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Reactions of initiation of the autoignition of H2–O2 mixtures in shock waves

  • Combustion, Explosion, and Shock Waves
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Abstract

The initiation of the autoignition of hydrogen–oxygen–argon mixtures behind reflected shock waves is studied by absorption and emission spectrophotometry in the temperature range of 960 < T < 1670 K at pressures of ~0.1 MPa. Introduction of Mo(CO)6 additive in an amount of ~80 ppm made it possible to study the effect of O atoms on the shortening of the ignition delay time of H2–O2–Ar mixtures. A kinetic modeling of our own and published experimental data at temperatures of 930 < T < 2500 K and pressures of 0.05 < P < 8.7 MPa enabled to establish how the initiation reactions influence the process of self-ignition and to evaluate the rate constant for one of the initiation reactions: k(H2 + O2 → 2OH) = (3 ± 1) × 1011exp(–E a/RT), cm3 mol–1 s–1, where E a = (40 ± 2) kcal/mol.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russia

    P. A. Vlasov, V. N. Smirnov & A. M. Tereza

  2. National Research Nuclear University “MEPhI,”, Moscow, Russia

    P. A. Vlasov

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  1. P. A. Vlasov
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  2. V. N. Smirnov
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  3. A. M. Tereza
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Correspondence to A. M. Tereza.

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Original Russian Text © P.A. Vlasov, V.N. Smirnov, A.M. Tereza, 2016, published in Khimicheskaya Fizika, 2016, Vol. 35, No. 6, pp. 35–48.

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Vlasov, P.A., Smirnov, V.N. & Tereza, A.M. Reactions of initiation of the autoignition of H2–O2 mixtures in shock waves. Russ. J. Phys. Chem. B 10, 456–468 (2016). https://doi.org/10.1134/S1990793116030283

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  • DOI: https://doi.org/10.1134/S1990793116030283

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