767.

    Article  Google Scholar 

  15. Zenkevich, I.G., Vestn. S.-Peterb. Gos. Univ., Ser.: Fiz.Khim., 1998, no. 2, p. 84.

    Google Scholar 

  16. Hennig, P. and Engewald, W., Chromatographia, 1994, vol. 38, p. 93.

    Article  Google Scholar 

  17. Ciazynska-Halarewicz, K., and Kowalska, T., Acta Chromatogr., 2003, vol. 13, p. 69.

    Google Scholar 

  18. Heberger, K., Gordenyi, M., and Kowalska, T., J. Chromatogr. A, 2002, vol. 973, p. 135.

    Article  Google Scholar 

  19. Gordenyi, M. and Heberger, K., J. Chromatogr. 2003, vol. 985, p. 11.

    Article  Google Scholar 

  20. Santiuste, J.M., Quintanilla-López, J.E., Becerra, R., and Lebrón-Aguilar, R., J. Chromatogr. A, 2014, vol. 1365, p. 204.

    Article  Google Scholar 

  21. Kowalska, T., Heberger, K., and Gordenyi, M., Acta Chromatogr., 2003, vol. 13, p. 60.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State University, Institute for Chemistry, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    I. G. Zenkevich & A. A. Pavlovskii

Authors
  1. I. G. Zenkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Pavlovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. G. Zenkevich.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zenkevich, I.G., Pavlovskii, A.A. Temperature dependence of gas chromatography retention indices as one of the main factors determining their interlaboratory reproducibility. Prot Met Phys Chem Surf 51, 1058–1064 (2015). https://doi.org/10.1134/S2070205115060258

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205115060258

Keywords

Search

Navigation