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Kinetics of reduced models of catalytic reactions

  • Kinetics and Mechanism of Chemical Reactions. Catalysis
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Abstract

Kinetic characteristics of catalytic reactions in open gradientless systems are studied based on full and reduced systems of ordinary differential equations under steady-state conditions for some of the reactants. By the example of two-step reactions constituting the basis of most of the multistep catalytic processes equilibrium and nonequilibrium properties are compared and the error of application of the steady-state approximation to describing the kinetics of these reactions within the framework of various reduced models is examined.

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Authors and Affiliations

  1. Chuvash State University, Cheboksary, Russia

    V. Kh. Fedotov & N. I. Kol’tsov

Authors
  1. V. Kh. Fedotov
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  2. N. I. Kol’tsov
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Corresponding author

Correspondence to V. Kh. Fedotov.

Additional information

Original Russian Text © V.Kh. Fedotov, N.I. Kol’tsov, 2015, published in Khimicheskaya Fizika, 2015, Vol. 34, No. 11, pp. 18–26.

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Fedotov, V.K., Kol’tsov, N.I. Kinetics of reduced models of catalytic reactions. Russ. J. Phys. Chem. B 9, 876–884 (2015). https://doi.org/10.1134/S1990793115060044

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  • DOI: https://doi.org/10.1134/S1990793115060044

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