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Promotion of Supported Sulfated Zirconia Catalysts with Iron and Manganese Sulfates

  • CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY
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Abstract

The effect of iron and manganese additives on the textural characteristics and phase composition of the alumina matrix support was studied for sulfated zirconia catalysts of hexane isomerization. The additives introduced at the stage of plastification of aluminum hydroxide significantly improved the catalyst activity (hexane conversion and selectivity of isomerization to hexane isomers). A distinction of the modified catalysts is the formation of acid sites in a ratio of LAS : BAS ≥ 2, which increase the yield of isomers and especially of high-octane 2,2-dimethylbutane.

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REFERENCES

  1. Wang, P., Yue, Y., Wang, T., and Bao, X., Int. J. Energy Res., 2020, vol. 44, no. 5, pp. 3270–3294.

    Article  CAS  Google Scholar 

  2. Bikmetova, L.I., Kazantsev, K.V., Zatolokina, E.V., Drozdov, V.A., Shilova, A.V., Paukshtis, E.A., Smolikov, M.D., and Belyi, A.S., Chem. Sustainable Dev., 2013, vol. 21, no. 1, pp. 39–45.

    Google Scholar 

  3. Smolikov, M.D., Bikmetova, L.I., Kazantsev, K.V., Zatolokina, E.V., and Belyi, A.S., Katal. Prom-sti, 2018, vol. 18, no. 2, pp. 45–49.

    CAS  Google Scholar 

  4. Hsu, C.Y., Heimbuch, C.R., Armes, C.T., and Gates, B.C., J. Chem. Soc., Chem. Commun., 1992, no. 22, pp. 1645–1646.

  5. Chen, W.-H., Ko, H.-H., Sakthivel, A., Huang, S.-J., Liu, S.-H., Lo, A.-Y., Tsai, T.-C., and Liu, S.-B., Catal. Today, 2006, vol. 116, pp. 111–120.

    Article  CAS  Google Scholar 

  6. Arata, K., Appl. Catal., A, 1996, vol. 146, pp. 3–32.

  7. Tabora, J.E. and Davis, R.J., J. Chem. Soc., Faraday Trans., 1995, no. 12, pp. 1825–1833.

  8. Wan, K.T., Khouw, C.B., and Davis, M.E., J. Catal., 1996, vol. 158, no. 1, pp. 311–326.

    Article  CAS  Google Scholar 

  9. Morterra, C., Cerrato, G., Di Ciero, S., Signoretto, M., Minesso, A., Pinna, F., and Strukul, G., Catal. Lett., 1997, vol. 49, pp. 25–34.

    Article  CAS  Google Scholar 

  10. Adeeva, V., Liu, H.Y., Xu, B.Q., and Sachtle, W.M.H., Top. Catal., 1998, vol. 6, pp. 61–76.

    Article  CAS  Google Scholar 

  11. Garcia, E.A., Rueda, E.H., and Rouco, A.J., Appl. Catal., A, 2001, vol. 210, pp. 363–370.

  12. Jentoft, F.C., Hahn, A., Kröhnert, J., Lorenz, G., Jentoft, R.E., Ressler, T., Wild, U., Schlögl, R., Häßner, C., and Köhler, K., J. Catal., 2004, vol. 224, pp. 124–137.

    Article  CAS  Google Scholar 

  13. Klose, B.S., Jentoft, F.C., Schlögl, R., Subbotina, I.R., and Kazansky, V.B., Langmuir ACS J. Surf. Colloids, 2005, vol. 21, no. 23, pp. 10564–10572.

    Article  CAS  Google Scholar 

  14. Song, H., Cui, H., and Li, F., Res. Chem. Intermed., 2015, vol. 42, no. 4, pp. 3029–3038.

    Article  Google Scholar 

  15. Ivanov, A.V. and Kustov, L.M., Ross. Khim. Zh., 2000, vol. 54, pp. 21–52.

    Google Scholar 

  16. Paukshtis, E.A., Infrakrasnaya spektroskopiya v geterogennom kislotno-osnovnom katalize (Infrared Spectroscopy in Heterogeneous Acid Catalysis), Novosibirsk: Nauka, 1992.

  17. Kuznetsov, P.N., Kuznetsova, L.I., and Kazbanova, A.V., Chem. Sustainable Dev., 2010, vol. 18, no. 3, pp. 283–298.

    CAS  Google Scholar 

  18. Sannikov, A.L., Regularities in the formation of catalysts based on sulfated zirconia and their activity in the isomerization of light alkanes, Cand. Sci. Dissertation, Krasnoyarsk, 2007.

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ACKNOWLEDGMENTS

We are grateful to G.G. Savel’eva for the study of the textural characteristics of the catalysts and to E.A. Paukshtis for assistance with IR spectroscopy of adsorbed pyridine.

Funding

This study was financially supported by the Ministry of Science and Higher Education of the Russian Federation under the government contract at the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences (project no. AAAA-A21-121011890074-4).

The textural characteristics, phase composition, and acidic properties were studied using the equipment of the Multiaccess Center “National Center for Catalyst Research” of the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences.

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Authors and Affiliations

  1. Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 644040, Omsk, Russia

    M. D. Smolikov, L. I. Bikmetova, K. V. Kazantsev, I. V. Muromtsev & A. S. Belyi

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  1. M. D. Smolikov
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  2. L. I. Bikmetova
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  3. K. V. Kazantsev
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  4. I. V. Muromtsev
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  5. A. S. Belyi
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Correspondence to M. D. Smolikov.

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Translated by L. Smolina

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Smolikov, M.D., Bikmetova, L.I., Kazantsev, K.V. et al. Promotion of Supported Sulfated Zirconia Catalysts with Iron and Manganese Sulfates. Catal. Ind. 13, 361–366 (2021). https://doi.org/10.1134/S2070050421040103

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  • DOI: https://doi.org/10.1134/S2070050421040103

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