Skip to main content
SpringerLink
Log in

Synthesis of Polyesters of Diatomic Phenols and Boric Acid and Their Interaction with Formaldehyde

  • POLYCONDENSATION
  • Published:
Polymer Science, Series B Aims and scope Submit manuscript

Abstract

The interaction of boric acid and diatomic phenols (resorcinol, hydroquinone and bisphenol А) yields boron-containing polyesters whose condensation with formaldehyde affords corresponding poly(methylene esters). The structure of oligomers is studied by IR, 1Н, 13С, and 11В NMR spectroscopy. Vicat softening temperatures of the synthesized compounds are 70–105°С. All oligomers are soluble in alcohol, acetone, and DMF, except poly(methylene esters) based on bisphenol A. The molecular weights of the oligomers based on resorcinol and hydroquinone are within (1.6–4.2) × 103, and soluble diane oligoesters have Mn = (9–14) × 103.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. W. F. Zhang, C. L. Liu, Y. G. Ying, and W. S. Dong, Mater. Chem. Phys. 121, 89 (2010).

    Article  CAS  Google Scholar 

  2. L. Liu and Z. P. Ye, Polym. Degrad. Stab. 94, 1972 (2009).

    Article  CAS  Google Scholar 

  3. C. Martin, B. J. Hunt, J. R. Ebdon, J. C. Ronda, and V. Cadiz, React. Funct. Polym. 66, 1047 (2006).

    Article  CAS  Google Scholar 

  4. M. Sacristan, J. C. Ronda, M. Galia, and V. Cadiz, Polymer 51, 6099 (2010).

    Article  CAS  Google Scholar 

  5. J. F. Chai, C. Wang, L. Jia, Y. Pang, M. Graham, and S. Z. D. Cheng, Synth. Met. 159, 1443 (2009).

    Article  CAS  Google Scholar 

  6. M. A. Lenskii, E. E. Shul’ts, A. A. Androshchuk, and G. A. Tolstikov, Russ. J. Org. Chem. 45, 1772 (2009).

    Article  CAS  Google Scholar 

  7. V. V. Korshak, V. A. Zamyatina, and N. I. Bekasova, Organoboron Polymers (Nauka, Moscow, 1975) [in Russian].

    Google Scholar 

  8. W. J. Emsley, J. Feeney, and L. H. Sutcliffe, High Resolution Nuclear Magnetic Resonance Spectroscopy (Pergamon Press, New York, 1966), Vol. 2.

    Google Scholar 

  9. P. Xu and P. Cong, in Boron-Containing Benzoxazine Resin (Elsevier, Amsterdam, 2017), Chap. 14, p. 233.

    Book  Google Scholar 

  10. Y. H. Liu, J. P. Qiang, and X. L. Jing, J. Rolym. Sci., Part A: Polym. Chem. 45, 3473 (2007).

    Article  CAS  Google Scholar 

  11. Y. H. Liu and X. L. Jing, Carbon 45, 1965 (2007).

    Article  CAS  Google Scholar 

  12. Y. H. Liu and X. L. Jing, J. Rolym. Sci., Part B: Polym. Phys. 46, 2012 (2008).

    Article  CAS  Google Scholar 

  13. J. J. Si, P. J. Xu, W. He, S. J. Wang, and X. L. Jing, Composites, Part A 43, 2249 (2012).

    Article  CAS  Google Scholar 

  14. S. J. Wang, C. Bian, B. B. Jia, Y. N. Wang, and X. L. Jing, Polym. Degrad. Stab. 130, 328 (2016).

    Article  CAS  Google Scholar 

  15. A. A. Androshchuk, A. M. Belousov, and M. A. Lenskii, Polzunovskii Vestn., No. 3, 332 (2008).

  16. A. A. Androshchuk, M. A. Lenskii, and A. M. Belousov, Int. Polym. Sci. Technol. 38 (1), 33 (2011).

    Article  Google Scholar 

  17. D. V. Korabel’nikov, M. A. Lenskii, and A. V. Ozhogin, Int. Polym. Sci. Technol. 39 (5), T/17 (2012).

  18. D. V. Korabel’nikov, M. A. Lenskii, M. S. Nekrasov, R. N. Kondrat’ev, and I. E. Kartavykh, Int. Polym. Sci. Technol. 40 (1), T51 (2013).

    Article  Google Scholar 

  19. D. V. Korabel’nikov, M. A. Lenskii, A. V. Ozhogin, A. S. Nartov, and E. S. Anan’eva, Int. Polym. Sci. Technol. 43 (2), T11 (2016).

    Article  Google Scholar 

  20. S. R. Rafikov, S. A. Pavlova, and I. I. Tverdokhlebova, Methods of Determination of Molecular Masses and Polydispersity of High-Molecular Compounds (Izd. AN SSSR, Moscow, 1963) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Biysk Technological Institute, Altai State Technical University, 659305, Biysk, Russia

    M. A. Lenskiy, D. V. Korabel’nikov, A. V. Ozhogin & A. N. Novitskiy

  2. Institute for Problems of Chemical and Energetic Technologies, Siberian Branch, Russian Academy of Sciences, 659322, Biysk, Russia

    M. A. Lenskiy & A. N. Novitskiy

  3. Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    E. E. Shul’ts

Authors
  1. M. A. Lenskiy
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. E. Shul’ts
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. V. Korabel’nikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Ozhogin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. N. Novitskiy
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. A. Lenskiy.

Additional information

Translated by T. Soboleva

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lenskiy, M.A., Shul’ts, E.E., Korabel’nikov, D.V. et al. Synthesis of Polyesters of Diatomic Phenols and Boric Acid and Their Interaction with Formaldehyde. Polym. Sci. Ser. B 61, 530–539 (2019). https://doi.org/10.1134/S1560090419050105

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1560090419050105

Search

Navigation