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Poly(p-Xylylene) and Poly(chloro-p-Xylylene) Protective Coatings Prepared by Deposition in a Nitrogen Flow

  • NATURAL SCIENTIFIC METHODS IN STUDYING CULTURAL HERITAGE SITES
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Abstract

Thin-film protective coatings based on poly(p-xylylene) (PPX) and poly(chloro-p-xylylene) (PCPX) have been synthesized by vapor deposition polymerization (VDP) in a vacuum and deposition in a nitrogen flow. Comparison of characteristics of the PPX coatings by atomic force microscopy, infrared spectroscopy, and thermogravimetric analysis has shown that the films deposited in a nitrogen flow, unlike the films prepared by VPD in a vacuum, contain a large amount of low-molecular-weight fractions that worsen the protective characteristics of the films. In addition, the growth rate of these films is too low for practical applications. Analysis of the PCPX-based coatings prepared by these methods has shown a high similarity in composition and structure at comparable growth rates of the coatings. Owing to the high transparency and hydrophobicity of PCPX coatings prepared by deposition in a nitrogen flow, they can be used for the conservation of historical artifacts and written monuments on paper media.

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Funding

This work was supported by the Russian Foundation for Basic Research (project no. 18-00-00427) within the framework of complex project KOMFI 18-00-00429(K) using the equipment of the Resource Centers of Kurchatov Institute National Research Center.

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Authors and Affiliations

  1. Kurchatov Institute National Research Center, 123182, Moscow, Russia

    A. A. Nesmelov, S. A. Zavyalov, D. R. Streltsov, S. N. Malakhov, P. V. Dmitryakov, A. V. Bakirov, T. E. Grigoryev & S. N. Chvalun

  2. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 117393, Moscow, Russia

    D. R. Streltsov, A. V. Bakirov & S. N. Chvalun

Authors
  1. A. A. Nesmelov
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  2. S. A. Zavyalov
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  3. D. R. Streltsov
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  4. S. N. Malakhov
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  5. P. V. Dmitryakov
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  6. A. V. Bakirov
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  7. T. E. Grigoryev
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  8. S. N. Chvalun
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Correspondence to A. A. Nesmelov.

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Translated by M. Timoshinina

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Nesmelov, A.A., Zavyalov, S.A., Streltsov, D.R. et al. Poly(p-Xylylene) and Poly(chloro-p-Xylylene) Protective Coatings Prepared by Deposition in a Nitrogen Flow. Nanotechnol Russia 15, 647–654 (2020). https://doi.org/10.1134/S1995078020050092

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