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Mechanical Properties and Biodegradability of Polylactide—Polysaccharide Compositions

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Abstract

Under the conditions of shear deformations, blends of polylactide with natural polysaccharides and their derivatives (starch, chitosan, and ethyl cellulose) were obtained in a Brabender mixer at different ratios of components; their properties were studied. It has been shown that the mechanical parameters of compositions depend on their composition and the nature of the polysaccharide used. In order to improve the plasticity of the compositions, a plasticizer, poly(ethylene glycol) (PEG), was added to them; the anomalous dependence of the change in elongation at break on the amount of PEG introduced was detected. The study of the biodegradability of the compositions obtained by various methods and changes in their structure during biodegradation made it possible to determine the characteristics of the biodestruction of the samples under study.

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References

  1. L. Yu and L. Chen, “Polymeric materials from renewable resources,” in Biodegradable Polymer Blends and Composites from Renewable Resources, Ed. by L. Yu (John Wiley & Sons, New Jersey, 2009), pp. 1–15.

    Google Scholar 

  2. E. Chiellini, A. Barghini, P. Cinelli, and V. I. Ilieva, “Overview of environmentally compatible polymeric materials for food packaging,” in Environmentally Compatible Food Packaging, Ed. by E. Chiellini (Woodhead Publishing Limited, Cambridge, 2008).

    Google Scholar 

  3. S. Z. Rogovina, “Biodegradable polymer composites based on synthetic and natural polymers of various classes,” Polym. Sci., Ser. C 58, 62–73 (2016).

    Article  CAS  Google Scholar 

  4. J.-W. Rhim, H.-M. Park, and C.-S. Ha, “Bio-nanocomposites for food packaging application,” Prog. Polym. Sci. 38, 1629–1652 (2013).

    Article  CAS  Google Scholar 

  5. C. S. K. Lin, L. A. Platzgraff, L. Herrero-Davila, E. B. Mubofu, S. Abderrahim, J. H. Clark, A. A. Koutinas, N. Kopsahelis, K. Stamatelatou, F. Dickson, S. Thankappan, Z. Mohamed, R. Blocklesby, and R. Luque, “Food waste as a valuable resource for the production chemicals, materials and fuels. Current situation and global perspective,” Energy Environ. Sci. 6, 426–464 (2013).

    Article  CAS  Google Scholar 

  6. T. Iwata, “Biodegradable and bio-based polymers: future prospects of eco-friendly plastics,” Angew. Chem., Int. Ed. 54, 3210–3215 (2015).

    Article  CAS  Google Scholar 

  7. S. Rogovina, K. Aleksanyan, L. Vladimirov, E. Prut, N. Ivanushkina, and A. Berlin, “Development of novel biodegradable polysaccharide-based composites and investigation of their structure and properties,” J. Polym. Environ. 26, 1727–1736 (2018).

    Article  CAS  Google Scholar 

  8. S. Z. Rogovina, S. M. Lomakin, K. V. Aleksanyan, and E. V. Prut, “The structure, properties, and thermal destruction of biodegradable blends of cellulose and ethylcellulose with synthetic polymers,” Russ. J. Phys. Chem. B 6, 416–424 (2012).

    Article  CAS  Google Scholar 

  9. Y. Yu, Y. Cheng, J. Ren, E. Cao, X. Fu, and W. Guo, “Plasticizing effect of poly(etylene glycol)s with different molecular weights in poly(lactic acid)/starch blends,” J. Appl. Polym. Sci. 132 (2015). https://doi.org/10.1002/app.41808

  10. B. W. Chieng, N. A. Ibrahim, W. M. Z. W. Yunus, and M. Z. Hussein, “Plasticized poly(lactic acid) with low molecular weight poly(ethylene glycol): Mechanical, thermal, and morphology properties,” J. Appl. Polym. Sci. 130, 4576–4580 (2013).

    CAS  Google Scholar 

  11. F.-J. Li, S.-D. Zhang, J.-Z. Liang, and J.-Z. Wang, “Effect of polyethylene glycol on the crystallization and impact properties of polylactide-based blends,” Polym. Adv. Technol. 26, 465–475 (2015).

    Article  CAS  Google Scholar 

  12. K. Sungsanit, N. Kao, and S. N. Bhattachrya, “Properties of linear poly(lactic acid)/polyethylene glycol blends,” Polym. Eng. Sci. 52, 108–116 (2012).

    Article  CAS  Google Scholar 

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Funding

This work was implemented in the framework of a state order of the Federal Agency of Scientific Organization of Russia, theme 46.14, no. 0082-2014-0006, no. AAAA-A17-117-117032750202-6.

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Correspondence to S. Z. Rogovina.

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Russian Text © The Author(s), 2019, published in Vse Materialy, 2019, No. 2, pp. 2–7.

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Rogovina, S.Z., Aleksanyan, K.V., Kuznetsova, O.P. et al. Mechanical Properties and Biodegradability of Polylactide—Polysaccharide Compositions. Polym. Sci. Ser. D 12, 300–304 (2019). https://doi.org/10.1134/S1995421219030195

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  • DOI: https://doi.org/10.1134/S1995421219030195

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