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Relative permittivity of monocomponent and binary solutions of N2O5 in liquid CO2 and their activity in nitration of cellulose

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Abstract

Static relative permittivity of liquid carbon dioxide solutions of dinitrogen pentoxide and its mixtures with nitric, acetic or trifluoroacetic acids is measured. The procedure for nitration of cellulose acquired from various natural noncotton sources (wood, linen, hemp) by mixtures of dinitrogen pentoxide and 100% nitric acid in a carbon dioxide medium is developed. A supercritical drying technique is implemented for dehydration of wet nitrocellulose.

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Authors and Affiliations

  1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. A. Guskov, I. V. Kuchurov & S. G. Zlotin

Authors
  1. A. A. Guskov
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  2. I. V. Kuchurov
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  3. S. G. Zlotin
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Correspondence to I. V. Kuchurov.

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Original Russian Text © A.A. Guskov, I.V. Kuchurov, S.G. Zlotin, 2014, published in Sverkhkriticheskie Flyuidy: Teoriya i Praktika, 2014, Vol. 9, No. 4, pp. 42–52.

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Guskov, A.A., Kuchurov, I.V. & Zlotin, S.G. Relative permittivity of monocomponent and binary solutions of N2O5 in liquid CO2 and their activity in nitration of cellulose. Russ. J. Phys. Chem. B 9, 1130–1136 (2015). https://doi.org/10.1134/S1990793115080059

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  • DOI: https://doi.org/10.1134/S1990793115080059

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