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Bifunctional Cobalt Catalysts for the Fischer–Tropsch Synthesis of Low-Pour-Point Diesel Fuel: From Development to Implementation: 2. Optimization of the Catalyst Component Composition

  • CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY
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Abstract

The effect of the content of metallic (Co–Al2O3/SiO2 catalyst) and acidic components (ZSM-5 zeolite in H-form) on the properties of a bifunctional catalyst for the integrated synthesis of low-pour-point diesel fuel by the Fischer–Tropsch method has been studied. The catalysts in the form of a composite mixture with a binder (boehmite) have been characterized by XRD, BET, and TPR methods. The tests are conducted in a fixed-bed flow reactor at a pressure of 2.0 MPa, a temperature of 240°C, and a gas space velocity of 1000 h–1. The activity and selectivity of catalysts and the fractional and hydrocarbon compositions of products as a function of the ratio of components have been compared. It has been found that the synthesis productivity with respect to С5+ hydrocarbons and selectivity to products of the С11–C18 diesel fraction with a high content of isomeric products correlate with the ratio of metallic and acidic components in the catalyst composition. The catalyst recommended for use in diesel fuel production has a composition with a ratio of metallic and acidic components of 1.17.

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Funding

This work was performed within the framework of the strategic project “Scientific and Innovation “Contract R&D Center” Cluster” of Platov South-Russian State Polytechnic University Development Program during the implementation of the program of strategic academic leadership “Priority-2030” using the equipment of the “Nanotechnologies” Center for collective use of Platov South-Russian State Polytechnic University.

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Authors and Affiliations

  1. Platov South-Russian State Polytechnic University, 346428, Novocherkassk, Rostov oblast, Russia

    R. E. Yakovenko, V. G. Bakun, I. N. Zubkov, O. P. Papeta, A. N. Saliev & A. P. Savost’yanov

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  1. R. E. Yakovenko
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  2. V. G. Bakun
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  3. I. N. Zubkov
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  6. A. P. Savost’yanov
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Correspondence to R. E. Yakovenko.

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Yakovenko, R.E., Bakun, V.G., Zubkov, I.N. et al. Bifunctional Cobalt Catalysts for the Fischer–Tropsch Synthesis of Low-Pour-Point Diesel Fuel: From Development to Implementation: 2. Optimization of the Catalyst Component Composition. Catal. Ind. 15, 357–366 (2023). https://doi.org/10.1134/S2070050423040128

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