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Formation of nanocomposites of platinum with nanotubular titanium dioxide

  • Nanoscale and Nanostructured Materials and Coatings
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Abstract

Metal oxide nanocomposites of platinized titania nanotube arrays (Pt-TNT) have been formed via electrochemical anodization-precipitation. Initially, the vertically aligned amorphous TiO2 nanotube arrays (TNTs) were formed in accordance with potentiostatic electrochemical anodization of titanium with the use of 1 M H2SO4 + 0.3% HF electrolyte. Then, using the potentiostatic and pulse electrodeposition, precipitates of Pt on TNT were formed from 0.04 M solution of chloroplatinic acid (CPA). It has been shown with the use of SEM and Raman spectroscopy that, in order to prepare functional metal oxide Pt-TNT nanocomposites, pulse electrodeposition and subsequent annealing at 400°C are preferable, because they lead to TNTs that are homogeneously distributed along the surface and in bulk (with anatase structure) for platinized layers and conglomerates.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Leninskii pr. 31, Moscow, 119071, Russia

    A. I. Shcherbakov, I. V. Kasatkina, V. V. Vysotskii, A. A. Averin, V. A. Kotenev & A. Yu. Tsivadze

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  1. A. I. Shcherbakov
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  2. I. V. Kasatkina
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  3. V. V. Vysotskii
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  4. A. A. Averin
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  5. V. A. Kotenev
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  6. A. Yu. Tsivadze
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Correspondence to A. I. Shcherbakov.

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Shcherbakov, A.I., Kasatkina, I.V., Vysotskii, V.V. et al. Formation of nanocomposites of platinum with nanotubular titanium dioxide. Prot Met Phys Chem Surf 50, 803–808 (2014). https://doi.org/10.1134/S2070205114060203

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  • DOI: https://doi.org/10.1134/S2070205114060203

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