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One-pot method for the synthesis of sulfonated poly(1,3,4-oxadiazoles) based on 4,4’-oxydibenzoic acid

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Abstract

A series of new copolymers of poly(1,3,4-oxadiazole) that contain side protogenic sulfo groups are synthesized by the direct copolycondensation of terephthalic and 4,4’-oxydibenzoic acids and hydrazine sulfate in oleum. Variation in the polycondensation conditions makes it possible to synthesize copolymers containing phenylene moieties with either 4-sulfo-10,10-dioxophenoxatiine or 4,4’-oxybis(3-sulfophenyl) moieties or a combination of the three moieties. This approach permits easy control over the physicochemical properties of the copolymers and the amount of protogenic sulfo groups. It is shown that the introduction of sulfonated moieties into copolymer molecules makes it possible to obtain materials with high values of ionexchange capacity (1.5 mmol/g) and water absorption (110%), while the strength and thermal stability inherent in poly(p-phenylene 1,3,4-oxadiazoles) remain intact.

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Authors and Affiliations

  1. Institute of Chemistry of New Materials, National Academy of Sciences of Belarus, ul. Frantsiska Skoriny 36, Minsk, 220141, Belarus

    V. S. Yashchenko, A. A. Pap, Yu. V. Matveenko & V. K. Ol’khovik

Authors
  1. V. S. Yashchenko
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  2. A. A. Pap
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  3. Yu. V. Matveenko
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  4. V. K. Ol’khovik
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Corresponding author

Correspondence to V. K. Ol’khovik.

Additional information

Original Russian Text © V.S. Yashchenko, A.A. Pap, Yu.V. Matveenko, V.K. Ol’khovik, 2016, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2016, Vol. 58, No. 5, pp. 375–386.

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Yashchenko, V.S., Pap, A.A., Matveenko, Y.V. et al. One-pot method for the synthesis of sulfonated poly(1,3,4-oxadiazoles) based on 4,4’-oxydibenzoic acid. Polym. Sci. Ser. B 58, 529–540 (2016). https://doi.org/10.1134/S1560090416050134

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  • DOI: https://doi.org/10.1134/S1560090416050134

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