Skip to main content
SpringerLink
Log in

Synthesis, structure, and luminescence properties of transition metal 12-crown-4-porphyrinates in a polystyrene matrix

  • Molecular and Supramolecular Structures at the Interfaces
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

A series of meso-tetra(benzo-12-crown-4)-substituted nickel(II), copper(II), zinc(II), palladium(II), and platinum(II) porphyrinates was synthesized. The structures of complexes were determined from the data of electronic absorption spectroscopy and MALDI TOF mass spectrometry. Analysis of the luminescence properties of metal porphyrinates in a polystyrene matrix at 25°C was performed. The quantum yields of fluorescence and phosphorescence were measured by an absolute method, and the lifetimes of fluorescence and phosphorescence were determined. On basis of the results obtained, analysis of the mechanisms of the influence of metal cations on the luminescence properties of the macrocyclic ligand in the molecules of 12-crown-4-substituted metal porphyrinates was performed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Thanabal, V. and Krishnan, V., Inorg. Chem., 1982, vol. 21, p. 3606.

    Article  Google Scholar 

  2. Thanabal, V. and Krishnan, V., J. Am. Chem. Soc., 1982, vol. 104, p. 3643.

    Article  Google Scholar 

  3. Murashima, T., Uchihara, Y., Wakamori, N., et al., Tetrahedron Lett., 1996, vol. 37, p. 3133.

    Article  Google Scholar 

  4. D’Souza, F., Chitta, R., Gadde, S., and Zandler, M., J. Phys. Chem. A, 2006, vol. 110, p. 4338.

    Article  Google Scholar 

  5. Korovin, Yu., Zhilina, Z., and Rusakova, N., J. Porphyrins Phthalocyanines, 2001, vol. 5, p. 481.

    Article  Google Scholar 

  6. Tsivadze, A.Yu., Russ. Chem. Rev., 2004, vol. 73, no. 1, pp. 5–23.

    Article  Google Scholar 

  7. Gorbunova, Y.G., Martynov, A.G., and Tsivadze, A.Y., in Handbook of Porphyrin Science, Kadish, K.M., Smith, K.M., and Guilard, R., Eds., Singapore: World Sci. Publ., 2012, p. 271.

  8. Kobayashi, N. and Lever, A., J. Am. Chem. Soc., 1987, vol. 109, p. 7433.

    Article  Google Scholar 

  9. Gorbunova, Yu.G., Lapkina, L.A., Martynov, A.G., Biryukova, I.V., and Tsivadze, A.Yu., Russ. J. Coord. Chem., 2004, vol. 30, no. 4, pp. 245–251.

    Article  Google Scholar 

  10. Gorbunova, Y.G., Enakieva, Y.Y., Sakharov, S.G., and Tsivadze, A.Y., J. Porphyrins Phthalocyanines, 2003, vol. 7, p. 795.

    Article  Google Scholar 

  11. Grishina, A.D., Gorbunova, Y.G., Zolotarevsky, V.I., et al., J. Porphyrins Phthalocyanines, 2009, vol. 13, p. 92.

    Article  Google Scholar 

  12. Vannikov, A.V., Gorbunova, Yu.G., Grishina, A.D., and Tsivadze, A.Yu., Prot. Met. Phys. Chem. Surf., 2013, vol. 49, no. 1, pp. 57–65.

    Article  Google Scholar 

  13. Kolesnikov, V.A., Tedoradze, M.G., Chernyad’ev, A.Yu., Vannikov, A.V., and Tsivadze, A.Yu., High Energy Chem., 2007, vol. 41, no. 2, pp. 103–108.

    Article  Google Scholar 

  14. Jahan, M., Safari, N., and Khosravi, H., Polyhedron, 2005, vol. 24, p. 1682.

    Article  Google Scholar 

  15. Adler, A.D., Longo, F.R., and Finarelli, J.D., J. Org. Chem., 1967, vol. 32, p. 476.

    Article  Google Scholar 

  16. Askarov, K.A., Berezin, B.D., Evstigneeva, R.P., et al., Porfiriny: struktura, svoistva, sintez (Porphyrins: Structure, Properties, and Synthesis), Moscow: Nauka, 1985.

    Google Scholar 

  17. Chernyadyev, A.Yu., Logacheva, N.M., and Tsivadze, A.Yu., Russ. J. Inorg. Chem., 2005, vol. 50, no. 4, pp. 552–556.

    Google Scholar 

  18. Lever, A., Inorganic Electronic Spectroscopy, Amsterdam: Elsevier, 1984.

    Google Scholar 

  19. Lakowicz, J., Principles of Fluorescence Spectroscopy, Baltimore: Univ. of Maryland School Med., 1983.

    Book  Google Scholar 

  20. El’yashevich, M.A., Atomnaya i molekulyarnaya spektroskopiya (Nuclear and Molecular Spectroscopy), Moscow: Fizmatgiz, 1962.

    Google Scholar 

  21. Ermolaev, V.L. and Sveshnikova, E.B., Acta Phys. Pol., 1968, vol. 34, p. 771.

    Google Scholar 

  22. Drouet, S., Paul-Roth, C., and Fattori, V., New J. Chem., 2011, vol. 35, p. 438.

    Article  Google Scholar 

  23. Mal’tsev, E.I., Brusentseva, M.A., Lypenko, D.A., Novikov, S.V., Vannikov, A.V., Rumyantseva, V.D., Mironov, A.F., and Berendyaev, V.I., Polym. Sci., Ser. A, 2006, vol. 48, no. 2, pp. 146–152.

    Article  Google Scholar 

  24. Nolan, E.M. and Lippard, S.J., Acc. Chem. Res., 2009, vol. 42, p. 193.

    Article  Google Scholar 

  25. Gordon, A. and Ford, R., The Chemist’s Companion: A Handbook of Practical Data, Techniques, and References, New York: Wiley, 1972.

    Google Scholar 

  26. Buchanan, G., Driega, A., and Moghimi, A., Can. J. Chem., 1993, vol. 71, p. 1983.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. Yu. Chernyad’ev & A. Yu. Tsivadze

Authors
  1. A. Yu. Chernyad’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Yu. Tsivadze
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. Yu. Chernyad’ev.

Additional information

Original Russian Text © A.Yu. Chernyad’ev, A.Yu. Tsivadze, 2015, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2015, Vol. 51, No. 4, pp. 385–391.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chernyad’ev, A.Y., Tsivadze, A.Y. Synthesis, structure, and luminescence properties of transition metal 12-crown-4-porphyrinates in a polystyrene matrix. Prot Met Phys Chem Surf 51, 533–539 (2015). https://doi.org/10.1134/S2070205115040073

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205115040073

Keywords

Search

Navigation