Abstract
A theoretical analysis of the nonlinear field dependence of the pulsed radiation-induced conductivity of polystyrene in strong electric fields is performed. An explanation of the previously uncomprehended phenomenon of the sharp increase in the radiation-induced electrical conductivity in the presence of an electric field with a strength of above 5 × 107 V/m is proposed. This behavior cannot be explained within the framework of Onsager’s theory of the field-assisted thermal production of free charges from generated geminate pairs.
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References
A. P. Tyutnev, High Energy Chem. 30 (1), 5 (1996).
A. V. Vannikov, V. K. Matveev, V. P. Sichkar’, and A. P. Tyutnev, Radiation Effects in Polymers: Electric Properties (Nauka, Moscow, 1982) [in Russian].
A. P. Tyutnev, A. V. Vannikov, G. S. Mingaleev, and V. S. Saenko, Electric Phenomena upon Irradiation of Polymers (Energoatomizdat, Moscow, 1985) [in Russian].
A. P. Tyutnev, V. S. Saenko, E. D. Pozhidaev, and N. S. Kostyukov, Dielectric Properties of Polymers in Ionizing Radiation Fields (Nauka, Moscow, 2005) [in Russian].
A. Hummel, Adv. Rad. Chem. 4, 1 (1974).
A. P. Tyutnev, V. N. Abramov, P. I. Dubenskov, A. V. Vannikov, V. S. Saenko, et al., Dokl. Akad. Nauk SSSR 289, 1437 (1986).
A. P. Tyutnev, V. N. Abramov, P. I. Dubenskov, V. S. Saenko, A. V. Vannikov, et al., Khim. Vys. Energ. 20, 509 (1986).
A. P. Tyutnev, V. N. Abramov, P. I. Dubenskov, V. S. Saenko, A. V. Vannikov, et al., Acta Polym. 37, 336 (1986).
P. M. Borsenberger and D. S. Weiss, Organic Photoreceptors for Xerography (Marcel Dekker, New York, 1998).
H. Bässler, Phys. Status Solidi B 175, 15 (1993).
S. V. Novikov, D. H. Dunlap, V. M. Kenkre, P. E. Parris, and A. V. Vannikov, Phys. Rev. Lett. 81, 4472 (1998).
L. B. Schein, Russ. J. Electrochem. 48, 281 (2012).
S. V. Novikov and A. P. Tyutnev, J. Chem. Phys. 138, 104120 (2013).
R. Sh. Ikhsanov, A. P. Tyutnev, V. S. Saenko, and E. D. Pozhidaev, Russ. J. Phys. Chem. B 2, 309 (2008).
V. R. Nikitenko, H. von Seggern, and H. Bässler, J. Phys.: Condens. Matter 19, 136210 (2007).
S. D. Baranovskii, Phys. Status Solidi B 251, 487 (2014).
V. R. Nikitenko, Nonstationary Processes of Transport and Recombination of Charge Carriers in Thin Layers of Organic Materials (NIYaU MIFI, Moscow, 2011) [in Russian].
A. P. Tyutnev, R. Sh. Ikhsanov, V. S. Saenko, and E. D. Pozhidaev, Chem. Phys. 404, 88 (2012).
A. P. Tyutnev, D. S. Weiss, D. H. Dunlap, and V. S. Saenko, J. Phys. Chem. C 118, 5150 (2014).
A. P. Tyutnev, R. Sh. Ikhsanov, V. S. Saenko, and E. D. Pozhidaev, Polymer Sci., Ser. A 48, 1196 (2006).
A. P. Tyutnev, Yu. F. Kundina, V. R. Nikitenko, V. S. Saenko, and E. D. Pozhidaev, High Energy Chem. 35, 79 (2001).
A. P. Tyutnev, V. S. Saenko, I. A. Smirnov, and E. D. Pozhidaev, High Energy Chem. 40, 319 (2006).
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Original Russian Text © A.P. Tyutnev, B.L. Linetskii, A.V. Nikerov, V.S. Saenko, 2015, published in Khimicheskaya Fizika, 2015, Vol. 34, No. 7, pp. 58–61.
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Tyutnev, A.P., Linetskii, B.L., Nikerov, A.V. et al. Pulsed radiation-induced conductivity of polymers in strong electric fields. Russ. J. Phys. Chem. B 9, 648–651 (2015). https://doi.org/10.1134/S1990793115040119
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DOI: https://doi.org/10.1134/S1990793115040119