Abstract
The relationship between the empirical parameters of the Havriliak–Negami formula with the physical characteristics of metal nanostructured composites is discussed. The analysis is based on a non-phenomenological theory of the complex permittivity of these materials. It turns out that the absolute values and temperature dependence of the empirical parameters are largely dependent on the energy of the electrons in traps located around metal nanoparticles. While the frequency dependence of the permittivity near the maximum is closely described by the empirical formula, the interpretation of the temperature dependence encounters serious difficulties, with the empirical parameters having no physical sense.
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Original Russian Text © M.A. Kozhushner, V.L. Bodneva, L.I. Trakhtenberg, 2015, published in Khimicheskaya Fizika, 2015, Vol. 34, No. 9, pp. 74–80.
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Kozhushner, M.A., Bodneva, V.L. & Trakhtenberg, L.I. Simulation of the dielectric and conductive properties of metal-containing nanostructured composites. Russ. J. Phys. Chem. B 9, 748–753 (2015). https://doi.org/10.1134/S1990793115050085
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DOI: https://doi.org/10.1134/S1990793115050085