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Effect of Annealing at High Temperatures on the Morphology of Aqueous Solutions of Star-Shaped Poly(2-Isopropyl-2-Oxazoline) and Linear Poly(2-Ethyl-5,6-Dihydrooxazine)

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Abstract

Aqueous solutions of linear poly(2-ethyl-5,6-dihydrooxazine) and eight-armed star-shaped poly(2-isopropyl-2-oxazoline) have been studied by light scattering and turbidimetry. The influence of the duration of annealing at temperatures above the phase separation temperature on the behavior of the solutions has been analyzed. It has been shown that the characteristics of linear polymer solutions do not vary in the studied annealing time interval. The cloud point of star polymer solutions also does not depend on the annealing time. However, significant changes have been observed at the microscopic level, namely, irreversible aggregation due to the interaction of hydrophobic segments of poly(2-isopropyl-2-oxazoline) arms formed during annealing at a high temperature.

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REFERENCES

  1. O. E. Philippova and A. R. Khokhlov, Pet. Chem. 50 (4), 266 (2010).

    Article  Google Scholar 

  2. Industrial Applications for Intelligent Polymers and Coatings, Ed. by M. Hosseini and A.S.H. Makhlouf (Springer, Heidelberg, 2016).

    Google Scholar 

  3. S. Kobayashi, T. Igarashi, Y. Moriuchi, and T. Saegusa, Macromolecules 19, 535 (1986).

    Article  CAS  Google Scholar 

  4. C. Weber, R. Hoogenboom, and U. S. Schubert, Prog. Polym. Sci. 37 (5), 686 (2012).

    Article  CAS  Google Scholar 

  5. K. Kempe, Macromol. Chem. Phys. 218 (11), 1700021 (2012).

  6. C. Weber, M. Wagner, D. Baykal, S. Hoeppener, R. M. Paulus, G. Festag, E. Altuntas, F. H. Schacher, U. S. Schubert, Macromolecules 46 (13), 5107 (2013).

    Article  CAS  Google Scholar 

  7. A. Dworak, B. Trzebicka, A. Kowalczuk, C. Tsvetanov, S. Rangelov, Polimery 59 (1), 88 (2014).

    Article  CAS  Google Scholar 

  8. R. Hoogenboom and H. Schlaad, Polym. Chem. 8 (1), 24 (2017).

    Article  CAS  Google Scholar 

  9. M. M. Lübtow, L. Hahn, M. S. Haider, and R. Luxenhofer, J. Am. Chem. Soc. 139 (32), 10980 (2017).

    Article  Google Scholar 

  10. N. Oleszko-Torbus, W. Waiach, A. Utrata-Wesoiek, and A. Dworak, Macromolecules 50 (19), 7636 (2017).

    Article  CAS  Google Scholar 

  11. B. Verbraeken, B. D. Monnery, K. Lava, and R. Hoogenboom, Eur. Polym. J. 88, 451 (2017).

    Article  CAS  Google Scholar 

  12. O. Sedlacek and R. Hoogenboom, Adv. Ther. 3 (1) (2019).

  13. G. Morgese, B. Verbraeken, S. N. Ramakrishna, Y. Gombert, E. Cavalli, J.-G. Rosenboom, M. Zenobi-Wong, N. D. Spencer, R. Hoogenboom, E. M. Benetti, Angew. Chem. 130 (1), 11841 (2018).

    Article  Google Scholar 

  14. N. Oleszko-Torbus, Polym. Rev. 62 (3), 529 (2022).

    Article  CAS  Google Scholar 

  15. M. M. Bloksma, R. M. Paulus, H. P. C. van Kuringen, F. van der Woerdt, H. M. L. Lambermont-Thijs, U. S. Schubert, R. Hoogenboom, Macromol. Rapid Commun. 33 (1), 92 (2012).

    Article  CAS  Google Scholar 

  16. M. S. Haider, M. M. Lübtow, S. Endres, S. Forster, V. J. Flegler, B. Böttcher, V. Aseyev, A.-C. Pöppler, R. Luxenhofer, ACS Appl. Mater. Interfaces 12 (22), 24531 (2020).

    Article  CAS  Google Scholar 

  17. H. Schlaad, C. Diehl, A. Gress, M. Meyer, A. L. Demirel, Y. Nur, A. Bertin, Macromol. Rapid Commun. 31 (6), 511 (2010).

    Article  CAS  Google Scholar 

  18. D. Roy, W. L. A. Brooks, and B. S. Sumerlin, Chem. Soc. Rev. 42, 7214 (2013).

    Article  CAS  Google Scholar 

  19. K. P. Luef, C. Petit, B. Ottersbock, G. Oreski, F. Ehrenfeld, B. Grassl, S. Reynaud, F. Wiesbrock, Eur. Polym. J. 88, 701 (2017).

    Article  CAS  Google Scholar 

  20. V. Schenk, E. Rossegger, C. Ebner, F. Bangerl, K. Reichmann, B. Hoffmann, M. Höpfner, F. Wiesbrock, Polymers 6 (2), 264 (2014).

    Article  Google Scholar 

  21. T. R. Dargaville, R. Forster, B. L. Farrugia, K. Kempe, L. Voorhaar, U. S. Schubert, R. Hoogenboom, Macromol. Rapid Commun. 33 (19), 1695 (2012).

    Article  CAS  Google Scholar 

  22. A.-Z. Zardad, Y. Essop Choonara, L. C. du Toit, P. Kumar, M. Mabrouk, P. P. D. Kondiah, V. Pillay, Polymers 8 (10), 359 (2016).

    Article  Google Scholar 

  23. D. Kuckling and A. Wycisk, J. Polym. Sci., Part A: Polym. Chem. 51, 2980 (2013).

    Article  CAS  Google Scholar 

  24. A. I. Amirova, O. V. Golub, T. U. Kirila, A. B. Razina, A. V. Tenkovtsev, A. P. Filippov, Colloid Polym. Sci. 294 (6), 947 (2016).

    Article  CAS  Google Scholar 

  25. A. Amirova, S. Rodchenko, S. Milenin, E. Tatarinova, M. Kurlykin, A. Tenkovtsev, A. Filippov, J. Polym. Res. 24 (8), Art. 124 (2017).

  26. T. Kirila, A. Smirnova, V. Aseyev, A. Tenkovtsev, H. Tenhu, A. Filippov, Polymers 13 (9), Art. 1429 (2021).

  27. T. Kirila, A. Smirnova, A. Razina, A. Tenkovtsev, A. Filippov, Polymers 13 (7), Art. 1152 (2021).

  28. A. Smirnova, T. Kirila, A. Blokhin, N. Kozina, M. Kurlykin, A. Tenkovtsev, A. Filippov, Eur. Polym. J. 156, Art.110637 (2021).

  29. T. Yu. Kirila, M. P. Kurlykin, A. V. Tenkovtsev, and A. P. Filippov, Polymer Science, Ser. A 59 (6), 826 (2017).

    Article  CAS  Google Scholar 

  30. T. Yu. Kirile, A. I. Tobolina, A. A. Elkina, M. P. Kurlykin, A. V. Ten’kovtsev, A. P. Filippov, Fibre Chem. 50 (3), 248 (2018).

    Article  CAS  Google Scholar 

  31. M. Meyer, M. Antonietti, and H. Schlaad, Soft Matter 3 (4) (2007).

  32. A. L. Demirel, M. Meyer, and H. Schlaad, Angew. Chem., Int. Ed. Engl. 46, 8622 (2007).

    Article  CAS  Google Scholar 

  33. Y. Katsumoto, A. Tsuchiizu, X. Qiu, and F. M. Winnik, Macromolecules 45 (8), 3531 (2012).

    Article  CAS  Google Scholar 

  34. T. Li, H. Tang, and P. Wu, Langmuir 31 (24), 6870 (2015).

    Article  CAS  Google Scholar 

  35. S. Sun and P. Wu, Phys. Chem. Chem. Phys. 17 (48), 32232 (2015).

    Article  CAS  Google Scholar 

  36. P. T. Güner, A. Miko, F. F. Schweinberger, and A. L. Demirel, Polym. Chem. 3 (2), 322 (2012).

    Article  Google Scholar 

  37. A. V. Ten’kovtsev, A. E. Trofimov, and L. I. Shcherbinskaya, Polymer Science, Ser. B 54 (3–4), 142 (2012).

    Article  Google Scholar 

  38. A. P. Filippov, A. I. Amirova, M. M. Dudkina, and A. V. Tenkovtsev, Int. J. Polym. Anal. Charact. 18 (8), 567 (2013).

    Article  CAS  Google Scholar 

  39. A. Smirnova, T. Kirila, A. Blokhin, N. Kozina, M. Kurlykin, A. Tenkovtsev, A. Filippov, Eur. Polym. J. 156, Art. 110637 (2021).

  40. K. Inoue, Prog. Polym. Sci. 25, 453 (2000).

    Article  CAS  Google Scholar 

  41. A. A. Steinschulte, B. Schulte, S. Rütten, T. Eckert, J. Okuda, M. Möller, S. Schneider, O. V. Borisov, F. A. Plamper, Phys. Chem. Chem. Phys. 16, 4917 (2014).

    Article  CAS  Google Scholar 

  42. I. Dimitrov, B. Trzebicka, A. H. E. Müller, A. Dworak, C. B. Tsvetanov, Prog. Polym. Sci. 32, 1275 (2007).

    Article  CAS  Google Scholar 

  43. X. Han, X. Zhang, H. Zhu, Q. Yin, H. L. Liu, Langmuir 29, 1024 (2013).

    Article  CAS  Google Scholar 

  44. Classical Light Scattering from Polymer Solutions, Ed. by P. Kratochvil (Elsevier, Amsterdam, 1987).

    Google Scholar 

  45. Light Scattering from Polymer Solutions and Nanoparticle Dispersions, Ed. by W. Schärtl (Springer, Heidelberg, 2007).

    Google Scholar 

  46. A. Amirova, O. Golub, T. Kirila, A. Razina, A. Tenkovtsev, A. Filippov, Colloid Polym. Sci. 295 (1), 117 (2017).

    Article  CAS  Google Scholar 

  47. A. V. Smirnova, T. U. Kirila, M. P. Kurlykin, A. V. Tenkovtsev, A. P. Filippov, Int. J. Polym. Anal. 22 (8), 687 (2017).

    Google Scholar 

  48. A. Amirova, S. Rodchenko, Z. Makhmudova, G. Cherkaev, S. Milenin, E. Tatarinova, M. Kurlykin, A. Tenkovtsev, A. Filippov, Macromol. Chem. Phys. 218 (4), Art. 1600387 (2017).

  49. A. Amirova, A. Tobolina, T. Kirila, A. Blokhin, A. Razina, A. Tenkovtsev, A. Filippov, Int. J. Polym. Anal. Charact. 23 (3), 278 (2018).

    Article  CAS  Google Scholar 

  50. T. Kirila, A. Smirnova, M. Kurlykin, A. Tenkovtsev, A. Filippov, Colloid Polym. Sci. 298 (6), 535 (2020).

    Article  CAS  Google Scholar 

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation, project no. 122012100166-4.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    A. V. Smirnova, A. V. Tenkovtsev & A. P. Filippov

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  1. A. V. Smirnova
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  2. A. V. Tenkovtsev
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Correspondence to A. V. Smirnova.

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Translated by S. Zatonsky

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Smirnova, A.V., Tenkovtsev, A.V. & Filippov, A.P. Effect of Annealing at High Temperatures on the Morphology of Aqueous Solutions of Star-Shaped Poly(2-Isopropyl-2-Oxazoline) and Linear Poly(2-Ethyl-5,6-Dihydrooxazine). Polym. Sci. Ser. C 64, 154–160 (2022). https://doi.org/10.1134/S1811238222700072

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