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Intoxication of the natural aqueous medium resulting from disbalance of redox and free-radical intrabasin processes

  • Chemical Physics of Ecological Processes
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Abstract

The mechanisms of redox processes occurring in natural water with participation of molecular oxygen and the product of its reduction hydrogen peroxide as a carrier of reactive oxidative equivalents and hydrosulfide as a carrier of reducing equivalents in the formation of a toxic quasi-reducing state of the natural water medium were analyzed. The conditions for the formation of the toxic superoxidation state of the aqueous medium as a result of intensification of free-radical processes involving OH radicals and microcolloidal mixed-valence manganese(III, IV) particles were characterized.

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, 119334, Russia

    V. O. Shvydkii & E. V. Shtamm

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    Yu. I. Skurlatov, E. V. Vichutinskaya & N. I. Zaitseva

  3. All-Russian Research Institute of Fish Industry and Oceanography, Moscow, 107140, Russia

    L. V. Semenyak

Authors
  1. V. O. Shvydkii
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  2. E. V. Shtamm
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  3. Yu. I. Skurlatov
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  4. E. V. Vichutinskaya
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  5. N. I. Zaitseva
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  6. L. V. Semenyak
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Corresponding author

Correspondence to Yu. I. Skurlatov.

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Original Russian Text © V.O. Shvydkii, E.V. Shtamm, Yu.I. Skurlatov, E.V. Vichutinskaya, N.I. Zaitseva, L.V. Semenyak, 2017, published in Khimicheskaya Fizika, 2017, Vol. 36, No. 8, pp. 23–33.

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Shvydkii, V.O., Shtamm, E.V., Skurlatov, Y.I. et al. Intoxication of the natural aqueous medium resulting from disbalance of redox and free-radical intrabasin processes. Russ. J. Phys. Chem. B 11, 643–651 (2017). https://doi.org/10.1134/S1990793117040248

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  • DOI: https://doi.org/10.1134/S1990793117040248

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