Skip to main content
SpringerLink
Log in

Preparing MoVTeNbBiO Catalysts for the Selective Oxidative Conversion of Light Alkanes

  • CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY
  • Published:
Catalysis in Industry Aims and scope Submit manuscript

Abstract

It is shown that the method of synthesis and source of bismuth greatly affect the physicochemical properties of modified MoVTeNbO catalysts. Adding an organic bismuth compound with a neutral pH at the stage of mixing the solutions of the initial components is accompanied by precipitation and the formation of inactive phases when the required M1 phase is missing. Regardless of the nature of the initial bismuth compound, introducing it into a dry MoVTeNb precursor leads to considerable destruction of it, resulting in a lower content of the M1 phase and the formation of binary V–Mo and Te–Мo oxides. It has been established that the ethylene yield attains a maximum (76.5 %) in the oxidative ethane dehydrogenation (OED)reaction, when the calcined MoVTeNb oxide catalyst is impregnated with a bismuth organic compound solution. The yield of acrylic acid is ≈48% over the same catalyst in the reaction of propane oxidation. Introducing bismuth nitrate into a solution of the initial components is nevertheless a more technologically advanced way of preparing bismuth-containing catalysts. The maximum ethylene yield is ≈76% in the OED reaction over the catalyst obtained using bismuth nitrate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Ushikubo, T., Oshima, K., Kayou, A., and Hatano, M., Stud. Surf. Sci. Catal., 1997, vol. 112, pp. 473–480.

    Article  CAS  Google Scholar 

  2. Cavani, F., Ballarini, N., and Cericola, A., Catal. Today, 2007, vol. 127, nos. 1–4, pp. 113–131.

  3. Chieregato, A., López Nieto, J.M., and Cavani, F., Coord. Chem. Rev., 2014, vols. 301–302, pp. 3–23.

  4. López Nieto, J. M., Solsona, B., Concepción, P., Ivars, F., Dejoz, A., and Vázquez, M. I., Catal. Today, 2010, vol. 157, nos. 1–4, pp. 291–296.

  5. Ishchenko, E.V., Kardash, T.Y., Gulyaev, R.V., Ishchenko, A.V., Sobolev, V.I., and Bondareva, V.M., Appl. Catal., A, 2016, vol. 514, pp. 1–13.

  6. Ishchenko, E.V., Gulyaev, R.V., Kardash, T.Y., Ishchenko, A.V., Gerasimov, E.Y., Sobolev, V.I., and Bondareva, V.M., Appl. Catal., A, 2017, vol. 534, pp. 58–69.

  7. Deniau, B., Nguyen, T.T., Delichere, P., Safonova, O., and Millet, J.-M.M., Top. Catal., 2013, vol. 56, pp. 1952–1962.

    Article  CAS  Google Scholar 

  8. Hibst, H., Rosowski, F., and Cox, G., Catal. Today, 2006, vol. 117, nos. 1–3, pp. 234–241.

  9. WO Patent 2004/099 081, 2004.

  10. Zhu, Y., Lu, W., Li, H., and Wan, H., J. Catal., 2007, vol. 246, no. 2, pp. 382–389.

    Article  CAS  Google Scholar 

  11. Oliver, J.M., López-Nieto, J.M., Botella, P., and Mifsud, A., Appl. Catal., A, 2004, vol. 257, no. 1, pp. 67–76.

  12. Yu, Z., Zheng, W., Xu, W., Zhang, Yu., Fu, H., and Zhang, P., Trans. Nonferrous Met. Soc. China, 2009, vol. 19, suppl. 2, pp. s476–s479.

    Article  CAS  Google Scholar 

  13. Ischenko, E.V., Andrushkevich, T.V., Popova, G.Ya., Bondareva, V.M., Chesalov, Yu.A., Kardash, T.Yu., Plyasova, L.M., Dovlitova, L.S., and Ischenko, A.V, Stud. Surf. Sci. Catal., 2010, vol. 175, pp. 479–482.

    Article  CAS  Google Scholar 

  14. Popova, G.Ya., Andrushkevich, T.V., Dovlitova, L.S., Aleshina, G.I., Chesalov, Yu.A., Ishenko, A.V., Ischenko, E.V., Plyasova, L.M., Malakhov, V.V., and Khramov, M.I., Appl. Catal., A, 2009, vol. 353, no. 2, pp. 249–257.

  15. Oh, K.S. and Woo, S.I., Catal. Today, 2008, vol. 137, no. 1, pp. 61–70.

    Article  CAS  Google Scholar 

  16. Turkevich. N.M., Ukr. Khim. Zh., 1949, vol. 15, no. 2, pp. 243–247.

  17. Turkevich, N.M., Ukr. Khim. Zh., 1949, vol. 15, no. 2, pp. 250–252.

    Google Scholar 

  18. Rabinovich, V.A. and Khavin, Z.Ya., Kratkii khimicheskii spravochnik: Spravochnoe izdanie (Brief Chemical Handbook: Reference Edition), Potekhin, A.A. and Efimov, A.I., Eds., St.Petersburg: Khimiya, 1994.

    Google Scholar 

  19. Valente, J.S., Armendáriz-Herrera, H., Quintana-Solórzano, R., Paz del Ángel, Nava, N., Massó, A., and López Nieto, J.M., ACS Catal., 2014, vol. 4, no. 5, pp. 1292–1301.

    Article  CAS  Google Scholar 

  20. Ishchenko, E.V., Andrushkevich, T.V., Popova, G.Ya., Chesalov, Yu.A., Plyasova, L.M., Ishchenko, A.V., Kardash, T.Yu., and Dovlitova, L.S., Catal. Ind., 2010, vol. 2, no. 4, pp. 291–298.

    Article  Google Scholar 

  21. Popova, G.Ya., Andrushkevich, T.V., Chesalov, Y.A., Plyasova, L.M., Dovlitova, L.S., Ischenko, E.V., Aleshina, G.I., and Khramov, M.I., Catal. Today, 2009, vol. 144, nos. 3–4, pp. 312–317.

  22. DeSanto, P., Buttrey, D.J., Grasselli, R.K., Lugmair, C.G., Volpe, A.F., Toby, B.H., and Vogt, Th., Z. Kristallogr., 2004, vol. 219, no. 3, pp. 152–165.

    CAS  Google Scholar 

  23. Inorganic Crystal Structure Database (ICSD), Release 2008, D-8211, D-1754. https://www.fiz-karlsruhe.de/de/ produkte-und-dienstleistungen/inorganic-crystal-structure-database-icsd. Cited January 8, 2020.

  24. Svintsitskiy, D.A., Kardash, T.Yu., Stonkus, O.A., Slavinskaya, E.M., Stadnichenko, A.I., Koscheev, S.V., Chupakhin, A.P., and Boronin, A.I., J. Phys. Chem., 2013, vol. 117, no. 28, pp. 14588–14599.

    Article  CAS  Google Scholar 

  25. Svintsitskiy, D.A., Slavinskaya, E.M., Kardash, T.Y., Avdeev, V.I., Senkovskiy, B.V., Koscheev, S.V., and Boronin, A.I., Appl. Catal., A, 2016, vol. 510, pp. 64–73.

  26. Moulder, J.F., Stickle, W.F., Sobol, P.E., and Bomben, K.D. Handbook of X-Ray Photoelectron Spectroscopy, Chastain, J., Ed., Eden Prairie, MN: Perkin-Elmer, 1992.

    Google Scholar 

  27. Bondareva, V.M., Kardash, T.Yu., Ishchenko, E.V., and Sobolev, V.I., Catal. Ind., 2015, vol. 7, no. 2, pp. 104–110.

    Article  Google Scholar 

  28. Holmberg, J., Grasselli, R.K., and Andersson, A., Appl. Catal., A, 2004, vol. 270, nos. 1–2, pp. 121–134.

  29. International Center for Diffraction Data (ICDD), PDF-2 Release 2009, no. 00-058-0789 (M1). http://www.icdd.com. Cited January 8, 2020.

  30. International Center for Diffraction Data (ICDD), PDF-2 Release 2009, no. 00-057-1099 (M2). http://www.icdd.com. Cited January 8, 2020.

  31. Kardash, T.Yu., Lazareva, E.V., Svintsitskiy, D.A., Ishchenko, A.V., Bondareva, V.M., and Neder, R.B., RSC Adv., 2018, vol. 8, no. 63, pp. 35903–35916.

    Article  CAS  Google Scholar 

  32. International Center for Diffraction Data (ICDD), PDF-2 Release 2009, no. 01-077-0649 (V0.97Mo0.95O5). http://www.icdd.com. Cited January 8, 2020.

  33. International Center for Diffraction Data (ICDD), PDF-2 Release 2009, no. 00-031-1437 ((V0.07Mo0.93)5O14). http://www.icdd.com. Cited January 8, 2020.

  34. International Center for Diffraction Data (ICDD), PDF-2 Release 2009, no. 00-031-0874 (TeMo5O16). http://www.icdd.com. Cited January 8, 2020.

  35. Ishikawa, S., Goto, Y., Kawahara, Y., Inukai, S., Hiyoshi, N., Dummer, N.F., Murayama, T., Yoshida, A., Sadakane, M., and Ueda, W., Chem. Mater., 2017, vol. 29, no. 7, pp. 2939–2950.

    Article  CAS  Google Scholar 

  36. Heine, C, Hävecker, M., Trunschke, A., Schlögl, R., and Eichelbaum, M., Phys. Chem. Chem. Phys., 2015, vol. 17, no. 14, pp. 8983–8993.

    Article  CAS  Google Scholar 

  37. Botella, P., López Nieto, J.M., Solsona, B., Mifsud, A., and Márquez, F, J. Catal., 2002, vol. 209, no. 2, pp. 445–455.

    Article  CAS  Google Scholar 

  38. Sanfiz, A.C., Hansen, T.W., Teschner, D., Schnörch, P., Girgsdies, F., Trunschke, A., Schlögl, R., Looi, M.H., and Bee abd Hamid, A., J. Phys. Chem. C, 2010, vol. 114, no. 4, pp. 1912–1921.

    Article  CAS  Google Scholar 

  39. Baca, M. and Millet, J.-M.M., Appl. Catal., A, 2005, vol. 288, nos. 1–2, p. 243.

  40. Bezdenezhnykh, A.A., Inzhenernye metody sostavleniya uravnenii skorostei reaktsii i pascheta kineticheskikh konstant (Engineering Methods for the Composition of Reaction Rate Equations and the Calculation of Kinetic Constants), Leningrad: Khimiya, 1973.

Download references

Funding

This work was supported by the Russian Science Foundation, project no. 17-73-20073.

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    E. V. Lazareva, V. M. Bondareva, D. A. Svintsitskii & T. Yu. Kardash

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    D. A. Svintsitskii & T. Yu. Kardash

Authors
  1. E. V. Lazareva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Bondareva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. A. Svintsitskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. Yu. Kardash
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to E. V. Lazareva, V. M. Bondareva, D. A. Svintsitskii or T. Yu. Kardash.

Additional information

Translated by G. Levit

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lazareva, E.V., Bondareva, V.M., Svintsitskii, D.A. et al. Preparing MoVTeNbBiO Catalysts for the Selective Oxidative Conversion of Light Alkanes. Catal. Ind. 12, 39–46 (2020). https://doi.org/10.1134/S2070050420010092

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070050420010092

Keywords:

Search

Navigation