Abstract
The effects of structural modification of epoxy polymers (EPs) with mono- and dicarboxylic adamantane acids are studied. Within a cluster model of the structure of amorphous polymers, the components of the X-ray amorphous halo of the objects under study are identified based on the assumption of the existence of an open-packed matrix and regions of local order. It is established that the introduction of bulk adamantane fragments increases the nonuniformity of the EP structure, which causes a change in molecular and topological characteristics.
Similar content being viewed by others
References
V. F. Stroganov and I. V. Stroganov, “Study of the relationship of topological characteristics of chemical and physical networks of adamantane anhydride epoxy polymers,” Polym. Sci. Ser. D (2014) (in press).
V. N. Belousov, G. V. Kozlov, A. K. Mikitaev, and Yu. S. Lipatov, Dokl. Akad. Nauk SSSR 313(3), 630 (1990).
D. S. Sanditov, G. V. Kozlov, V. N. Belousov, and Yu. S. Lipatov, Ukr. Polym. J. 1(3–4), 241 (1992).
A. V. Beloshenko, G. V. Kozlov, I. V. Stroganov, and V. F. Stroganov, Fiz. Tekh. Vys. Davlen. 4(3–4), 113 (1994).
G. V. Kozlov, V. A. Beloshenko, E. N. Kuznetsov, and Yu. S. Lipatov, Dokl. NAN Ukrainy, No. 12, 126 (1994).
R. L. Miller and R. F. Boyer, Pol. Sci. Ser. Pol. Phys. 22(12), 2043 (1984).
R. F. Boyer and R. L. Miller, Macromolecules 10(5), 1167 (1977).
B. K. Vainshtein, Diffraction of X-Rays by Chain Molecules (Elsevier, London, 1996).
P. J. Flory, Pure Appl. Chem. 56(3), 305 (1984).
H.-H. Song and R.-J. Roe, Macromolecules 20(11), 2723 (1987).
C. A. Majid, A. U. Ahmad, R. A. Akber, and H. A. Khan, Radiat. Phys. Chem. 16(5), 379 (1980).
S. E. B. Petrie, Macromol. Sci.-Phys., B12(2), 225 (1976).
Kozlov, G.V. and Sanditov, D.S., Anharmonic Effects and Physicomechanical Properties of Polymers (Nauka, Novosibirsk, 1994) [in Russian].
V. A. Beloshenko, G. V. Kozlov, and V. N. Varyukhin, Fiz. Tekh. Vys. Davlen. 4(2), 70 (1994).
S. M. Aharoni, Macromolecules 16(9), 1722 (1983).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.F. Stroganov, I.V. Stroganov, 2014, published in Klei. Germetiki. Tekhnologii, 2014, No. 1, pp. 7–13.
Rights and permissions
About this article
Cite this article
Stroganov, V.F., Stroganov, I.V. An investigation of the effect of adamantanecarboxylic acids on the structure of epoxy polymers by means of X-ray structural and thermomechanical analyses. Polym. Sci. Ser. D 7, 265–270 (2014). https://doi.org/10.1134/S1995421214040145
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1995421214040145